Damping thermoplastic olefin elastomers

Patent metadata

Field	Value
Publication number	US-11566122-B2
Application number	US-201816760982-A
Country	US
Kind code	B2
Filing date	Nov 1, 2018
Priority date	Nov 1, 2017
Publication date	Jan 31, 2023
Grant date	Jan 31, 2023

Abstract

A thermoplastic elastomer compound includes polyolefin elastomer, high softening point tackifier, and, optionally, styrenic block copolymer. When styrenic block copolymer is present, the weight ratio of polyolefin elastomer to styrenic block copolymer is no less than about 1:1. The polyolefin elastomer has a POE Tan Delta Peak Temperature, the styrenic block copolymer has a SBC Tan Delta Peak Temperature, and the thermoplastic elastomer compound has a Compound Tan Delta Peak Temperature. The Compound Tan Delta Peak Temperature is greater than the POE Tan Delta Peak Temperature. When styrenic block copolymer is present, Compound Tan Delta Peak Temperature is also greater than the SBC Tan Delta Peak Temperature. The thermoplastic elastomer compound exhibits useful damping properties at or above room temperature and can be formed into plastic articles, including foamed plastic articles and/or crosslinked plastic articles, which can be useful for a variety of damping applications.

First claim

What is claimed is:

1. A thermoplastic elastomer compound comprising:
(a) polyolefin elastomer having a POE Tan Delta Peak Temperature;
(b) tackifier having a softening point of at least about 80° C. according to ASTM 6493; and
(c) optionally, styrenic block copolymer having a SBC Tan Delta Peak Temperature, provided that, when the styrenic block copolymer is present, the polyolefin elastomer is present relative to the styrenic block copolymer at a weight ratio of no less than about 1:1;
wherein the compound has a Compound Tan Delta Peak Temperature, and the Compound Tan Delta Peak Temperature is greater than the POE Tan Delta Peak Temperature;
wherein, when the styrenic block copolymer is present, the Compound Tan Delta Peak Temperature is greater than the SBC Tan Delta Peak Temperature; and
wherein the thermoplastic elastomer compound is a non-adhesive thermoplastic elastomer compound.

2. The compound of claim 1 , wherein the styrenic block copolymer is present, and wherein the weight ratio of polyolefin elastomer to styrenic block copolymer is no less than about 3:1.

3. The compound of claim 1 , wherein the styrenic block copolymer is present, and wherein the weight ratio of polyolefin elastomer to styrenic block copolymer is no less than about 8:1.

4. The compound of claim 1 , wherein the styrenic block copolymer is selected from the group consisting of styrene-ethylene/butylene-styrene (SEBS) block copolymer, styrene-ethylene/propylene-styrene (SEPS) block copolymer, styrene-ethylene/ethylene/propylene-styrene (SEEPS) block copolymer, styrene-isobutylene-styrene (SIBS) block copolymer, styrene-butadiene-styrene (SBS) block copolymer, styrene-isoprene-styrene (SIS) block copolymer, and combinations thereof.

5. The compound of claim 1 , wherein the compound includes the styrenic block copolymer, and the styrenic block copolymer consists of styrene-ethylene-ethylene/propylene-styrene (SEEPS) block copolymer.

6. The compound of claim 1 , wherein the compound is free of styrenic block copolymer.

7. The compound of claim 1 , wherein the polyolefin elastomer is selected from the group consisting of propylene-based elastomers, ethylene/α-olefin random copolymers, ethylene/α-olefin block copolymers, ethylene-vinyl acetate copolymers, and combinations thereof.

8. The compound of claim 1 , wherein the polyolefin elastomer is propylene-based elastomer comprising (a) at least about 60 weight percent of propylene-derived units, (b) at least about 6 weight percent of ethylene-derived units, and (c) from about 0.3 to about 10 weight percent of diene-derived units, based on a combined weight of the propylene-derived units, the ethylene-derived units, and the diene-derived units.

9. The compound of claim 1 , wherein the POE Tan Delta Peak Temperature is from about −65° C. to about −20° C.

10. The compound of claim 1 , wherein the Compound Tan Delta Peak Temperature is at least 3° C.

11. The compound of claim 1 , wherein the tackifier has a softening point ranging from about 80° C. to about 150° C. according to ASTM 6493.

12. The compound of claim 1 , wherein the tackifier has a weight average molecular weight ranging from about 400 to about 3,500.

13. The compound of claim 1 , wherein the tackifier comprises a saturated cyclo-aliphatic amorphous hydrocarbon resin.

14. The compound of claim 1 , wherein a weight ratio of the polyolefin elastomer relative to the tackifier is from about 1:1 to about 3:1.

15. The compound of claim 1 , wherein the compound further comprises non-elastomeric thermoplastic polymer.

16. The compound of claim 1 , wherein the compound further comprises at least one additive selected from the group consisting of antioxidants and stabilizers; blowing and foaming agents; colorants; crosslinking agents; fillers; flame retardants and smoke suppressants; impact modifiers; plasticizers; ultraviolet light absorbers; waxes; and combinations thereof.

17. A plastic article formed from the compound of claim 1 .

18. The plastic article of claim 17 , wherein the plastic article is foamed.

19. The plastic article of claim 17 , wherein the plastic article is at least partially crosslinked.

20. A method of making a plastic article, the method comprising the steps of:
(a) providing the compound of claim 1 ; and
(b) forming the compound into the plastic article.

21. The compound of claim 10 , wherein the Compound Tan Delta Peak Temperature is in the range of 5° C. to 50° C.

22. The compound of claim 1 , wherein the polyolefin elastomer is selected from ethylene/α-olefin random copolymers, ethylene/α-olefin block copolymers, ethylene-vinyl acetate copolymers, and combinations thereof.

Assignees

• Polyone Corp
• Avient Corp

Inventors

• Gu Jiren

Classifications

• C08L23/12 Primary

  Polypropene · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08J2431/04

  Homopolymers or copolymers of vinyl acetate · CPC title

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C08J2423/12

  Polypropene · CPC title