Methods and apparatuses for phenol fractionation in a single dividing wall column

Patent metadata

Field	Value
Publication number	US-9815756-B2
Application number	US-201715469251-A
Country	US
Kind code	B2
Filing date	Mar 24, 2017
Priority date	Mar 31, 2016
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

This present disclosure relates to processes and apparatuses for use of a single dividing wall distillation column for phenol fractionation. More specifically, the present disclosure relates to processes and apparatuses for phenol fractionation by combining crude acetone column and cumene-AMS column into a single dividing wall distillation column. The proper allocation of steam or water injection, chemical treatment reactor and internal liquid phase separator, the positioning of the side draw enables high yield of acetone and phenol.

First claim

The invention claimed is:

1. A process for the work-up by distillation of cleavage product mixtures produced in the cleavage of alkylaryl hydroperoxides, which comprises resolving the cleavage product mixture into at least three fractions in a single distillation step by:
feeding the cleavage product mixture to a side of a dividing wall distillation column;
removing a first fraction comprising ketone at the top of the dividing wall distillation column comprises at least 95% of a ketone present in the cleavage product before the distillation step;
removing a second fraction comprising of substituted or unsubstituted phenol at the bottom of the dividing wall distillation column; and
removing a third fraction comprising unreacted mono-, di- and/or trialkyl substituted benzene, water, and hydroxy ketone as side stream, whereby the side stream take-off is situated below the feed of cleavage product mixture to the dividing wall distillation column.

2. The process of claim 1 , wherein the ketone is acetone.

3. The process of claim 1 , wherein the second fraction is sent to a chemical treatment reactor.

4. The process of claim 3 , wherein the chemical treatment reactor is located within the dividing wall distillation column.

5. The process of claim 3 , wherein the chemical treatment reactor is located outside of the dividing wall distillation column.

6. The process of claim 1 , wherein a steam or water is injected between the bottom of the dividing wall distillation column and an injection point in the bottom-third of the dividing wall distillation column.

7. The process of claim 3 , wherein acetol and other carbonyl impurities are removed from the second fraction of the dividing wall distillation column by treating with amine in the chemical treatment reactor.

8. The process of claim 1 , the pressure of the dividing wall distillation column is about 70 kPa to about 345 kPa and the temperature at the bottom of the dividing wall distillation column is about 174° C. to about 225° C.

9. A process for the work-up by distillation of cleavage product mixtures produced in the cleavage of alkylaryl hydroperoxides, which comprises resolving the cleavage product mixture into at least three fractions in a single distillation step by:
feeding the cleavage product mixture to a side of a dividing wall distillation column;
removing a first fraction comprising ketone at the top of the dividing wall distillation column comprises at least 95% of a ketone present in the cleavage product before the distillation step;
removing a second fraction comprising substituted or unsubstituted phenol at the bottom of the dividing wall distillation column;
removing a third fraction comprising unreacted mono-, di- and/or trialkyl substituted benzene, water and hydroxy ketone as side stream of the distillation column, whereby the side stream take-off is situated below the feed of cleavage product mixture to the dividing wall distillation column; and
sending the second fraction to a chemical treatment reactor.

10. The process of claim 9 , wherein the ketone is acetone.

11. The process of claim 9 , wherein tray spacing of the dividing wall distillation column below the feed of cleavage product mixture is increased from about 680 mm to about 1450 mm and tray spacing of the dividing wall distillation column above the side stream is increased from about 450 mm to about 2100 mm.

12. The process of claim 9 , wherein acetol and other carbonyl impurities are removed from the second fraction of distillation column by treating with amine in the chemical treatment reactor.

13. The process of claim 9 , wherein the pressure of the dividing wall distillation column is about 70 kPa to about 345 kPa and the temperature at the bottom of the dividing wall distillation column is about 174° C. to 225° C.

14. The process of claim 9 , wherein the third fraction overflows a liquid collection apparatus and flows into a decanter.

15. The process of claim 14 , wherein the decanter is located within the dividing wall distillation column.

16. The process of claim 9 , wherein the cleavage product mixture before the work-up distillation comprises a concentration of about 40 mol % ketone, about 40 mol % substituted or unsubstituted phenol, and remainder comprises of unreacted mono-, di- and/or trialkyl substituted benzene and hydroxy ketone.

17. A process for the work-up by distillation of cleavage product mixtures produced in the cleavage of alkylaryl hydroperoxides, which comprises resolving the cleavage product mixture into at least three fractions in a single distillation step by:
feeding the cleavage product mixture to a side of a dividing wall distillation column;
removing a first fraction comprising ketone at the top of the dividing wall distillation column comprises at least 95% of a ketone present in the cleavage product before the distillation step;
removing a second fraction comprising substituted or unsubstituted phenol at the bottom of the dividing wall distillation column;
sending the second fraction to a chemical treatment reactor;
removing a third fraction comprising unreacted mono-, di- and/or trialkyl substituted benzene, water and hydroxy ketone as side stream of the dividing wall distillation column, whereby the side stream take-off is situated below the feed of cleavage product mixture to the distillation column; and
the third fraction overflows a liquid collection apparatus and flows into a decanter.

18. The process of claim 17 , wherein a steam or water is injected between the bottom of the dividing wall distillation column and an injection point in the bottom-third of the dividing wall distillation column.

19. The process of claim 17 , wherein the pressure of the distillation column is about 70 kPa to about 345 kPa and the temperature at the bottom of the distillation column is about 174° C. to about 225° C.

20. The process of claim 17 , wherein the recovery of acetol into the side stream is about 50% relative to the feed and the concentration of acetol in the second fraction of the distillation column is about 100 wt-ppm to about 500 wt-ppm.

Assignees

• Uop Llc

Inventors

• Schmidt Robert J
• Fang Charlotte Y
• Schulz Russell C
• Zhu Xin X
• Keenan Scott R
• Williams Chad A
• Tsihlis Heather D
• Miramontes Jose L
• Tsai Robert E

Classifications

• C07C37/74 Primary

  by distillation · CPC title

• B01D3/141

  where at least one distillation column contains at least one dividing wall · CPC title

• C07C39/04

  Phenol · CPC title

• C07C45/82

  by distillation · CPC title

• C07C45/53

  of hydroperoxides · CPC title