Foam molded product of thermoplastic polyester elastomer resin and method for producing the same

Patent metadata

Field	Value
Publication number	US-11542380-B2
Application number	US-201816621818-A
Country	US
Kind code	B2
Filing date	Jun 25, 2018
Priority date	Jun 27, 2017
Publication date	Jan 3, 2023
Grant date	Jan 3, 2023

Abstract

According to the present invention, there is provided a foam molded product of thermoplastic polyester elastomer resin which exhibits light weight and excellent rebound resilience. The foam molded product is characterized in that, the foam molded product has a foamed layer consisting of a resin phase and an isolated foamed cell.

First claim

The invention claimed is:

1. A foam molded product of thermoplastic polyester elastomer resin, comprising:
a foamed layer consisting of a resin phase and an isolated foamed cell,
wherein the resin phase contains a thermoplastic polyester elastomer (A),
wherein the thermoplastic polyester elastomer (A) is prepared by bonding a hard segment and at least one soft segment,
wherein the hard segment consists of polyester constituted from aromatic dicarboxylic acid and aliphatic and/or alicyclic diol as constituting ingredients,
wherein the at least one soft segment is selected from the group consisting of aliphatic polyether, aliphatic polyester and aliphatic polycarbonate,
wherein a content of the soft segment is 55 to 90% by mass,
wherein an average cell diameter of the foamed cell is 10 to 400 μm,
wherein the maximum cell diameter of the foamed cell is 10 to 500 μm,
wherein rebound resilience of the foam molded product is 60 to 90%, and
wherein density of the foam molded product is 0.1 to 0.35 g/cm 3 .

2. The foam molded product of thermoplastic polyester elastomer resin according to claim 1 , wherein the average cell diameter of the foamed cell is 200 to 400 μm.

3. The foam molded product of thermoplastic polyester elastomer resin according to claim 1 , wherein the density of the foam molded product is 0.1 to 0.25 g/cm 3 .

4. The foam molded product of thermoplastic polyester elastomer resin according to claim 1 , wherein the rebound resilience of the foam molded product is 70% to 90%.

5. The foam molded product of thermoplastic polyester elastomer resin according to claim 1 ,
wherein each surface of the foam molded product has a non-foamed skin layer having a thickness of 100 to 800 μm,
wherein an inner layer of the foam molded product includes the foamed layer, and
wherein the foam molded product has a sandwich structure of the non-foamed skin layers and the foamed layer in a thickness direction.

6. A method for producing the foam molded product of thermoplastic polyester elastomer resin according to claim 1 , comprising:
injecting a resin ingredient containing the polyester elastomer resin in a melted state together with a chemical foaming agent and/or an inert gas in a supercritical state into a cavity defined by clamped plural molds, thereby filling the cavity, and
when a non-foamed skin layer having a thickness of 100 to 800 μm is formed on each surface of the foam molded product, moving at least one of the plural molds in a mold-opening direction so as to expand a volume of the cavity,
wherein a core back transition time is 0.5 seconds to 5 seconds, and
wherein a molding temperature is a melting point of the resin plus 10 to 50° C.

7. The method for producing the foam molded product of thermoplastic polyester elastomer resin according to claim 6 , wherein the inert gas in a supercritical state is nitrogen.

Assignees

• Toyo Boseki

Inventors

• Morio Eri
• Akaishi Takuya

Classifications

• C08J2203/08

  Supercritical fluid · CPC title

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title

• B29C45/56

  using mould parts movable during or after injection, e.g. injection-compression moulding {(B29C45/1705 and B29C45/572 take precedence)} · CPC title

• B29C44/42

  using pressure difference, e.g. by injection or by vacuum · CPC title

• C08J9/12

  by a physical blowing agent · CPC title