Water-repellent substrate
US-11118085-B2 · Sep 14, 2021 · US
US11634608B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11634608-B2 |
| Application number | US-202117210340-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 23, 2021 |
| Priority date | Sep 23, 2016 |
| Publication date | Apr 25, 2023 |
| Grant date | Apr 25, 2023 |
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A compound represented by the following formula (1):wherein R1 is a monovalent organic group containing a polyether chain; X1 and X2 are each individually a monovalent group; and the polyether chain is a chain represented by the following formula: —(OC6F12)m11—(OC5F10)m12—(OC4F8)m13—(OC3X106)m14—(OC2F4)m15—(OCF2)m16—, wherein m11, m12, m13, m14, m15, and m16 are each individually an integer of 0 or 1 or greater; X10s are each individually H, F, or Cl; the repeating units are present in any order; and the sum of m11 to m16 is an integer of 10 or greater, R1 being other than those containing a urethane bond.
Opening claim text (preview).
The invention claimed is: 1. A compound represented by the following formula (1): wherein R 1 is a monovalent organic group containing a polyether chain; X 1 and X 2 are each individually a monovalent group; and the polyether chain is a chain represented by the following formula: —(OC 6 F 12 ) m11 —(OC 5 F 10 ) m12 —(OC 4 F 8 ) m13 —(OC 3 X 10 6 ) m14 —(OC 2 F 4 ) m15 —(OCF 2 ) m16 — wherein one of m11 or m12 is an integer of 1 or greater; and the other of m11 and m12, m13, m14, m15, and m16 are each individually an integer of 0 or 1 or greater; X 10 s are each individually H, F, or Cl; the repeating units are present in any order; and the sum of m11 to m16 is an integer of 10 or greater, R 1 being other than those containing a urethane bond. 2. The compound according to claim 1 , wherein at least one or both of X 1 and X 2 are each individually a monovalent organic group containing a polyether chain, and the polyether chain is a chain represented by the following formula: —(OC 6 F 12 ) m11 —(OC 5 F 10 ) m12 —(OC 4 F 8 ) m13 —(OC 3 X 10 6 ) m14 —(OC 2 F 4 ) m15 —(OCF 2 ) m16 — wherein m11, m12, m13, m14, m15, and m16 of the polyether chains of X 1 and X 2 are each individually an integer of 0 or 1 or greater; X 10 s are each individually H, F, or Cl; and the repeating units are present in any order. 3. The compound according to claim 1 , wherein X 1 is a monovalent crosslinkable group. 4. The compound according to claim 1 , wherein X 2 is a monovalent crosslinkable group. 5. The compound according to claim 1 , wherein X 1 and X 2 are each individually a monovalent crosslinkable group. 6. The compound according to claim 1 , wherein X 1 is a monovalent crosslinkable group containing a polyether chain, and the polyether chain is a chain represented by the following formula: —(OC 6 F 12 ) m11 —(OC 5 F 10 ) m12 —(OC 4 F 8 ) m13 —(OC 3 X 10 6 ) m14 —(OC 2 F 4 ) m15 —(OCF 2 ) m16 — wherein m11, m12, m13, m14, m15, and m16 of the polyether chain of X 1 are each individually an integer of 0 or 1 or greater; X 10 s are each individually H, F, or Cl; and the repeating units are present in any order. 7. The compound according to claim 1 , wherein X 2 is a monovalent crosslinkable group containing a polyether chain, and the polyether chain is a chain represented by the following formula: —(OC 6 F 12 ) m11 —(OC 5 F 10 ) m12 —(OC 4 F 8 ) m13 —(OC 3 X 10 6 ) m14 —(OC 2 F 4 ) m15 —(OCF 2 ) m16 — wherein m11, m12, m13, m14, m15, and m16 of the polyether chain of X 2 are each individually an integer of 0 or 1 or greater; X 10 s are each individually H, F, or Cl; and the repeating units are present in any order. 8. The compound according to claim 1 , wherein X 1 and X 2 are each individually a monovalent crosslinkable group containing a polyether chain, and the polyether chain is a chain represented by the following formula: —(OC 6 F 12 ) m11 —(OC 5 F 10 ) m12 —(OC 4 F 8 ) m13 —(OC 3 X 10 6 ) m14 —(OC 2 F 4 ) m15 —(OCF 2 ) m16 — wherein m11, m12, m13, m14, m15, and m16 of the polyether chains of X 1 and X 2 are each individually an integer of 0 or 1 or greater; X 10 s are each individually H, F, or Cl; and the repeating units are present in any order. 9. The compound according to claim 3 , wherein the crosslinkable group is at least one crosslinkable group selected from the group consisting of a monovalent Si-containing group, an acryloyl group, a methacryloyl group, an epoxy group, a glycidyl group, an oxetane group, an isocyanate group, a vinyl group, an allyl group, a vinyloxy group, a carboxyl group, a mercapto group, an amino group, a hydroxy group, a phosphonyl group, a cyclic acid anhydride group, a lactone group, a lactam group, a —OC(O)Cl group, a triazine group, an imidazole group, a conjugated olefin group, an acetylene group, a diazo group, an aldehyde group, a ketone group, an alkylboron group, an alkylaluminum group, an alkyltin group, an alkylgermanium group, an alkylzircon group, and a monovalent group containing any of these groups. 10. The compound according to claim 1 , wherein X 1 is at least one selected from the group consisting of H, an alkyl group, a halogenated alkyl group, an alkyl ester group, a halogenated alkyl ester group, an alkyl ether group, a halogenated alkyl ether group, an alkyl amide group, a halogenated alkyl amide group, a uril group, a halogenated uril group, a urea group, a halogenated urea group, —OCOOR j , wherein R j is an alkyl group or a halogenated alkyl group, —CONR k COR l , wherein R k and R l are each individually H, an alkyl group, or a halogenated alkyl group, a glycan-containing group, an alkylene polyether group, an arene group, a halogenated arene group, a heterocycle-containing group, an aryl group, a halogenated aryl group, a silicone residue other than those containing a reactive group, and a silsesquioxane residue other than those containing a reactive group. 11. The compound according to claim 1 , wherein X 2 is at least one selected from the group consisting of H, an alkyl group, a halogenated alkyl group, an alkyl ester group, a halogenated alkyl ester group, an alkyl ether group, a halogenated alkyl ether group, an alkyl amide group, a halogenated alkyl amide group, a uril group, a halogenated uril group, a urea group, a halogenated urea group, —OCOOR j , wherein R j is an alkyl group or a halogenated alkyl group, —CONR k COR l , wherein R k and R l are each individually H, an alkyl group, or a halogenated alkyl group, a glycan-containing group, an alkylene polyether group, an arene group, a halogenated arene group, a heterocycle-containing group, an aryl group, a halogenated aryl group, a silicone residue other than those containing a reactive group, and a silsesquioxane residue other than those containing a reactive group. 12. The compound according to claim 1 , wherein X 1 and X 2 are each individually at least one selected from the group consisting of H, an alkyl group, a halogenated alkyl group, an alkyl ester group, a halogenated alkyl ester group, an alkyl ether group, a halogenated alkyl ether group, an alkyl amide group, a halogenated alkyl amide group, a uril group, a halogenated uril group, a urea group, a halogenated urea group, —OCOOR j , wherein R j is an alkyl group or a halogenated alkyl group, —CONR k COR l , wherein R k and R l are each individually H, an alkyl group, or a halogenated alkyl group, a glycan-containing group, an alkylene polyether group, an arene group, a halogenated arene group, a heterocycle-containing group, an aryl group, a halogenated aryl group, a silicone residue other than those containing a reactive group, and a silsesquioxane residue other than those containing a reactive group.
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Compounds having Si-O-C linkages (Si-O-acyl linkages C07F7/1896) · CPC title
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having oxygen in addition to nitrogen · CPC title
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