High flash point fluids for in situ plasticization of polymers
US-9878486-B2 · Jan 30, 2018 · US
US11525341B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11525341-B2 |
| Application number | US-202016919376-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 2, 2020 |
| Priority date | Jul 2, 2020 |
| Publication date | Dec 13, 2022 |
| Grant date | Dec 13, 2022 |
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A fluid control device includes a support structure configured to be deployed in a borehole and a filtration component disposed at the support structure. The filtration component includes a porous medium made from a shape memory epoxy, the shape memory epoxy including a soft segment monomer and a hard segment monomer, the porous medium configured to be compacted from an initial shape to a compacted shape, deployed in the borehole, and subsequently expanded due to a downhole temperature to conform to a surface of the borehole.
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The invention claimed is: 1. A fluid control device comprising: a support structure configured to be deployed in a borehole; a filtration component disposed at the support structure, the filtration component including a porous medium made from a shape memory epoxy, the shape memory epoxy including a mixture of a first material made from a soft segment monomer and a second material made from a first hard segment monomer and a second hard segment monomer, the first hard segment monomer having a different functionality than the second hard segment monomer, the porous medium configured to be compacted from an initial shape to a compacted shape, deployed in the borehole, and subsequently expanded due to a downhole temperature to conform to a surface of the borehole. 2. The device of claim 1 , wherein the mixture forms a single material having a mixed network of the soft segment monomer, the first hard segment monomer and the second hard segment monomer. 3. The device of claim 1 , wherein the shape memory epoxy is formed by combining a mixture of the soft segment monomer, the first hard segment monomer and the second hard segment monomer with a curing agent. 4. The device of claim 1 , wherein at least one of the first hard segment monomer and the second hard segment monomer is a tetrafunctional monomer. 5. The device of claim 1 , wherein the first hard segment monomer is a difunctional monomer and the second hard segment monomer is a tetrafunctional monomer. 6. The device of claim 5 , wherein the soft segment monomer includes bisphenol A diglycidyl ether, and the first hard segment monomer includes phenol-formaldehyde polymer glycidyl ether. 7. The device of claim 6 , wherein the second hard segment monomer includes N,N,N′,N′-tetraglycidyl-4,4′-methylenebisbenzenamine. 8. The device of claim 1 , wherein the porous medium is produced using a blowing agent, the blowing agent selected from at least one of sodium polyacrylate and sodium bicarbonate. 9. The device of claim 1 , wherein the shape memory epoxy includes a toughening additive, the toughening additive including an engineering thermoplastic configured to be dissolved in an epoxy monomer or monomer blend prior to curing. 10. The device of claim 1 , wherein the fluid control device is configured as a screen assembly, the screen assembly configured to filter undesirable material including sand from fluid entering the borehole from a subterranean region, the support structure including a tubular having a fluid conduit defined therein, the porous medium being at least one layer disposed on an outer surface of the tubular and at least partially surrounding the tubular. 11. A fluid control method comprising: deploying a fluid control device in a borehole, the fluid control device including a support structure and a filtration component disposed at the support structure, the filtration component including a porous medium made from a shape memory epoxy, the shape memory epoxy including a mixture of a first material made from a soft segment monomer and a second material made from a first hard segment monomer and a second hard segment monomer, the first hard segment monomer having a different functionality than the second hard segment monomer, wherein the fluid control device is deployed when the porous medium is in a compacted shape; activating the porous medium to cause the porous medium to expand due to a downhole temperature, and conform to a surface of the borehole; and flowing a fluid through the porous medium and filtering undesirable material from the fluid. 12. The method of claim 11 , wherein the fluid control device is configured as a screen assembly, the support structure includes a tubular having a fluid conduit defined therein, the porous medium includes at least one layer disposed on an outer surface of the tubular and at least partially surrounding the tubular, and the undesirable material includes sand from the subterranean region. 13. The method of claim 11 , wherein the mixture forms a single material having a mixed network of the soft segment monomer, the first hard segment monomer and the second hard segment monomer. 14. The method of claim 11 , wherein the shape memory epoxy is formed by combining a mixture of the soft segment monomer, the first hard segment monomer and the second hard segment monomer with a curing agent. 15. The method of claim 11 , wherein at least one of the first hard segment monomer and the second hard segment monomer is a tetrafunctional monomer. 16. The method of claim 11 , wherein the first hard segment monomer is a difunctional monomer and the second hard segment monomer is a tetrafunctional monomer or a trifunctional monomer. 17. The method of claim 16 , wherein the soft segment monomer includes bisphenol A diglycidyl ether, and the first hard segment monomer includes phenol-formaldehyde polymer glycidyl ether. 18. The method of claim 17 , wherein the second hard segment monomer includes N,N,N′,N′-tetraglycidyl-4,4′-methylenebisbenzenamine. 19. The method of claim 11 , wherein the shape memory epoxy includes a thermoplastic polymer configured to be resistant to a downhole temperature. 20. The method of claim 11 , wherein the shape memory epoxy includes a toughening additive, the toughening additive including at least one of polysulfone and polyethersulfone.
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