Contact between interconnect and electrode

Patent metadata

Field	Value
Publication number	US-11552306-B2
Application number	US-202117338925-A
Country	US
Kind code	B2
Filing date	Jun 4, 2021
Priority date	Dec 16, 2016
Publication date	Jan 10, 2023
Grant date	Jan 10, 2023

Abstract

Improved contact between interconnect and oxygen electrode material is achieved through a contact point between an electrode or a contact layer and a coated ferritic stainless steel interconnect, where the coating on the metallic interconnect comprises Cu.

First claim

The invention claimed is:

1. A method for creating a contact point between a coating on an interconnect and an electrode or contact layer, comprising the steps of:
providing a ferritic stainless steel interconnect substrate,
depositing at least one layer of Co or Ni on the interconnect substrate;
coating the layer of Co or Ni on the interconnect substrate with a coating comprising Cu having a thickness of approximately 100-200 nm, and
sintering the coated interconnect substrate and the electrode or contact layer by heat treatment in air at a temperature exceeding 800° C.,
where the Cu in the coating functions as a sintering aid towards the electrode or contact layer material, and a fraction of the Cu in the coating diffuses into the electrode or contact layer, thereby increasing the adhesion strength and lowering the electrical resistance of the contact point between the coated interconnect substrate and the electrode or contact layer.

2. The method of claim 1 , wherein the contact point is created between the coating of the interconnect and the electrode of a solid oxide fuel cell.

3. The method of claim 1 , wherein the contact point is created between the coating of the interconnect and an oxygen contact layer of a solid oxide fuel cell.

4. The method of claim 1 , wherein the coating on the interconnect comprises an oxide of Cu and Fe, an oxide of Cu and Ni, an oxide of Cu and Cu, or an oxide of Cu, Co and Ni, or an oxide of Cu, Co, Ni and Fe.

5. The method of claim 1 , wherein the electrode or contact layer material comprises a perovskite, a double perovskite, or a Ruddlesden-Popper phase material.

6. The method of claim 2 , wherein the adhesion strength of the contact point is of the same order of magnitude as the adhesion strength between an electrolyte and a barrier layer of the solid oxide fuel cell.

7. The method of claim 2 , wherein the operating temperature of the solid oxide fuel cell is between 500° C. and 900° C.

8. A solid oxide fuel cell stack including a contact point between a coating on an interconnect and an electrode or contact layer of a solid oxide fuel cell of the stack, wherein the contact point is created by a method comprising the steps of:
providing a ferritic stainless steel interconnect substrate,
depositing at least one layer of Co or Ni on the interconnect substrate;
coating the layer of Co or Ni on the interconnect substrate with a coating comprising Cu having a thickness of approximately 100-200 nm, and
sintering the coated interconnect substrate and the electrode or contact layer of the solid oxide fuel cell by heat treatment in air at a temperature exceeding 800° C.,
where the Cu in the coating functions as a sintering aid towards the electrode or contact layer material of the solid oxide fuel cell, and a fraction of the Cu in the coating diffuses into the electrode or contact layer of the solid oxide fuel cell, thereby increasing the adhesion strength and lowering the electrical resistance of the contact point between the coated interconnect substrate and the electrode or contact layer of the solid oxide fuel cell.

9. The solid oxide fuel cell stack of claim 8 , wherein the coating on the interconnect comprises an oxide of Cu and Fe, an oxide of Cu and Ni, an oxide of Cu and Cu, or an oxide of Cu, Co and Ni, or an oxide of Cu, Co, Ni and Fe.

10. The solid oxide fuel cell stack of claim 8 , wherein the electrode or contact layer material of the solid oxide fuel cell comprises a perovskite, a double perovskite, or a Ruddlesden-Popper phase material.

11. The solid oxide fuel cell stack of claim 8 , wherein the adhesion strength of the contact point is of the same order of magnitude as the adhesion strength between an electrolyte and a barrier layer of the solid oxide fuel cell.

12. The solid oxide fuel cell stack of claim 8 , wherein the operating temperature of the solid oxide fuel cell is between 500° C. and 900° C.

Assignees

• Haldor Topsoe As
• Topsoe As

Inventors

• Holt Nørby Tobias
• Blennow Bengt Peter Gustav
• Küngas Rainer
• Rass-Hansen Jeppe
• Heiredal-Clausen Thomas

Classifications

• H01M8/0228 Primary

  in the form of layered or coated products · CPC title

• H01M8/021 Primary

  Alloys based on iron · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/0215

  Glass; Ceramic materials · CPC title

• H01M8/0217

  Complex oxides, optionally doped, of the type AMO3, A being an alkaline earth metal or rare earth metal and M being a metal, e.g. perovskites · CPC title