Method of decomposing by-product in phenol preparation process

Patent metadata

Field	Value
Publication number	US-11547951-B2
Application number	US-202117511310-A
Country	US
Kind code	B2
Filing date	Oct 26, 2021
Priority date	Nov 20, 2017
Publication date	Jan 10, 2023
Grant date	Jan 10, 2023

Abstract

A method of decomposing a phenol by-product produced in a phenol preparation process, in which acetophenone separated from a distillation column is mixed with tar separated and collected in a decomposition reactor, thereby significantly decreasing viscosity of tar. The decomposition method according to the present invention allows tar to have sufficient viscosity for flowability even at room temperature, whereby transfer and storage of tar may be more smoothly done without using any heating device for transfer of tar.

First claim

The invention claimed is:

1. A phenol by-product decomposition device, comprising:
a decomposition reactor for decomposing a phenol by-product produced in a phenol and acetone preparation process, wherein the decomposition reactor is a reaction distillation column in which a reactor and a distillation column are integrated;
a tar collection unit provided in a lower portion of the reaction distillation column;
a tar transfer line for transferring the tar collected from the tar collection unit;
a first component collection unit provided in an upper portion of the reaction distillation column for collecting a first component from the phenol by-product, wherein the first component comprises phenol, α-methylstyrene, and cumene;
an acetophenone collection unit provided in a lower portion of the reaction distillation column for collecting acetophenone from the phenol by-product;
an acetophenone transfer line connected to the tar transfer line for mixing the acetophenone collected from the acetophenone collection unit with the collected tar; and
wherein the tar transfer tube and the acetophenone collection unit are connected to each other, and
wherein an inside of the reaction distillation column is subjected to a pressurizing condition.

2. The phenol by-product decomposition device of claim 1 ,
wherein the phenol by-product decomposition device further comprises: an upper fraction collection unit provided in an upper portion of the decomposition reactor for collecting an upper fraction containing the first component and the acetophenone; and
wherein the reaction distillation column is connected to the upper fraction collection unit for separating the acetophenone and the first component from the upper fraction.

3. A phenol by-product decomposition device comprising:
a decomposition reactor for decomposing a phenol by-product produced in a phenol and acetone preparation process, wherein the decomposition reactor is a reaction distillation column in which a reactor and a distillation column are integrated;
a tar collection unit provided in a lower portion of the reaction distillation column;
a tar transfer line for transferring the tar collected from the tar collection unit;
an acetophenone collection unit provided in a middle portion of a side of the reaction distillation column for collecting acetophenone from the phenol by-product;
an acetophenone transfer line connected to the tar transfer line for mixing the acetophenone collected from the acetophenone collection unit with the collected tar; and
a first component collection unit provided in an upper portion of the reaction distillation column for collecting a first component from the phenyl by-product, wherein the first component comprises phenol, α-methylstyrene, and cumene,
wherein the tar transfer tube and the acetophenone collection unit are connected to each other.

4. The phenol by-product decomposition device of claim 3 , wherein the phenol by-product decomposition device further comprises: an upper fraction collection unit provided in an upper portion of the decomposition reactor for collecting an upper fraction containing the first component and the acetophenone; and
wherein the reaction distillation column is connected to the upper fraction collection unit for separating the acetophenone and the effective component from the upper fraction.

Assignees

• Lg Chemical Ltd

Inventors

• Kang Minsuk
• Lee Sang Beom
• Lee Sung Ho
• Shin Joon Ho
• Kim Sangeun

Classifications

• C07C37/74 Primary

  by distillation · CPC title

• C07C45/82

  by distillation · CPC title

• C07C1/20 Primary

  starting from organic compounds containing only oxygen atoms as heteroatoms · CPC title

• C07C7/04

  by distillation · CPC title

• C07C15/085

  Isopropylbenzene · CPC title