Reactive matrix infiltration of powder preforms

Patent metadata

Field	Value
Publication number	US-11565318-B2
Application number	US-202017011316-A
Country	US
Kind code	B2
Filing date	Sep 3, 2020
Priority date	Sep 3, 2019
Publication date	Jan 31, 2023
Grant date	Jan 31, 2023

Abstract

A reactive matrix infiltration process is described herein, which includes contacting a surface of a preform comprising reinforcement material particles with a molten infiltrant comprising a matrix material, the matrix material comprising an Al—Ce alloy, whereby the infiltrant at least partially fills spaces between the reinforcement material particles by capillary action and reacts with the reinforcement material particles to form a composite material form, the composite material comprising the matrix material, at least one intermetallic phase, and, optionally, reinforcement material particles. A composite material form also is described, which includes a plurality of reinforcement material particles comprising a metal alloy or a ceramic, a matrix material at least partially filling spaces between the reinforcement material particles; and at least one intermetallic phase surrounding at least some of the reinforcement material particles. The reinforcement material particles and intermetallic phase together may form a gradient core-shell structure.

First claim

We claim:

1. A composite material form, comprising:
a plurality of reinforcement material powder particles comprising a metal alloy or a ceramic, the reinforcement material powder particles having an aspect ratio of from 1 to 2;
a matrix material at least partially filling spaces between the reinforcement material powder particles, the matrix material comprising Al and Ce; and
at least one intermetallic phase surrounding one or more of the reinforcement material powder particles, the intermetallic phase including one or more elements of the reinforcement material powder particles, Al, and Ce, and wherein, the reinforcement material powder particle is ceramic, an average diameter of the ceramic reinforcement material powder particles is within a rnage of from 65 μm to 250 μm.

2. The composite material form of claim 1 , wherein the reinforcement material comprises a Ti-Al-V alloy.

3. The composite material form of claim 1 , wherein the reinforcement material comprises a first metal M1, and the reinforcement material powder particles and the intermetallic phase together comprise a gradient core-shell structure comprising:
a gradient core comprising M1, Al, and Ce, and a plurality of intermetallic phases, the gradient core having a compositional gradient with a first average M1 concentration and a first average Ce concentration at a first average distance from a center of the gradient core, a second average M1 concentration and a second average Ce concentration at a second, further average distance from the center, wherein the second average M1 concentration is less than the first average M1 concentration; and
a shell surrounding the gradient core, the shell comprising an average Ce concentration at least 5 -fold greater than the second average Ce concentration.

4. The composite material form of claim 3 , wherein M1 comprises Ti.

5. The composite material form of claim 1 , wherein the reinforcement material powder particles are spherical.

6. A composite material form, comprising:
a plurality of spherical reinforcement material powder particles comprising a metal alloy or a ceramic;
a matrix material at least partially filling spaces between the spherical reinforcement material powder particles, the matrix material comprising Al and Ce; and
at least one intermetallic phase surrounding one or more of the spherical reinforcement material powder particles, the intermetallic phase including one or more elements of the spherical reinforcement material powder particles, Al, and Ce.

7. A method, comprising:
contacting a surface of a preform comprising a plurality of reinforcement material powder particles having an initial average diameter and an aspect ratio of from 1 to 2 with a molten infiltrant at a temperature T 1 , wherein T 1 is greater than a melting point of the molten infiltrant and less than a melting point of the reinforcement material powder particles, the molten infiltrant comprising an aluminum-cerium (Al-Ce) alloy and the reinforcement material powder particles comprising a metal alloy or a ceramic, whereby the molten infiltrant at least partially fills spaces between the reinforcement material powder particles by capillary action and reacts with the reinforcement material powder particles to form a composite material form, the composite material form comprising a matrix material comprising the Al-Ce alloy and at least one intermetallic phase comprising at least one element of the reinforcement material powder particles, Al, and Ce, the matrix material at least partially filling the spaces between the reinforcement material powder particles and the at least one intermetallic phase surrounding one or more of the reinforcement material powder particles; and
cooling the composite material form to a temperature T 2 less than a melting point of the molten infiltrant, and wherein, when the reinforcement material powder particle is ceramic, an average diameter of the ceramic reinforcement material powder particles is within a range of from 65 μm to 250 μm.

8. The method of claim 7 , wherein the composite material form further comprises reinforcement material powder particles having a final average diameter, wherein the final average diameter is less than the initial average diameter.

9. The method of claim 7 , wherein the preform is maintained at a temperature greater than the melting point of the molten infiltrant while contacting the surface of the preform with the molten infiltrant.

10. The method of claim 7 , wherein the preform is a bonded powder preform comprising the reinforcement material powder particles and a binder, the method further comprising:
heating the bonded powder preform to a temperature T 3 , wherein T 3 is effective to decompose the binder and T 3 is less than a melting point of the reinforcement material powder particles and less than a melting point of the molten infiltrant, thereby decomposing the binder and producing the preform, the preform having spaces between the reinforcement material powder particles; and
subsequently contacting the surface of the preform with molten infiltrant at the temperature T 1 .

11. The method of claim 10 , further comprising forming the preform using binder jet technology.

12. The method of claim 7 , wherein contacting the surface of the preform with the molten infiltrant comprises dipping the surface of the preform into the molten infiltrant.

13. The method of claim 7 , further comprising subsequently heating the composite material form to a temperature T 4 , whereby the matrix material reacts further with the reinforcement material powder particles to form additional intermetallic.

14. The method of claim 7 , wherein the Al-Ce alloy comprises from 5 wt % to 20 wt % Ce with the balance being Al.

15. The method of claim 7 , wherein the reinforcement material powder particles constitute 50% (v/v) of the preform.

16. The method of claim 1 , wherein when the reinforcement material powder particle is metal alloy, an average diameter of the metal alloy reinforcement material powder particles is within a range of from 20 μm to 250 μm.

17. The method of claim 7 , wherein the reinforcement material powder particles comprise a first metal M1, and the composite material form comprises one or more gradient core-shell structures, the gradient core-shell structure comprising:
a gradient core comprising M1, Al, and Ce, and a plurality of intermetallic phases, the gradient core having a compositional gradient with a first average M1 concentration and a first average Ce concentration at a first average distance from a center of the gradient core, a second average M1 concentration and a second average Ce concentration at a second, further average distance from the center, wherein the second average M1 concentration is less than the first average M1 concentration; and
a shell surrounding the gradient core, the shell comprising an average Ce concentration at least 5-fold greater than the second average Ce concentration.

18. The method of claim 7 , wherein the reinforcement material powder particles comprise a metal alloy.

19. The method of claim 18 , wherein the metal alloy comprises a titanium alloy, a nickel alloy, a copper alloy, an iron alloy, steel, an aluminum alloy, a high-entropy alloy, or any combination thereof.

20. The method of claim 19 , wherein the metal alloy is a Ti-Al-V alloy.

21. A method, comprising:
contacting a binder jet preform comprising a plurality of reinforcement material powder particles and a binder with an infiltrant compr

Assignees

• Rios Orlando
• Bridges Craig A
• Elliott Amelia M
• Henderson Hunter B
• Kesler Michael S
• Sims Zachary
• Weiss David
• Ut Battelle Llc
• Univ Tennessee Res Found
• Eck Ind Incorporated

Inventors

• Rios Orlando
• Bridges Craig A
• Elliott Amelia M
• Henderson Hunter B
• Kesler Michael S
• Sims Zachary
• Weiss David

Classifications

• B22F2301/205

  Titanium, zirconium or hafnium · CPC title

• C22C21/00 Primary

  Alloys based on aluminium · CPC title

• B22F3/26

  Impregnating {(making ferrous alloys by impregnation C22C33/0242)} · CPC title

• B22F7/08 Primary

  with one or more parts not made from powder {(B22F7/062 takes precedence)} · CPC title

• C22C14/00

  Alloys based on titanium · CPC title