Hydride-coated microparticles and methods for making the same

Patent metadata

Field	Value
Publication number	US-10787728-B2
Application number	US-201816014014-A
Country	US
Kind code	B2
Filing date	Jun 21, 2018
Priority date	May 26, 2014
Publication date	Sep 29, 2020
Grant date	Sep 29, 2020

Abstract

A metal microparticle coated with metal hydride nanoparticles is disclosed. Some variations provide a material comprising a plurality of microparticles (1 micron to 1 millimeter) containing a metal or metal alloy and coated with a plurality of nanoparticles (less than 1 micron) containing a metal hydride or metal alloy hydride. The invention eliminates non-uniform distribution of sintering aids by attaching them directly to the surface of the microparticles. No method is previously known to exist which can assemble nanoparticle metal hydrides onto the surface of a metal microparticle. Some variations provide a solid article comprising a material with a metal or metal alloy microparticles coated with metal hydride or metal alloy hydride nanoparticles, wherein the nanoparticles form continuous or periodic inclusions at or near grain boundaries within the microparticles.

First claim

What is claimed is:

1. A material comprising a plurality of non-metallic microparticles that are at least partially coated with a plurality of nanoparticles containing a metal hydride or metal alloy hydride, wherein said microparticles are characterized by an average microparticle size from between 1 micron to about 1 millimeter, wherein said nanoparticles are characterized by an average nanoparticle size less than 1 micron, and wherein said nanoparticles are attached to said microparticles with organic ligands.

2. The material of claim 1 , wherein said material is in powder form.

3. The material of claim 1 , wherein said average microparticle size is between about 10 microns to about 500 microns.

4. The material of claim 1 , wherein said average nanoparticle size is between about 10 nanometers to about 500 nanometers.

5. The material of claim 1 , wherein said plurality of nanoparticles forms a single-layer or multiple-layer nanoparticle coating that is between about 5 nanometers to about 100 microns thick.

6. The material of claim 1 , wherein said non-metallic microparticles contain one or more materials selected from the group consisting of a glass, a ceramic, an organic structure, a composite, and a combination thereof.

7. The material of claim 1 , wherein said nanoparticles contain hydrogen and one or more metals selected from the group consisting of Li, Be, Na, Mg, K, Ca, Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, Fe, Ru, Os, Fe, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Al, Si, B, C, P, S, Ga, Ge, In, Sn, Sb, Pb, Bi, La, Ac, Ce, Th, Nd, U, and combinations or alloys thereof.

8. The material of claim 1 , wherein said organic ligands are selected from the group consisting of aldehydes, alkanes, alkenes, silicones, polyols, poly(acrylic acid), poly(quaternary ammonium salts), poly(alkyl amines), poly(alkyl carboxylic acids) including copolymers of maleic anhydride or itaconic acid, poly(ethylene imine), poly(propylene imine), poly(vinylimidazoline), poly(trialkylvinyl benzyl ammonium salt), poly(carboxymethylcellulose), poly(D- or L-lysine), poly(L-glutamic acid), poly(L-aspartic acid), poly(glutamic acid), heparin, dextran sulfate, 1-carrageenan, pentosan polysulfate, mannan sulfate, chondroitin sulfate, and combinations or derivatives thereof.

9. A material comprising a plurality of non-metallic microparticles that are at least partially coated with a plurality of nanoparticles containing a metal hydride or metal alloy hydride, wherein said microparticles are characterized by an average microparticle size from between 1 micron to about 1 millimeter, wherein said nanoparticles are characterized by an average nanoparticle size less than 1 micron, and wherein said plurality of nanoparticles forms a discontinuous nanoparticle coating that is between about 5 nanometers to about 100 microns thick.

10. The material of claim 9 , wherein said material is in powder form.

11. The material of claim 9 , wherein said average microparticle size is between about 10 microns to about 500 microns.

12. The material of claim 9 , wherein said average nanoparticle size is between about 10 nanometers to about 500 nanometers.

13. The material of claim 9 , wherein said plurality of nanoparticles forms a multiple-layer nanoparticle coating.

14. The material of claim 9 , wherein said non-metallic microparticles contain one or more materials selected from the group consisting of a glass, a ceramic, an organic structure, a composite, and a combination thereof.

15. The material of claim 9 , wherein said nanoparticles contain hydrogen and one or more metals selected from the group consisting of Li, Be, Na, Mg, K, Ca, Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, Fe, Ru, Os, Fe, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Al, Si, B, C, P, S, Ga, Ge, In, Sn, Sb, Pb, Bi, La, Ac, Ce, Th, Nd, U, and combinations or alloys thereof.

16. The material of claim 9 , wherein said nanoparticles are attached to said microparticles with organic ligands.

17. The material of claim 16 , wherein said organic ligands are selected from the group consisting of aldehydes, alkanes, alkenes, silicones, polyols, poly(acrylic acid), poly(quaternary ammonium salts), poly(alkyl amines), poly(alkyl carboxylic acids) including copolymers of maleic anhydride or itaconic acid, poly(ethylene imine), poly(propylene imine), poly(vinylimidazoline), poly(trialkylvinyl benzyl ammonium salt), poly(carboxymethylcellulose), poly(D- or L-lysine), poly(L-glutamic acid), poly(L-aspartic acid), poly(glutamic acid), heparin, dextran sulfate, 1-carrageenan, pentosan polysulfate, mannan sulfate, chondroitin sulfate, and combinations or derivatives thereof.

18. The material of claim 9 , wherein said nanoparticles are attached to said microparticles without organic ligands.

Assignees

• Hrl Lab Llc

Inventors

• Martin John H
• Schaedler Tobias A
• Gross Adam F
• Jacobsen Alan J

Classifications

• B22F1/05 Primary

  Metallic powder characterised by the size or surface area of the particles · CPC title

• B22F1/0549

  Hollow particles, including tubes and shells · CPC title

• B22F1/16

  Metallic particles coated with a non-metal (coated with lubricating or binding agents or with organic material B22F1/10) · CPC title

• B22F1/102

  Metallic powder coated with organic material · CPC title

• B22F1/056

  Submicron particles having a size above 100 nm up to 300 nm · CPC title