Metal-ceramic composite powders

Patent metadata

Field	Value
Publication number	US-11633784-B2
Application number	US-202016901879-A
Country	US
Kind code	B2
Filing date	Jun 15, 2020
Priority date	Jun 13, 2019
Publication date	Apr 25, 2023
Grant date	Apr 25, 2023

Abstract

A process for manufacturing metal-ceramic composite material powder comprising ball milling metal powder and ceramic nanoparticles to yield a metal-ceramic composite powder comprising ceramic nanoparticles embedded in a metal matrix powder particles; wherein the ball milling is performed using a ceramic milling media and a milling vessel having a ceramic interior surface. Metal matrix nanocomposite powders comprising ceramic nanoparticles imbedded in metal matrix powder particles; wherein the metal matrix powder particles have a spherical shape; wherein there is uniform distribution the ceramic nanoparticles; wherein the nanocomposite powders have good flowability.

First claim

The invention claimed is:

1. A process for manufacturing metal-ceramic composite material powder comprising:
ball milling a starting metal powder and ceramic nanoparticles to yield a metal-ceramic composite powder comprising ceramic nanoparticles embedded in a metal matrix powder;
wherein the ball milling is performed using a ceramic milling media and a milling vessel having a ceramic interior surface; and
wherein one of the following conditions is met:
the ceramic nanoparticles comprise a titanium compound and the ceramic milling media and milling vessel interior surface also comprise a titanium compound;
the ceramic nanoparticles comprise a zirconium compound and the ceramic milling media and milling vessel interior surface also comprise a zirconium compound; or
the ceramic nanoparticles comprise a niobium compound and the ceramic milling media and milling vessel interior surface also comprise a niobium compound.

2. The process of claim 1 wherein the ceramic nanoparticles comprise a titanium compound and the ceramic milling media and milling vessel interior surface also comprise a titanium compound and the ceramic nanoparticles comprise a titanium compound which is different from the titanium compound of the ceramic milling media and milling vessel interior surface.

3. The process of claim 1 wherein the ceramic nanoparticles comprise a zirconium compound and the ceramic milling media and milling vessel interior surface also comprise a zirconium compound and the ceramic nanoparticles comprise a zirconium compound which is different from the zirconium compound of the ceramic milling media and milling vessel interior surface.

4. The process of claim 1 wherein the ceramic nanoparticles comprise a niobium compound and the ceramic milling media and milling vessel interior surface also comprise a niobium compound and the ceramic nanoparticles comprise a niobium compound which is different from the niobium compound of the ceramic milling media and milling vessel interior surface.

5. The process of claim 1 wherein the ceramic milling media are spherical and have a particle size which is between about 50000 and about 500000 times the particle size of the ceramic nanoparticles.

6. The process of claim 1 wherein the ceramic milling media are spherical and have a particle size which is between about 100000 and about 300000 times the particle size of the ceramic nanoparticles.

7. The process of claim 1 wherein the ceramic nanoparticles have a particle size of between about 10 and about 100 nm.

8. The process of claim 7 wherein the ceramic milling media has a particle size of between about 1 and about 10 mm.

9. The process of claim 8 , wherein the starting metal powder has a particle size between about 10 and about 100 μm.

10. The process of claim 1 further comprising subjecting the composite powders to plasma spheroidization.

11. The process of claim 1 wherein the ceramic milling media and milling vessel interior surface have a hardness which is the same as or greater than the hardness of the ceramic nanoparticles, and which is greater than a hardness of the metal matrix powder.

12. A process for manufacturing metal-ceramic composite material powder comprising:
ball milling a starting metal powder and ceramic nanoparticles to yield a metal-ceramic composite powder comprising ceramic nanoparticles embedded in a metal matrix powder;
wherein the ball milling is performed using a ceramic milling media and a milling vessel having a ceramic interior surface; and
wherein the starting metal powder is an aluminum alloy and the nanoparticles, milling media, and milling vessel interior surface are TiC.

13. The process of claim 12 wherein the ceramic milling media are spherical and have a particle size which is between about 50000 and about 500000 times the particle size of the ceramic nanoparticles.

14. The process of claim 12 wherein the ceramic milling media are spherical and have a particle size which is between about 100000 and about 300000 times the particle size of the ceramic nanoparticles.

15. The process of claim 12 wherein the ceramic nanoparticles have a particle size of between about 10 and about 100 nm.

16. The process of claim 15 wherein the ceramic milling media has a particle size of between about 1 and about 10 mm.

17. The process of claim 16 , wherein the starting metal powder has a particle size between about 10 and about 100 μm.

18. The process of claim 12 further comprising subjecting the composite powders to plasma spheroidization.

19. The process of claim 12 wherein the ceramic milling media and milling vessel interior surface have a hardness which is the same as or greater than the hardness of the ceramic nanoparticles, and which is greater than a hardness of the metal matrix powder.

Assignees

• Univ Missouri

Inventors

• Chen Lianyi
• Qu Minglei

Classifications

• B22F1/065

  Spherical particles · CPC title

• B22F9/04 Primary

  starting from solid material, e.g. by crushing, grinding or milling ({C22C1/1084 takes precedence}; crushing, grinding or milling, in general, see the relevant subclasses, e.g. B02C) · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• B22F2202/13

  Use of plasma · CPC title

• B22F2009/043

  by ball milling · CPC title