Metal-organic frameworks (mof) for gas capture
US-2015047505-A1 · Feb 19, 2015 · US
US9102691B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9102691-B2 |
| Application number | US-201414555535-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 26, 2014 |
| Priority date | Nov 26, 2013 |
| Publication date | Aug 11, 2015 |
| Grant date | Aug 11, 2015 |
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The invention relates to monocrystalline single crystals of metal-organic framework materials comprising at least one aluminum metal ion, processes for preparing the same, methods for employing the same, and the use thereof. The invention also relates to monocrystalline aluminum metal-organic frameworks.
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The invention claimed is: 1. A single crystal metal-organic framework comprising one or more metal-ligand clusters, each metal-ligand cluster comprising (i) a metal cluster having an Al 3 O cornerstone, and (ii) one or more ligands having two or more carboxylate groups; wherein the single crystal has a size greater than or equal to 10 μm; the metal-organic framework comprises cavities having a free diameter of about 4 Å to about 40 Å; and the metal-organic framework comprising por…
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