Polymer-based resin compositions derived from cellulose and articles made using these compositions

Patent metadata

Field	Value
Publication number	US-11655309-B2
Application number	US-201716348586-A
Country	US
Kind code	B2
Filing date	Nov 9, 2017
Priority date	Nov 11, 2016
Publication date	May 23, 2023
Grant date	May 23, 2023

Abstract

A shaped article comprising a polymer-based resin derived from cellulose, wherein the polymer-based resin has an HDT of at least 95° C., a bio-derived content of at least 20 wt %, a notched izod impact strength of greater than 80 J/m and at least one of the following properties chosen from: flexural modulus of greater than 1900 MPa; a spiral flow length or at least 3.0 cm; a flex creep deflection of less than 12 mm; a transmission of at least 70%; a ΔE value of less than 25; or an L* color of at least 85.

First claim

That which is claimed is:

1. A shaped article comprising a polymer-based resin derived from cellulose, wherein the polymer-based resin has a heat deflection temperature (HDT) of at least 95° C., a bio-derived content of at least 20 wt %, a notched Izod impact strength of greater than 100 J/m as measured according to ASTM D256 using a 3.2 mm thick bar that has been subjected to 50% relative humidity for 48 hours at 23° C., and has at least one of the following properties chosen from: flexural modulus of greater than 1900 MPa as measured according to ASTM D790 using a 3.2 mm thick bar that has been subjected to 50% relative humidity for 48 hours at 23° C.; a spiral flow length of at least 3.0 cm, when the polymer-based resin is molded with a spiral flow mold with the conditions of a barrel temperature of 238° C., a melt temperature of 246° C., a molding pressure of 13.8 MPa, a mold thickness of 0.8 mm, and a mold width of 12.7 mm; a flex creep deflection of less than 12 mm, measured using a molded bar having dimensions of 5″ length, 0.5″ width, and 0.125″ thickness positioned horizontally on a fixture with a 4″ span, inside a dry oven for 68 hours at 90° C. with a nominal 500 psi stress on the center of the span; a transmission of at least 70 measured according to ASTM D1003 using a 3.2 mm plaque after injection molding at a barrel set point of 249° C. and a residence time of 5 min; a ΔE value of less than 25, using a 3.2 mm plaque after injection molding with a barrel temperature of 249° C. and a residence time of 5 min; or an L* color of at least 85, measured according to ASTM E1348 using a 3.2 mm plaque after injection molding with a barrel temperature of 249° C. and a residence time of 5 min, wherein the polymer-based resin contains less than 4 wt % of a plasticizer, wherein the polymer-based resin comprises a cellulose ester which has an absolute weight average molecular weight in the range of from about 40,000 Da to about 200,000 Da measured according to ASTM D5296 using tetrahydrofuran as a solvent and a flow rate of 1 mL/min and a core-shell impact modifier in the range of 1 to 15 wt % based on the total weight of the polymer-based resin, and wherein the cellulose ester is chosen from cellulose acetate (CA), cellulose acetate propionate (CAP), cellulose acetate butyrate (CAB) or cellulose acetate isobutyrate (CAIB).

2. The shaped article according to claim 1 , wherein the polymer-based resin has an HDT in the range from 95° C. to 140° C.

3. The shaped article according to claim 2 , wherein the polymer-based resin has an HDT in the range from 100° C. to 140° C.

4. The shaped article according to claim 1 , wherein the polymer-based resin has a bio-derived content in the range from 20 wt % to 60 wt %.

5. The shaped article according to claim 4 , wherein the polymer-based resin has a bio-derived content in the range from 40 wt % to 60 wt %.

6. The shaped article according to claim 1 , wherein the polymer-based resin has at least 2 of the listed properties.

7. The shaped article according to claim 1 , wherein the cellulose ester is CAP.

8. The shaped article according to claim 7 , wherein the CAP contains no plasticizer.

9. The shaped article according to claim 1 , wherein the cellulose ester is CA.

10. The shaped article according to claim 1 , wherein the polymer-based resin is CAP, wherein the CAP has an HDT of at least 95° C., a bio-derived content of at least 40 wt %, a spiral flow length or at least 5.0 cm, when the polymer-based resin is molded with a spiral flow mold with the conditions of a barrel temperature of 238° C., a melt temperature of 246° C., a molding pressure of 13.8 MPa, a mold thickness of 0.8 mm, and a mold width of 12.7 mm; a flex creep deflection of less than 10 mm, measured using a molded bar having dimensions of 5″ length, 0.5″ width, and 0.125″ thickness positioned horizontally on a fixture with a 4″ span, inside a dry oven for 68 hours at 90° C. with a nominal 500 psi stress on the center of the span; and a ΔE value of less than 25, using a 3.2 mm plaque after injection molding with a barrel temperature of 249° C. and a residence time of 5 min.

11. The shaped article according to claim 1 , wherein the shaped article can be chosen from injection molded articles, extrusion molded articles, rotational molded articles, compression molded articles, blow molded articles, injection blow molded articles, injection stretch blow molded articles, extrusion blow molded articles, sheet or film extrusion articles, profile extrusion articles, gas assist molding articles, structural foam molded articles, or thermoformed articles.

12. The shaped article according to claim 1 , wherein the shaped article can be chosen from transparent articles, see-through articles, thin-walled articles, technical articles, articles having high design specifications, intricate design articles, articles made from molds that are difficult to fill under typical molding operations or conditions, wearable articles, body contact articles, containers, food contact articles, household articles, general consumer products, packaging articles, medical articles, or components thereof.

Assignees

• Eastman Chem Co

Inventors

• Feng Wenlai
• An Haining
• Donelson Michael Eugene
• Pecorini Thomas Joseph
• Mccrary Robert Ellis
• Carico Douglas Weldon
• Gilliam Spencer Allen

Classifications

• B29C2945/76668

  barrel · CPC title

• B29C2945/76561

  duration · CPC title

• B29C2945/76531

  Temperature · CPC title

• B29C2945/76498

  Pressure · CPC title

• B29C45/78

  of temperature · CPC title