Additive manufacturing methods using aluminum-rare earth alloys and products made using such methods

Patent metadata

Field	Value
Publication number	US-10760148-B2
Application number	US-201715650664-A
Country	US
Kind code	B2
Filing date	Jul 14, 2017
Priority date	Sep 19, 2016
Publication date	Sep 1, 2020
Grant date	Sep 1, 2020

Abstract

Described herein are additive manufacturing methods and products made using such methods. The alloy compositions described herein are specifically selected for the additive manufacturing methods and provide products that exhibit superior mechanical properties as compared to their cast counterparts. Using the compositions and methods described herein, products that do not exhibit substantial coarsening, such as at elevated temperatures, can be obtained. The products further exhibit uniform microstructures along the print axis, thus contributing to improved strength and performance. Additives also can be used in the alloys described herein.

First claim

We claim:

1. An alloy product, comprising one or more shaped alloy layers formed about a print axis, wherein the one or more shaped alloy layers includes an alloy comprising:
4 wt % to 60 wt % Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or any combination thereof;
5 wt % to 15 wt % Mg;
0 wt % to 12 wt % Si;
0 wt % to 6 wt % Fe;
0 wt % to 5 wt % Ni;
0 wt % to 6 wt % Zn; and
a balance of aluminum; and

wherein Vickers hardness of the alloy product changes by less than 20% when exposed to a 400° C. environment for 24 hours, wherein the Vickers hardness is measured by ASTM method E384.

2. The alloy product of claim 1 , wherein the alloy comprises 4 wt % to 20 wt % Ce, La, or any combination thereof.

3. The alloy product of claim 1 , wherein the alloy comprises 8 wt % to 16 wt % Ce, La, or any combination thereof.

4. The alloy product of claim 1 , wherein the alloy product has at least substantially uniform bulk mechanical properties.

5. The alloy product of claim 1 , wherein the alloy product comprises a eutectic microstructural constituent that does not exhibit substantial coarsening such that an increase in average spacing of lamellae and/or particles within a microstructure of the shaped alloy layers does not occur after being exposed to a post-additive manufacturing process utilizing processing temperatures of 150° C. to 500° C. for 1500 hours.

6. The alloy product of claim 1 , wherein 40% to 100% by volume of the alloy product comprises a eutectic structure, a semi-eutectic structure, or a combination thereof.

7. An alloy product, comprising one or more shaped alloy layers formed about a print axis, wherein the one or more shaped alloy layers includes an alloy comprising:
4 wt % to 60 wt % Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or any combination thereof;
5 wt % to 15 wt % Mg;
0 wt % to 12 wt % Si;
0 wt % to 6 wt % Fe;
0 wt % to 5 wt % Ni;
0 wt % to 6 wt % Zn; and
a balance of aluminum; and

wherein the alloy product further comprises one or more additional shaped alloy layers made of an alloy that does not comprise aluminum and/or a rare earth component selected from Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or any combination thereof.

8. The alloy product of claim 1 , wherein the one or more shaped alloy layers do not exhibit substantial coarsening such that an increase in average spacing of lamellae and/or particles within a microstructure of the shaped alloy layers does not occur over 24 hours at 300° C.

9. An alloy product, comprising one or more shaped alloy layers formed about a print axis, wherein the one or more shaped alloy layers includes an alloy comprising:
4 wt% to 60 wt % Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or any combination thereof;
2 wt % to 15 wt % Mg;
0 wt % to 12 wt % Si;
0 wt % to 6 wt % Fe;
0 wt % to 5 wt % Ni;
0 wt % to 6 wt % Zn; and
a balance of aluminum;

wherein the alloy product has a Vickers hardness that changes by less than 20% when the alloy product is exposed to a 400° C. environment for 24 hours, wherein the Vickers hardness is measured by ASTM method E384.

10. The alloy product of claim 1 , wherein the alloy product comprises a microstructure containing an Al 11 X 3 intermetallic particle having a particle size ranging from 250 nm to 2 microns.

11. The alloy product of claim 7 , wherein the alloy comprises 4 wt % to 20 wt % Ce, La, or any combination thereof.

12. The alloy product of claim 7 , wherein the alloy comprises 8 wt % to 16 wt % Ce, La, or any combination thereof.

13. The alloy product of claim 9 , wherein the alloy comprises 4 wt % to 20 wt % Ce, La, or any combination thereof.

14. The alloy product of claim 9 , wherein the alloy comprises 8 wt % to 16 wt % Ce, La, or any combination thereof.

15. The alloy product of claim 9 , wherein the alloy product has at least substantially uniform bulk mechanical properties.

16. The alloy product of claim 9 , wherein the alloy product comprises a eutectic microstructural constituent that does not exhibit substantial coarsening such that an increase in average spacing of lamellae and/or particles within a microstructure of the shaped alloy layers does not occur after being exposed to a post-additive manufacturing process utilizing processing temperatures of 150° C. to 500° C. for 1500 hours.

17. The alloy product of claim 9 , wherein 40% to 100% by volume of the alloy product comprises a eutectic structure, a semi-eutectic structure, or a combination thereof.

Assignees

• Ut Battelle Llc
• Univ Tennessee Res Found
• Univ Iowa State Res Found Inc
• Eck Ind Incorporated

Inventors

• Plotkowski Alex J
• Rios Orlando
• Babu Sudarsanam Suresh
• Dehoff Ryan R
• Ott Ryan
• Sims Zachary C
• Sridharan Niyanth
• Weiss David
• Henderson Hunter B

Classifications

• C22C23/06 Primary

  with a rare earth metal as the next major constituent · CPC title

• B22F10/22

  Direct deposition of molten metal · CPC title

• Y02P10/25

  Process efficiency · CPC title

• C22C21/16

  with magnesium · CPC title

• B22F10/00

  Additive manufacturing of workpieces or articles from metallic powder (apparatus or devices therefor B22F12/00) · CPC title