Core-shell morphology of composite filaments for use in extrusion-based additive manufacturing systems

Patent metadata

Field	Value
Publication number	US-11643754-B2
Application number	US-202016750514-A
Country	US
Kind code	B2
Filing date	Jan 23, 2020
Priority date	Mar 21, 2016
Publication date	May 9, 2023
Grant date	May 9, 2023

Abstract

A consumable filament for use in an extrusion-based additive manufacturing system, where the consumable filament comprises a core portion of a matrix of a first base polymer and particles dispersed within the matrix, and a shell portion comprising a same or a different base polymer. The consumable filament is configured to be melted and extruded to form roads of a plurality of solidified layers of a three-dimensional part, and where the roads at least partially retain cross-sectional profiles corresponding to the core portion and the shell portion of the consumable filament and retain the particles within the roads of the printed part and do not penetrate the outer surface of the shell portion.

First claim

The invention claimed is:

1. A consumable filament for use in an additive manufacturing system, the consumable filament comprising:
a core portion extending along a longitudinal length of the consumable filament, the core portion compositionally comprising a matrix of a first base polymer and glass beads, glass fiber, carbon fiber particles or combinations thereof dispersed in the matrix, wherein the particles comprise between at least about 20 percent to about 85 percent by volume of the core portion; and
a shell portion extending along the longitudinal length of the consumable filament and at least partially encasing the core portion, the shell portion compositionally comprising a second base polymer, wherein the consumable filament is configured to be supplied through a feed line to an extruder of the additive manufacturing system, melted and extruded through a nozzle of the extruder, wherein the shell retains the particles within the core portion and is configured to remain substantially intact as the filament is extruded, to thereby reduce wear on the nozzle and other machinery of the additive manufacturing system relative to a filament loaded with a similar amount of particles throughout a cross-section of the filament such that the filament is configured to print a loaded polymer based 3D part.

2. The consumable filament of claim 1 , wherein the particles comprises between at least about 50 percent to about 85 percent by volume of the core portion.

3. The consumable filament of claim 1 , wherein the first base polymer and the second base polymer are the same.

4. The consumable filament of claim 1 , wherein the first base polymer and the second base polymer are different.

5. The consumable filament of claim 1 , wherein a glass transition temperature of the first base polymer and the second base polymer are substantially similar.

6. The consumable filament of claim 1 , wherein the filament has a cylindrical configuration.

7. The consumable filament of claim 1 , wherein the filament has a ribbon configuration.

8. The consumable filament of claim 1 , wherein the shell portion and the core portion both comprise Acrylonitrile Styrene Acrylate (ASA).

9. The consumable filament of claim 1 , wherein the shell comprises glass beads, carbon fiber particles or combinations thereof, and wherein a concentration of the shell comprises glass beads, carbon fiber particles or combinations thereof in the shell is less than a concentration of the shell comprises glass beads, glass fiber, carbon fiber particles or combinations thereof in the core.

10. The consumable filament of claim 1 , wherein the shell comprises glass beads, glass fiber, carbon fiber particles or combinations thereof have a size between about 10 microns and about 200 microns.

11. A consumable filament for use in an additive manufacturing system, the consumable filament comprising:
a core portion extending along a longitudinal length of the consumable filament, the core portion compositionally comprising a matrix of a first base polymer and carbon fiber particles dispersed in the matrix, wherein the carbon fiber particles comprises between at least about 1 percent to about 80 percent by weight of the filament; and
a shell portion extending along the longitudinal length of the consumable filament and at least partially encasing the core portion, the shell portion compositionally comprising a second base polymer, wherein the consumable filament is configured to be melted and extruded in an additive manufacturing system, wherein the core portion is configured to remain substantially intact as the filament travels from a source to a print head to increase reliability of delivery of the filament to the print head from the source such that the filament is configured to print a loaded polymer based 3D part.

12. The consumable filament of claim 11 , wherein the filler further comprises glass spheres, glass fiber and combinations thereof.

13. The consumable filament of claim 11 , wherein the first base polymer and the second base polymer are the same.

14. The consumable filament of claim 11 , wherein the first base polymer and the second base polymer are different.

15. The consumable filament of claim 11 , wherein the filament has a cylindrical configuration.

16. The consumable filament of claim 11 , wherein the filament has a ribbon configuration.

17. The consumable filament of claim 11 , wherein the shell comprises carbon fiber particles, and wherein a concentration of the carbon fiber particles in the shell is less than a concentration of the carbon fiber particles in the core.

18. The consumable filament of claim 11 , wherein the core portion further comprises glass beads and/or glass fiber.

Assignees

• Stratasys Inc

Inventors

• Graley Christopher Scott
• Sumerel Christine Lawrence
• Orrock James E

Classifications

• Y10T428/2938

  Coating on discrete and individual rods, strands or filaments · CPC title

• B29C48/154

  Coating solid articles, i.e. non-hollow articles · CPC title

• D01F8/08

  with at least one polyacrylonitrile as constituent · CPC title

• B29L2009/00

  Layered products · CPC title

• B29C48/16

  Articles comprising two or more components, e.g. co-extruded layers · CPC title