Metal organic frameworks for gas storage
US-10870101-B2 · Dec 22, 2020 · US
US11607665B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11607665-B2 |
| Application number | US-202017001286-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 24, 2020 |
| Priority date | Aug 25, 2014 |
| Publication date | Mar 21, 2023 |
| Grant date | Mar 21, 2023 |
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Embodiments of the present disclose provide a method of sorbing one or more compounds from a fluid, wherein the method may include contacting a M-soc-MOF composition with a fluid containing at least H2S and one or more of CO2 and CH4; and sorbing at least H2S from the fluid. Embodiments of the present disclosure provide a membrane that may include a metal-organic framework (MOF) composition, wherein the MOF composition includes a M-soc-MOF composition, where M is a metal and soc is a square-octahedral topology, and wherein the M-soc-MOF composition is a continuous thin film on a support.
Opening claim text (preview).
What is claimed is: 1. A membrane comprising: a metal-organic framework (MOF) composition, wherein the MOF composition includes a M-soc-MOF composition, where M is a metal that includes Al +3 and soc is a square-octahedral topology, and wherein the M-soc-MOF composition is a continuous thin film on a support. 2. The membrane of claim 1 , wherein the metal of the M-soc-MOF composition includes In 3+ . 3. The membrane of claim 1 , wherein the metal of the M-soc-MOF composition includes Fe 3+ . 4. The membrane of claim 1 , wherein the metal of the M-soc-MOF composition includes Ga 3+ . 5. The membrane of claim 1 , wherein the M-soc-MOF includes 3,3′,5,5′-azobenzenetetracarboxylate (ABTC) as a ligand. 6. The membrane of claim 1 , wherein the M-soc-MOF composition includes an extra-framework counter-ion selected from the group consisting of NO 3− , Cl − , Br − , and OH − , or a combination thereof. 7. The membrane of claim 1 , wherein the M-soc-MOF composition includes Fe-soc-MOF. 8. The membrane of claim 1 , wherein the M-soc-MOF composition includes Ga-soc-MOF.
without C-Metal linkages · CPC title
Sulfur containing contaminants · CPC title
Carbon dioxide · CPC title
without C-aluminium linkages · CPC title
without a metal-carbon linkage · CPC title
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