Multilayer material

Patent metadata

Field	Value
Publication number	US-11578895-B2
Application number	US-201816493037-A
Country	US
Kind code	B2
Filing date	Mar 12, 2018
Priority date	Mar 13, 2017
Publication date	Feb 14, 2023
Grant date	Feb 14, 2023

Abstract

Thermoregulated multilayer material characterized in that it comprises at least one substrate and one thermoregulated layer, said thermoregulated multilayer material having: for λ radiation of between 0.25 and 2 μm, an absorption coefficient αm≥0.8; and, for incident λ radiation of between 7.5 and 10 μm, a reflection coefficient ρm: ρm≥0.85, when the temperature T of said multilayer material 1 is ≤100° C.; ρm between 0.3 and 0.85, when the temperature T of said multilayer material is between 0 and 400° C.

First claim

The invention claimed is:

1. A thermoregulated multilayer material comprising:
a support having
a transmission coefficient Γ s substantially equal to 0, for rays with a wavelength λ in a range of from 0.25 to 25 μm;
a reflection coefficient ρs>0.9, for incident rays with wavelength λ of between 7.5 and 10 μm;

a thermoregulated layer having a thickness in a range of from 50 to 500 nm and a base of rare earth perovskite cobaltites or rare earth perovskite nickelates or rare earth manganites, the thermoregulated layer topping one of the surfaces of the support;
wherein the thermoregulated material has:
for rays with wavelength λ of between 0.25 and 2.5 μm; an absorption coefficient αm>0.8; and
for incident rays with wavelength λ of between 7.5 and 10 μm; a reflection coefficient ρ m , wherein:
ρ m ≥0.85, when the temperature T of said multilayer material (M) is ≤100° C.;
0.3≤ρ m ≤0.85, when the temperature T of said multilayer material is in a range of from 100 to 400° C.

2. The thermoregulated multilayer material according to claim 1 , wherein the perovskites have formula:
ABO 3
wherein:
“A” is at least one single chemical element or a group of chemical elements belonging to the rare earths group;
“B” is either cobalt Co, or nickel Ni, or manganese Mn, and
“O 3 ” represents three oxygens.

3. The thermoregulated multilayer material according to claim 2 , wherein “A” corresponds to at least one chemical element belonging to the rare earths family and being selected from the group consisting of lanthanum La, praseodymium Pr, neodymium Nd, samarium Sm, gadolinium Gd, and europium Eu.

4. The thermoregulated multilayer material according to claim 3 , wherein the at least one chemical element “A” of the perovskite with formula ABO 3 is partially doped with at least one chemical element “E” of atomic fraction “z” in a range of from 0.1 to 0.6, the element “E” belonging to the alkaline-earth group and being selected from the group consisting of strontium Sr, calcium Ca, and barium Ba.

5. The thermoregulated multilayer material according claim 3 , wherein the element “B” of the perovskite with formula ABO 3 is partially doped with at least one chemical element “D” of atomic fraction “y” in a range of from 0.1 to 0.5, the element “D” belonging to the transition metals group and being selected from the group consisting of cobalt Co, nickel Ni, manganese Mn, iron Fe, titanium Ti, vanadium V, and chromium Cr.

6. The thermoregulated multilayer material according to claim 2 , wherein the at least one chemical element “A” of the perovskite with formula ABO 3 is partially doped with at least one chemical element “E” of atomic fraction “z” in a range of from 0.1 to 0.6, the element “E” belonging to the alkaline-earth group and being selected from the group consisting of strontium Sr, calcium Ca, and barium Ba.

7. The thermoregulated multilayer material according claim 6 , wherein the thermoregulated layer having formula ABO3, comprising at least one of these elements “A”, “B” or partially doped “O 3 ”, has:
a thickness of between 300 and 500 nm, and
for incident rays with wavelength λ in a range of from 7.5 to 10 μm, a transmission coefficient Γ T , wherein:
Γ T ≥0.95 for an internal temperature of the thermoregulated layer less than or equal to 100° C.;
Γ T ≤0.6 for an internal temperature of the thermoregulated layer in a range of from 100 to 200° C.

8. The thermoregulated multilayer material according to claim 6 , wherein the thermoregulated layer has formula A 1-z E z CoO 3 or A 1-z E z NiO 3 or A 1-z E z MnO 3 .

9. The thermoregulated multilayer material according claim 6 , wherein the element “B” of the perovskite with formula ABO 3 is partially doped with at least one chemical element “D” of atomic fraction “y” in a range of from 0.1 to 0.5, the element “D” belonging to the transition metals group and being selected from the group consisting of cobalt Co, nickel Ni, manganese Mn, iron Fe, titanium Ti, vanadium V, and chromium Cr.

10. The thermoregulated multilayer material according claim 2 , wherein the element “B” of the perovskite with formula ABO 3 is partially doped with at least one chemical element “D” of atomic fraction “y” in a range of from 0.1 to 0.5, the element “D” belonging to the transition metals group and being selected from the group consisting of cobalt Co, nickel Ni, manganese Mn, iron Fe, titanium Ti, vanadium V, and chromium Cr.

11. The thermoregulated multilayer material according to claim 10 , wherein the thermoregulated selective layer has formula ACO 1-y D y O 3 or ANi 1-y D y O 3 or AMn 1-y D y O 3 .

12. The thermoregulated multilayer material according to claim 2 , wherein the oxygens “O 3 ” of the perovskite with formula ABO 3 are partially doped with nitrogen N having atomic fraction “x” in a range of from 0.03 to 1.

13. The thermoregulated multilayer material according to claim 12 , wherein the thermoregulated layer has formula ACoO 3-x N x or ANiO 3-x N x or AMn 3-x N x .

14. The thermoregulated multilayer material according to claim 1 , wherein the support consists of a metal sheet having a base of aluminum Al or copper Cu.

15. The thermoregulated multilayer material according to claim 1 , wherein the thermoregulated layer is covered with an antiglare layer.

16. The thermoregulated multilayer material according to claim 1 , further comprising a barrier layer able to prevent the diffusion in solid state of chemical elements of the support toward the thermoregulated layer, the barrier layer being positioned between the support and the thermoregulated layer.

17. The thermoregulated multilayer material according to claim 1 , having:
for rays having a wavelength λ in a range of from 0.25 to 2.5 μm, an absorption coefficient αm≥0.94; and
for incident rays having a wavelength λ in a range of from 7.5 to 10 μm, a reflection coefficient ρ m , wherein:
ρ m ≥0.92, when the temperature T of the multilayer material is ≤100° C.;
ρ m ≤0.6, when the temperature of the multilayer material is ≥100° C.

18. A method for manufacturing a thermoregulated multilayer material, comprising:
depositing a thermoregulated layer having general formula ABO 3 on a support by vacuum co-sputtering, in the presence of a reactive plasma of argon and oxygen or of pure argon, wherein “A” is at least one single chemical element or a group of chemical elements belonging to the rare earths group and “B” is a transition metal of type Ni, Mn or Co,
annealing the material previously obtained ex situ at temperatures in a range of from 525 to 800° C. for a duration of from 30 seconds to 1 hour,
so as to obtain the thermoregulated multilayer ma al according to claim 1 .

19. The method according to claim 18 , wherein the material previously obtained is annealed ex situ at temperatures in a range of from 575 and 600° C. for a duration of from 30 seconds to 240 seconds.

20. A solar panel comprising a thermoregulated multilayer material according to claim 1 .

Assignees

• Viessmann Faulquemont
• Centre Nat Rech Scient
• Univ De Lorraine

Inventors

• Mercs David
• Capon Fabien
• Portha Nicolas
• Boileau Alexis

Classifications

• C23C14/3464

  using more than one target (C23C14/56 takes precedence) · CPC title

• F24S70/20 Primary

  characterised by absorbing coatings; characterised by surface treatment for increasing absorption · CPC title

• F24S70/30

  Auxiliary coatings, e.g. anti-reflective coatings · CPC title

• Y02B10/20

  Solar thermal · CPC title

• C23C14/5806

  Thermal treatment · CPC title