Stable nanocrystalline ordering alloy systems and methods of identifying same

Patent metadata

Field	Value
Publication number	US-10585054-B2
Application number	US-201816218356-A
Country	US
Kind code	B2
Filing date	Dec 12, 2018
Priority date	May 21, 2013
Publication date	Mar 10, 2020
Grant date	Mar 10, 2020

Abstract

Provided in one embodiment is a method of identifying a stable phase of an ordering binary alloy system comprising a solute element and a solvent element, the method comprising: determining at least three thermodynamic parameters associated with grain boundary segregation, phase separation, and intermetallic compound formation of the ordering binary alloy system; and identifying the stable phase of the ordering binary alloy system based on the first thermodynamic parameter, the second thermodynamic parameter and the third thermodynamic parameter by comparing the first thermodynamic parameter, the second thermodynamic parameter and the third thermodynamic parameter with a predetermined set of respective thermodynamic parameters to identify the stable phase; wherein the stable phase is one of a stable nanocrystalline phase, a metastable nanocrystalline phase, and a non-nanocrystalline phase.

First claim

What is claimed:

1. An alloy comprising:
a solvent element and a solute element;
the alloy comprising at least one of Ag—Sc, Ag—La, Ag—Y, Ba—Pd, Ba—Pt, Be—Ti, Bi—Pd, Ca—Pt, Cd—Pd, Co—Al, Co—As, Co—Ga, Co—Ge, Co—Hf, Co—Nb, Co—Sc, Co—Ta, Co—Ti, Co—Y, Co—Zr, Cr—Pt, Fe—Al, Fe—As, Fe—Hf, Fe—Sc, Hf—Ag, Hf—Bi, Hf—Co, Hf—Ni, Hf—Re, Hf—Tl, Ir—Cd, Ir—Cr, Ir—Ge, Ir—In, Ir—Mg, Ir—Mn, Ir—Sb, Ir—Zn, La—Ag, La—Au, La—Ir, La—Rh, La—Zn, Mn—Ga, Mn—Pd, Mn—Sb, Mo—Al, Mo—Ge, Mo—Pd, Nb—Co, Nb—Ga, Nb—Ni, Nb—Re, Nb—Sb, Nb—Sn, Nb—Zn, Ni—Ga, Ni—Ge, Ni—Hf, Ni—In, Ni—La, Ni—Mg, Ni—Nb, Ni—Ta, Ni—Th, Ni—Y, Ni—Zn, Os—As, Os—Ga, Os—Ge, Os—P, Os—V, Os—Y, Os—Zn, Pd—Mn, Pt—Bi, Pt—K, Pt—Mn, Pt—Na, Pt—Tl, Re—Al, Re—As, Re—Ga, Re—Ge, Re—Hf, Re—Nb, Re—Sc, Re—Ta, Re—Ti, Rh—Bi, Rh—Cd, Rh—In, Rh—Mg, Rh—Mn, Rh—Sb, Rh—Sn, Rh—Tl, Rh—Zn, Ru—Ga, Ru—Ge, Ru—La, Ru—Y, Ru—Zn, Sc—Ag, Sc—Ni, Sc—Os, Sc—Ru, Sc—Tc, Sn—Pd, Sr—Pd, Sr—Pt, Ta—Al, Ta—Fe, Ta—Ga, Ta—Ni, Ta—Re, Ta—Sb, Ta—Sn, Ta—Zn, Tc—Ge, Tc—La, Tc—Th, Tc—V, Tc—Y, Tc—Zn, Th—Ir, Th—Rh, Ti—Be, Ti—Bi, Ti—Cd, Ti—Co, Ti—In, Ti—Ni, Ti—Pb, Ti—Sn, Ti—Zn, V—Ga, V—Ru, V—Sb, V—Tc, W—Al, W—As, W—Ge, W—Hf, W—Ir, W—Pt, W—Si, W—Zr, Y—Ag, Y—Ir, Y—Rh, Y—Zn, Zn—Hf, Zn—La, Zn—Sc, Zn—Y, Zr—Ag, Zr—Be, Zr—Co, and Zr—Ni;
the alloy having an average grain size of less than or equal to about 1,000 nm; and
a phase of the alloy being stable against grain growth.

2. The alloy of claim 1 , wherein the alloy comprises less than about 40 at % of the solute element.

3. The alloy of claim 1 , wherein the solute element is about 1 at % to about 30 at % of the alloy.

4. The alloy of claim 1 , wherein the alloy is formed by at least one of electrodeposition, physical vapor deposition, chemical vapor deposition, plasma-spraying, mechanical alloying, casting, and solidification.

5. The alloy of claim 1 , wherein an enthalpy of mixing of the alloy is negative.

6. The alloy of claim 1 , wherein the alloy is substantially thermodynamically stable at a temperature of 1,000 K.

7. The alloy of claim 1 , wherein the phase of the alloy that is stable against grain growth is a nanocrystalline phase.

8. The alloy of claim 1 , wherein the phase of the alloy that is stable against grain growth is a metastable nanocrystalline phase.

9. The alloy of claim 1 , wherein the phase of the alloy that is stable against grain growth is a non-nanocrystalline phase.

10. The alloy of claim 1 , wherein the phase of the alloy that is stable against grain growth has a first thermodynamic parameter associated with grain boundary segregation of the alloy, and the phase is stable when the first thermodynamic parameter is within a predetermined region of a stability map of the alloy.

11. The alloy of claim 10 , wherein the phase of the alloy that is stable against grain growth has a second thermodynamic parameter associated with phase separation of the alloy, and the phase is stable when the second thermodynamic parameter is within a predetermined region of a stability map of the alloy.

12. The alloy of claim 11 , wherein the phase of the alloy that is stable against grain growth has a third thermodynamic parameter associated with intermetallic compound formation of the alloy, and the phase is stable when the third thermodynamic parameter is within a predetermined region of a stability map of the alloy.

13. An alloy comprising:
a mixture of a solute element and a solvent element,
the mixture having a phase including at least one of a stable nanocrystalline phase, a metastable nanocrystalline phase, and a non-nanocrystalline phase, and
the phase being stable at a temperature of 1,000 K when a plurality of thermodynamic parameters are within a predetermined region of a stability map of the alloy.

14. The alloy of claim 13 , wherein the alloy is an ordered binary alloy comprising at least one of Ag—Sc, Ag—La, Ag—Y, Ba—Pd, Ba—Pt, Be—Ti, Bi—Pd, Ca—Pt, Cd—Pd, Co—Al, Co—As, Co—Ga, Co—Ge, Co—Hf, Co—Nb, Co—Sc, Co—Ta, Co—Ti, Co—Y, Co—Zr, Cr—Pt, Cu—Sc, Fe—Al, Fe—As, Fe—Hf, Fe—Sc, Fe—Zr, Hf—Ag, Hf—Bi, Hf—Co, Hf—Ni, Hf—Os, Hf—Re, Hf—Tl, Ir—Cd, Ir—Cr, Ir—Ge, Ir—In, Ir—Mg, Ir—Mn, Ir—Sb, Ir—Zn, La—Ag, La—Au, La—Ir, La—Rh, La—Zn, Mn—Ga, Mn—Pd, Mn—Sb, Mo—Al, Mo—Ge, Mo—Pd, Nb—Co, Nb—Ga, Nb—Ni, Nb—Re, Nb—Sb, Nb—Sn, Nb—Zn, Ni—Ga, Ni—Ge, Ni—Hf, Ni—In, Ni—La, Ni—Mg, Ni—Nb, Ni—Ta, Ni—Th, Ni—Y, Ni—Zn, Os—As, Os—Ga, Os—Ge, Os—P, Os—V, Os—Y, Os—Zn, Pd—Mn, Pt—Bi, Pt—K, Pt—Mn, Pt—Na, Pt—Tl, Re—Al, Re—As, Re—Ga, Re—Ge, Re—Hf, Re—Nb, Re—Sc, Re—Ta, Re—Ti, Rh—Bi, Rh—Cd, Rh—In, Rh—Mg, Rh—Mn, Rh—Sb, Rh—Sn, Rh—Tl, Rh—Zn, Ru—Ga, Ru—Ge, Ru—La, Ru—Mg, Ru—V, Ru—Y, Ru—Zn, Sc—Ag, Sc—Cu, Sc—Ni, Sc—Os, Sc—Ru, Sc—Tc, Sn—Pd, Sr—Pd, Sr—Pt, Ta—Al, Ta—Fe, Ta—Ga, Ta—Ni, Ta—Re, Ta—Sb, Ta—Sn, Ta—Zn, Tc—Ge, Tc—La, Tc—Th, Tc—V, Tc—Y, Tc—Zn, Th—Ir, Th—Rh, Ti—Be, Ti—Bi, Ti—Cd, Ti—Co, Ti—In, Ti—Ni, Ti—Pb, Ti—Sn, Ti—Zn, V—Ga, V—Ru, V—Sb, V—Tc, W—Al, W—As, W—Ge, W—Hf, W—Ir, W—Pt, W—Si, W—Zr, Y—Ag, Y—Ir, Y—Rh, Y—Zn, Zn—Hf, Zn—La, Zn—Sc, Zn—Y, Zr—Ag, Zr—Be, Zr—Co, Zr—Cu, and Zr—Ni.

15. The alloy of claim 13 , wherein the plurality of thermodynamic parameters are associated with at least two of grain boundary segregation, phase separation of the alloy system, and intermetallic compound formation of the alloy system.

16. The alloy of claim 13 , wherein the alloy is substantially free of a classical segregation-stabilized nanocrystalline phase.

17. The alloy of claim 13 , wherein the alloy system is formed by at least one of electrodeposition, physical vapor deposition, chemical vapor deposition, plasma-spraying, mechanical alloying, casting, and solidification.

18. An alloy comprising:
a mixture of a solute element and a solvent element, the mixture having a phase including at least one of a stable nanocrystalline phase, a metastable nanocrystalline phase, and a non-nanocrystalline phase,
the phase having a first thermodynamic parameter associated with grain boundary segregation of the alloy and a second thermodynamic parameter associated with phase separation of the alloy, the phase being stable against grain growth when the first and second thermodynamic parameters are within a predetermined set of predetermined parameters.

19. The alloy of claim 18 , wherein the alloy is an ordered binary alloy comprising at least one of Ag—Sc, Ag—La, Ag—Y, Ba—Pd, Ba—Pt, Be—Ti, Bi—Pd, Ca—Pt, Cd—Pd, Co—Al, Co—As, Co—Ga, Co—Ge, Co—Hf, Co—Nb, Co—Sc, Co—Ta, Co—Ti, Co—Y, Co—Zr, Cr—Pt, Cu—Sc, Fe—Al, Fe—As, Fe—Hf, Fe—Sc, Fe—Zr, Hf—Ag, Hf—Bi, Hf—Co, Hf—Ni, Hf—Os, Hf—Re, Hf—Tl, Ir—Cd, Ir—Cr, Ir—Ge, Ir—In, Ir—Mg, Ir—Mn, Ir—Sb, Ir—Zn, La—Ag, La—Au, La—Ir, La—Rh, La—Zn, Mn—Ga, Mn—Pd, Mn—Sb, Mo—Al, Mo—Ge, Mo—Pd, Nb—Co, Nb—Ga, Nb—Ni, Nb—Re, Nb—Sb, Nb—Sn, Nb—Zn, Ni—Ga, Ni—Ge, Ni—Hf, Ni—In, Ni—La, Ni—Mg, Ni—Nb, Ni—Ta, Ni—Th, Ni—Y, Ni—Zn, Os—As, Os—Ga, Os—Ge, Os—P, Os—V, Os—Y, Os—Zn, Pd—Mn, Pt—Bi, Pt—K, Pt—Mn, Pt—Na, Pt—Tl, Re—Al, Re—As, Re—Ga, Re—Ge, Re—Hf, Re—Nb, Re—Sc, Re—Ta, Re—Ti, Rh—Bi, Rh—Cd, Rh—In, Rh—Mg, Rh—Mn, Rh—Sb, Rh—Sn, Rh—Tl, Rh—Zn, Ru—Ga, Ru—Ge, Ru—La, Ru—Mg, Ru—V, Ru—Y, Ru—Zn, Sc—Ag, Sc—Cu, Sc—Ni, Sc—Os, Sc—Ru, Sc—Tc, Sn—Pd, Sr—Pd, Sr—Pt, Ta—Al, Ta—Fe, Ta—Ga, Ta—Ni, Ta—Re, Ta—Sb, Ta—Sn, Ta—Zn, Tc—Ge, Tc—La, Tc—Th, Tc—V, Tc—Y, Tc—Zn, Th—Ir, Th—Rh, Ti—Be, Ti—Bi, Ti—Cd, Ti—Co, Ti—In, Ti—Ni, Ti—Pb, Ti—Sn, Ti—Zn, V—Ga, V—Ru, V—Sb, V—Tc, W—Al, W—As, W—Ge, W—Hf, W—Ir, W—Pt, W—Si, W—Zr, Y—Ag, Y—Ir, Y—Rh, Y—Zn, Zn—Hf, Zn—La, Zn—Sc, Zn—Y, Zr—Ag, Zr—Be, Zr—Co, Zr—Cu, and Zr—Ni.

20. The alloy of claim 18 , wherein the alloy is substantially thermodynamically stable at a temperature of 1,000 K.

21. The alloy of claim 18 , wherein the phase of the alloy that

Assignees

• Massachusetts Inst Technology

Inventors

• Murdoch Heather A
• Schuh Christopher A

Classifications

• C22C12/00

  Alloys based on antimony or bismuth · CPC title

• C22C1/00 Primary

  Making non-ferrous alloys (by electrothermic methods C22B4/00; by electrolysis C25C1/24, C25C3/36) · CPC title

• C22C24/00

  Alloys based on an alkali or an alkaline earth metal · CPC title

• C22C45/00

  Amorphous alloys (making amorphous non-ferrous alloys C22C1/11) · CPC title

• C22C20/00

  Alloys based on cadmium · CPC title