Gas supply method and gas sampler

Patent metadata

Field	Value
Publication number	US-11566976-B2
Application number	US-202016913357-A
Country	US
Kind code	B2
Filing date	Jun 26, 2020
Priority date	Sep 24, 2019
Publication date	Jan 31, 2023
Grant date	Jan 31, 2023

Abstract

A gas sampler includes a connection portion connectable to an introduction piping connected to a sample tank, a switching valve for switching a connection state between the connection portion and a sample loop, a pump, and a control device. A buffer flow path between the sample loop and the pump is configured to be selectively connectable to any one of a plurality of buffer tanks different in volume. A volume of the buffer flow path is greater than a volume of the introduction piping by a predetermined amount. The control device operates the pump in a state in which the switching valve is in a closed state to set an inside of the buffer flow path to a negative pressure, and thereafter stops the pump and make the switching valve in an open state to fill the sample loop with a sample gas by using the negative pressure of the buffer flow path.

First claim

The invention claimed is:

1. A gas supply method for supplying a sample gas to a column of a gas analyzer by using a gas sampler, the gas sampler including a connection portion connectable, via an introduction flow path, to a sample tank filled with the sample gas, a sample holding portion arranged to accommodate the sample gas introduced from the sample tank to the connection portion, a switching valve configured to change a connection between the connection portion and the sample holding portion, and a suction pump connected to the sample holding portion via a buffer flow path, wherein a volume of the buffer flow path is greater than a volume of the introduction flow path, the gas supply method comprising:
adjusting a pressure of an inside of the buffer flow path to a negative pressure by operating the suction pump in a state in which the switching valve is in a closed state; and
introducing the sample gas from the sample tank to the sample holding portion via the connection portion by opening the switching valve with the suction pump being stopped, after the adjusting of the pressure.

2. The gas supply method as recited in claim 1 ,
wherein the buffer flow path is configured to be selectively connectable to any one of a plurality of buffer tanks different in volume, and
wherein the gas supply method further comprises the step of:
selecting a buffer tank to be connected to the buffer flow path from the plurality of buffer tanks according to the volume of the introduction flow path to be connected to the connection portion such that the volume of the buffer flow path becomes greater than the volume of the introduction flow path by a predetermined amount, before the adjusting of the pressure of the inside of the buffer flow path.

3. The gas supply method as recited in claim 2 , further comprising the step of:
supplying the sample gas in the sample holding portion to the column, after the introducing of the sample gas.

4. A gas sampler for supplying a sample gas to a column of a gas analyzer, comprising:
a connection portion connectable, via an introduction flow path, to a sample tank filled with the sample gas;
a sample holding portion configured to hold the sample gas introduced to the connection portion from the sample tank;
a switching valve configured to switch a connection state between the connection portion and the sample holding portion;
a suction pump connected to the sample holding portion via a buffer flow path; and
a control device configured to control the suction pump and the switching valve,
wherein a volume of the buffer flow path is greater than a volume of the introduction flow path connecting between the sample tank and the connection portion,
wherein the buffer flow path is configured to be selectively connectable to any one of a plurality of buffer tanks different in volume, and
wherein the control device executes
negative pressure processing by operating the suction pump to set an inside of the buffer flow path to a negative pressure in a state in which the switching valve is in a closed state, and
introduction processing for introducing the sample gas from the sample tank to the sample holding portion via the connection portion by making the switching valve in an open state in a state in which the suction pump is stopped, after executing the negative pressure processing.

5. The gas sampler as recited in claim 4 ,
wherein the control device executes selection processing for selecting a buffer tank to be connected to the buffer flow path from the plurality of buffer tanks according to the volume of the introduction flow path to be connected to the connection portion such that the volume of the buffer flow path becomes greater than the volume of the introduction flow path by a predetermined amount, before executing the negative pressure processing.

6. The gas sampler as recited in claim 4 ,
wherein the control device executes supply processing for supplying the sample gas in the sample holding portion to the column, after executing the introduction processing.

7. A gas sampler for supplying a sample gas to a column of a gas analyzer, comprising:
a connection portion connectable, via an introduction flow path, to a sample tank filled with the sample gas;
a sample holding portion configured to hold the sample gas introduced to the connection portion from the sample tank;
a switching valve configured to switch a connection state between the connection portion and the sample holding portion; and
a suction pump connected to the sample holding portion via a buffer flow path,
wherein a volume of the buffer flow path is greater than a volume of the introduction flow path connecting between the sample tank and the connection portion, and
wherein the buffer flow path is configured to be selectively connectable to any one of a plurality of buffer tanks different in volume.

Assignees

• Shimadzu Corp

Inventors

• Shibamoto Shigeaki
• Lu Wenjian
• Sato Ayaka

Classifications

• G01N2030/025

  Gas chromatography · CPC title

• G01N1/2226 Primary

  Sampling from a closed space, e.g. food package, head space · CPC title

• G01N30/32

  of pressure or speed (G01N30/36 takes precedence) · CPC title

• G01N2030/324

  speed, flow rate · CPC title

• G01N30/20 Primary

  using a sampling valve · CPC title