Method for preparing oxygen-free passivated titanium or titanium-alloy powder product by means of gas-solid fluidization

Patent metadata

Field	Value
Publication number	US-11612936-B2
Application number	US-202017275198-A
Country	US
Kind code	B2
Filing date	Mar 27, 2020
Priority date	Feb 24, 2020
Publication date	Mar 28, 2023
Grant date	Mar 28, 2023

Abstract

A method for preparing an oxygen-free passivated titanium or titanium-alloy powder product by means of gas-solid fluidization is provided. The new method includes placing the metal halide and the titanium powder which meet formula requirements into a gasifier and a fluidized bed reactor respectively; heating the gasifier to gasify the metal halide, and introducing dry argon and halide gas into the fluidized bed reactor; opening the fluidized bed, heating the fluidized bed, fluidizing the titanium powder after the introduction of the argon and the metal halide gas, and cooling the product to obtain the titanium powder subjected to oxygen-free passivation using metal chloride; molding the oxygen-free passivated titanium powder into a green body with powder metallurgy technology; and sintering the green body in vacuum or argon atmosphere according to the molding technology, and after temperature rise treatment, performing a densification sintering operation to obtain a high-performance titanium product component.

First claim

What is claimed is:

1. A method for preparing an oxygen-free passivated titanium or titanium-alloy powder product by means of gas-solid fluidization, comprising:
1) placing a metal halide and a titanium powder into a gasifier and a fluidized bed reactor respectively, wherein the titanium powder and the metal halide have a mass ratio of 80:20-98:2;
2) heating the gasifier to a first predetermined temperature to gasify the metal halide to obtain a metal halide gas, and introducing dry argon and the metal halide gas into the fluidized bed reactor in a volume ratio of 10:90-90:10 at a predetermined flow rate;
3) initiating the fluidized bed reactor, heating the fluidized bed reactor to a second predetermined temperature, fluidizing the titanium powder for 10-300 min after introducing the dry argon and the metal halide gas to obtain a product, and cooling the product to obtain a metal halide oxygen-free passivated titanium powder, wherein the second predetermined temperature is greater than the first predetermined temperature, and the titanium powder is fluidized by the fluidized bed reactor;
4) molding the metal halide oxygen-free passivated titanium powder obtained in step 3 into a green body with a powder metallurgy technology; and
5) sintering the green body obtained in step 4 in vacuum or an argon atmosphere according to a molding technology, and after a temperature rise treatment on the green body, performing a densification sintering operation on the green body with a sintering temperature of 1070-1400° C. and a heat preservation time of 0.5-5 h to finally obtain a titanium product component,
wherein the metal halide in step 1 is one selected from the group consisting of anhydrous SnF 4 , anhydrous SnBr 4 , and anhydrous SnI 4 ; and
no liquid medium or organic solvent is used while performing steps 1 to 3.

2. The method according to claim 1 , wherein the first predetermined temperature of the gasifier in step 2 is 50-400° C., and the predetermined flow rate is 100-300 ml/min.

3. The method according to claim 1 , wherein the second predetermined temperature of the fluidized bed reactor in step 3 is 100-500° C.

4. The method according to claim 1 , wherein the powder metallurgy technology in step 4 comprises a die forming technology, an isostatic pressing technology, a 3D printing technology, an injection forming technology, or a gel casting forming technology.

5. The method according to claim 1 , wherein the temperature rise treatment in step 5 comprises: raising to a third predetermined temperature from room temperature to 100-650° C. at a temperature raising rate of 0.5-3° C./min, and keeping the third temperature for 120-240 min.

Assignees

• Univ Beijing Science & Technology

Inventors

• Yang Fang
• Shao Yanru
• Zhou Yang
• Guo Zhimeng
• Sui Yanli
• Qin Qian
• Chen Cunguang

Classifications

• B33Y10/00 Primary

  Processes of additive manufacturing · CPC title

• B22F9/30 Primary

  with decomposition of metal compounds, e.g. by pyrolysis · CPC title

• B22F10/14

  by jetting of binder onto a bed of metal powder · CPC title

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• C23C16/08

  from metal halides · CPC title