Slurry composition, cured product of the slurry composition, and substrate, film and prepreg using the cured product

Patent metadata

Field	Value
Publication number	US-11530324-B2
Application number	US-202016828525-A
Country	US
Kind code	B2
Filing date	Mar 24, 2020
Priority date	Apr 5, 2019
Publication date	Dec 20, 2022
Grant date	Dec 20, 2022

Abstract

Provided are a slurry composition having a low thixotropy and a superior handling property; a cured product of this slurry composition; and a substrate, film and prepreg using such cured product, the substrate, film and prepreg exhibiting excellent mechanical properties and a low relative permittivity and dielectric tangent. The slurry composition has a thixotropic ratio of not higher than 3.0, and comprises:(A) a cyclic imide compound having, per molecule, at least one dimer acid backbone, at least one linear alkylene group having not less than 6 carbon atoms, and at least two cyclic imide groups;(B) spherical silica fine particles and/or alumina fine particles having an average particle size of 0.05 to 20 μm when measured by a laser diffraction method;(C) a silane coupling agent capable of reacting with the components (A) and (B); and(D) an organic solvent.

First claim

What is claimed is:

1. A slurry composition having a thixotropic ratio of not higher than 3.0, comprising:
(A) a cyclic imide compound having, per molecule, at least one dimer acid backbone, at least one linear alkylene group having not less than 6 carbon atoms, and at least two cyclic imide groups, wherein the cyclic imide compound as the component (A) is contained in the slurry composition in an amount of 15 to 85%, and is represented by the following formula (1):

wherein each A independently represents a tetravalent organic group having an aromatic or aliphatic ring; B represents an alkylene chain having 6 to 18 carbon atoms or a divalent aliphatic ring that may contain a hetero atom; each Q independently represents a linear alkylene group having 6 to 20 carbon atoms; each R independently represents a linear or branched alkyl group having 6 to 12 carbon atoms; n represents a number of 1 to 10; and m represents a number of 0 to 10;
(B) spherical silica fine particles and/or alumina fine particles having an average particle size of 0.05 to 20 μm when measured by a laser diffraction method, the component (B) being contained in the slurry composition in an amount of 35 to 90%;
(C) a silane coupling agent capable of reacting with the components (A) and (B), the component (C) being contained in an amount of 0.3 to 6.0% by mass with respect to the component (A); and
(D) an aromatic hydrocarbon-based organic solvent, the component (D) being contained in an amount of 20 to 200 parts by mass per 100 parts by mass of a sum total of the components (A) and (B),
wherein the components (A), (B), (C) and (D) are present in amounts which form a slurry composition having a thixotropic ratio of not higher than 3.0.

2. The slurry composition according to claim 1 , wherein A in the formula (1) is represented by any one of the following structural formulae:

wherein bonds in the above structural formulae that are yet unbonded to substituent groups are to be bonded to carbonyl carbons forming cyclic imide structures in the formula (1).

3. The slurry composition according to claim 1 , wherein the silane coupling agent as the component (C) contains one or more (meth)acrylic groups and/or amino groups.

4. A cured product of the slurry composition according to claim 1 .

5. The cured product according to claim 4 , wherein the cured product is a substrate.

6. The cured product according to claim 4 , wherein the cured product is a film.

7. The cured product according to claim 4 , wherein the cured product is a prepreg.

Assignees

• Shinetsu Chemical Co

Inventors

• Tsutsumi Yoshihiro
• Iguchi Hiroyuki
• Kudo Yuki
• Tsuura Atsushi

Classifications

• C08G73/1042

  Copolyimides derived from at least two different tetracarboxylic compounds or two different diamino compounds · CPC title

• C08J5/249

  characterised by the additives used in the prepolymer mixture · CPC title

• C08K2201/003

  Additives being defined by their diameter · CPC title

• C08G73/128

  the unsaturated precursors containing heterocyclic moieties in the main chain · CPC title

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title