Stable binary nanocrystalline alloys and methods of identifying same

Patent metadata

Field	Value
Publication number	US-11650193-B2
Application number	US-201916254570-A
Country	US
Kind code	B2
Filing date	Jan 22, 2019
Priority date	Mar 12, 2012
Publication date	May 16, 2023
Grant date	May 16, 2023

Abstract

Identifying a stable phase of a binary alloy comprising a solute element and a solvent element. In one example, at least two thermodynamic parameters associated with grain growth and phase separation of the binary alloy are determined, and the stable phase of the binary alloy is identified based on the first thermodynamic parameter and the second thermodynamic parameter, wherein the stable phase is one of a stable nanocrystalline phase, a metastable nanocrystalline phase, and a non-nanocrystalline phase. In different aspects, an enthalpy of mixing of the binary alloy may be calculated as a first thermodynamic parameter, and an enthalpy of segregation of the binary alloy may be calculated as a second thermodynamic parameter. In another example, a diagram delineating a plurality of regions respectively representing different stable phases of at least one binary alloy is employed, wherein respective regions of the plurality of regions are delineated by at least one boundary determined as a function of at least two thermodynamic parameters associated with grain growth and phase separation of the at least one binary alloy.

First claim

What is claimed:

1. An alloy comprising:
a pair of elements in which one element of the pair is a solvent element and a second element of the pair is a solute element, the pair of elements being Al and Pb, Co and Au, Co and Bi, Co and Cd, Co and Pb, Cr and Au, Cr and Bi, Cr and Cd, Cr and La, Cr and Na, Cr and Pb, Cr and Sc, Cr and Sn, Cr and Th, Cr and Y, Cu and Y, Fe and Au, Fe and Ba, Fe and Bi, Fe and Ca, Fe and Cd, Fe and In, Fe and La, Fe and Mg, Fe and Pb, Hf and Mg, Hf and Ti, Jr and Cu, Jr and Ni, Jr and Rh, La and Li, La and Mn, Mn and Ba, Mn and Ca, Mn and Cd, Mn and Mg, Mn and Pb, Mn and Sr, Mn and Tl, Mo and Au, Mo and Ba, Mo and Cr, Mo and Cd, Mo and In, Mo and Na, Mo and Pb, Mo and Sc, Mo and Th, Mo and V, Mo and Y, Nb and Bi, Nb and Cu, Nb and Ti, Nb and Tl, Nb and V, Ni and Pb, Ni and Sn, Ni and Tl, Os and Bi, Os and Co, Os and Ni, Os and Pb, Os and Pt, Os and Rh, Os and Ru, Pd and Au, Pt and Au, Re and Bi, Re and Co, Re and La, Re and Ni, Re and Pd, Re and Rh, Re and Sb, Re and Sn, Re and Tc, Rh and Ag, Rh and Au, Rh and Co, Rh and Cu, Rh and Ni, Ru and Au, Ru and Bi, Ru and Co, Ru and Hg, Ru and Ni, Ru and Pt, Ru and Sb, Ta and Bi, Ta and Cu, Ta and Hf, Ta and In, Ta and Ti, Ta and Tl, Ta and Zr, Tc and Ni, Tc and Pd, Tc and Rh, Th and La, Th and Sc, Th and Y, V and Bi, V and Cd, V and In, V and Sc, V and Ti, V and Tl, W and Au, W and Cr, W and In, W and La, W and Mn, W and Pb, W and Sb, W and Sc, W and Sn, W and Sr, W and Th, W and Ti, W and V, W and Y, W and Zn, Y and Sr, Zn and Pb, Zr and Mg, or Zr and Sc;
wherein:
the solute element and the solvent element are the two most abundant elements in the alloy by atomic percentage;
the alloy has a plurality of grains, the plurality having an average largest dimension of less than or equal to 1,000 nm; and
atoms of either the solute element or the solvent element are segregated to grain boundaries of the alloy.

2. The alloy of claim 1 , wherein the solute element is 1 at % to 40 at % of the alloy.

3. The alloy of claim 1 , wherein the alloy is formed by at least one of electrodeposition, physical vapor deposition, chemical vapor deposition, plasma-spraying, mechanical alloying, casting, and solidification.

4. The alloy of claim 1 , wherein an enthalpy of mixing of the alloy is negative.

5. The alloy of claim 1 , wherein the alloy is thermodynamically stable at a temperature of 1,000 K.

6. The alloy of claim 1 , wherein atoms of the solute element are segregated to grain boundaries of the alloy.

7. The alloy of claim 1 , wherein the pair of elements is W and Au, W and Cr, W and In, W and La, W and Mn, W and Pb, W and Sb, W and Sc, W and Sn, W and Sr, W and Th, W and Ti, W and V, W and Y, or W and Zn.

8. The alloy of claim 1 , wherein the pair of elements is Cr and Au, Cr and Bi, Cr and Cd, Cr and La, Cr and Na, Cr and Pb, Cr and Sc, Cr and Sn, Cr and Th, Cr and Y, or Mo and Cr.

9. The alloy of claim 1 , wherein the pair of elements is Fe and Au, Fe and Ba, Fe and Bi, Fe and Ca, Fe and Cd, Fe and In, Fe and La, Fe and Mg, or Fe and Pb.

10. The alloy of claim 1 , wherein the pair of elements is Hf and Ti, Nb and Ti, Ta and Ti, V and Ti, or W and Ti.

11. The alloy of claim 1 , wherein the pair of elements is Pt and Au.

12. The alloy of claim 1 , wherein the plurality of grains has an average largest dimension of greater than or equal to 2 nm and less than or equal to 1000 nm.

13. The alloy of claim 1 , wherein the solute element content of the alloy ranges from 0.1 mass % to 48 mass %.

14. The alloy of claim 1 , wherein the solute element content of the alloy is at least 0.5 mass %.

15. The alloy of claim 14 , wherein the solute element content of the alloy ranges from 0.5 mass % to 45 mass %.

16. The alloy of claim 15 , wherein the solute element content of the alloy ranges from 0.5 mass % to 1 mass %.

Assignees

• Massachusetts Inst Technology

Inventors

• Murdoch Heather A
• Schuh Christopher A

Classifications

• G01N33/204 Primary

  Structure thereof, e.g. crystal structure · CPC title

• C22C27/02

  Alloys based on vanadium, niobium, or tantalum · CPC title

• C22C12/00

  Alloys based on antimony or bismuth · CPC title

• C22C43/00

  Alloys containing radioactive materials · CPC title

• C22C11/00

  Alloys based on lead · CPC title