High flash point fluids for in situ plasticization of polymers

Patent metadata

Field	Value
Publication number	US-9878486-B2
Application number	US-201615082080-A
Country	US
Kind code	B2
Filing date	Mar 28, 2016
Priority date	Dec 22, 2011
Publication date	Jan 30, 2018
Grant date	Jan 30, 2018

Abstract

An in situ method to deploy and/or plasticize a shape-memory material in order to change the material's physical dimensions and/or mechanical properties, includes a method for deploying a shape memory polymer having a deformed or compressed shape in an environment at a first temperature, the shape memory polymer having a first glass transition temperature which is greater than the first temperature. The method also includes contacting the shape memory polymer with an activation fluid in an amount effective to decrease the glass transition temperature of the shape memory polymer from the first glass transition temperature to a second glass transition temperature which is less than or equal to the first temperature, where the activation fluid comprises a sugar present in an amount effective to raise a flash point of the activation fluid.

First claim

What is claimed is:

1. A method for deploying a shape memory polymer in a downhole environment, comprising:
disposing a shape memory polymer having a deformed shape in the downhole environment at a first temperature, the shape memory polymer having a first glass transition temperature that is greater than the first temperature;
contacting the shape memory polymer with an activation fluid in an amount effective to decrease the glass transition temperature of the shape memory polymer from the first glass transition temperature to a second glass transition temperature which is less than or equal to the first temperature where the activation fluid comprises acetyl acetone and methanol; where the activation fluid comprises a sugar present in an amount effective to raise a flash point of the activation fluid where the sugar is selected from the group consisting of fructose, sucrose, and combinations thereof, where the amount of sugar in the activation fluid ranges from about 0.5 to about 20 wt %; and
expanding the shape memory polymer to deploy the shape memory polymer in a deployed shape in the downhole environment.

2. The method of claim 1 where the flash point is raised by at least 2° F. (1.1° C.).

3. The method of claim 1 where the shape memory polymer is selected from the group consisting of a polyurethane, a polyurethane made by reacting a polycarbonate polyol with a polyisocyanate, a polystyrene, a polyethylene, an epoxy, a rubber, a fluoroelastomers, a nitrile, a polymer made from ethylene propylene diene monomers (EPDM), a polyamide, a polyurea, a polyvinyl alcohol, a vinyl alcohol-vinyl ester copolymer, a phenolic polymer, a polybenzimidazole, a polyethylene oxide/acrylic acid/methacrylic acid copolymer crosslinked with N,N′-methylene-bis-acrylamide, a polyethylene oxide/methacrylic acid/N-vinyl-2-pyrrolidone copolymer crosslinked with ethylene glycol dimethacrylate, a polyethylene oxide/poly(methyl methacrylate)/N-vinyl-2-pyrrolidone copolymer crosslinked with ethylene glycol dimethacrylate, combinations thereof.

4. The method of claim 1 where the first glass transition temperature ranges from about 100° C. to about 150° C., and where the second glass transition temperature ranges from about 40° C. to about 100° C.

5. The method of claim 1 where the second glass transition temperature is about 10° C. to about 60° C. less than the first glass transition temperature.

6. The method of claim 1 where the first temperature ranges from about 60° C. to about 100° C.

7. The method of claim 1 further comprising changing a mechanical property of the shape memory polymer, where the property is selected from the group consisting of lowering Young's modulus, increasing toughness, and both.

8. A method for deploying a shape memory polymer in a downhole environment, comprising:
disposing a shape memory polymer having a deformed shape in the downhole environment at a first temperature;
contacting the shape memory polymer with an activation fluid to decrease the glass transition temperature of the shape memory polymer below the first temperature, where the activation fluid is comprises acetyl acetone and methanol; where the activation fluid comprises a sugar present in an amount effective to raise a flash point of the activation fluid by at least 2° F. (1.1° C.) where the sugar is selected from the group consisting of fructose, sucrose, and combinations thereof, where the amount of sugar in the activation fluid ranges from about 0.5 to about 20 wt %;
expanding the shape memory polymer to a deployed shape; and
displacing the activation fluid to increase the glass transition temperature to greater than the first temperature and to maintain the shape memory polymer in the deployed shape.

9. The method of claim 8 where the shape memory polymer is selected from the group consisting of a polyurethane, a polyurethane made by reacting a polycarbonate polyol with a polyisocyanate, a polystyrene, a polyethylene, an epoxy, a rubber, a fluoroelastomers, a nitrile, a polymer made from ethylene propylene diene monomers (EPDM), a polyamide, a polyurea, a polyvinyl alcohol, a vinyl alcohol-vinyl ester copolymer, a phenolic polymer, a polybenzimidazole, a polyethylene oxide/acrylic acid/methacrylic acid copolymer crosslinked with N,N′-methylene-bis-acrylamide, a polyethylene oxide/methacrylic acid/N-vinyl-2-pyrrolidone copolymer crosslinked with ethylene glycol dimethacrylate, a polyethylene oxide/poly(methyl methacrylate)/N-vinyl-2-pyrrolidone copolymer crosslinked with ethylene glycol dimethacrylate, combinations thereof.

10. A system for deploying a shape memory polymer in a downhole environment, comprising:
an activation fluid comprising acetyl acetone and methanol; where the activation fluid comprises a sugar present in an amount effective to raise a flash point of the activation fluid where the sugar is selected from the group consisting of fructose, sucrose, and combinations thereof, where the amount of sugar in the activation fluid ranges from about 0.5 to about 20 wt %; and
a shape memory polymer configured to deploy in the downhole environment at a first temperature by a decrease in its glass transition temperature in response to contact with the activation fluid.

11. The system of claim 10 where the flash point is raised by at least 2° F. (1.1° C.).

12. The system of claim 10 where the shape memory polymer is selected from the group consisting of a polyurethane, a polyurethane made by reacting a polycarbonate polyol with a polyisocyanate, a polystyrene, a polyethylene, an epoxy, a rubber, a fluoroelastomers, a nitrile, a polymer made from ethylene propylene diene monomers (EPDM), a polyamide, a polyurea, a polyvinyl alcohol, a vinyl alcohol-vinyl ester copolymer, a phenolic polymer, a polybenzimidazole, a polyethylene oxide/acrylic acid/methacrylic acid copolymer crosslinked with N,N′-methylene-bis-acrylamide, a polyethylene oxide/methacrylic acid/N-vinyl-2-pyrrolidone copolymer crosslinked with ethylene glycol dimethacrylate, a polyethylene oxide/poly(methyl methacrylate)/N-vinyl-2-pyrrolidone copolymer crosslinked with ethylene glycol dimethacrylate, combinations thereof.

13. The system of claim 10 where the shape memory polymer has a first glass transition temperature, and the activation fluid is effective to decrease the first glass transition temperature to a second glass transition temperature, where the second glass transition temperature is about 10° C. to about 60° C. less than the first glass transition temperature.

Assignees

• Baker Hughes Inc
• Baker Hughes A Ge Co Llc

Inventors

• Liu Bairu
• Sadana Anil
• Crews James B

Classifications

• E21B33/12

  Packers; Plugs (used for cementing E21B33/134, E21B33/16) · CPC title

• B29C61/06 Primary

  Making preforms having internal stresses, e.g. plastic memory · CPC title

• B29C61/04 Primary

  Thermal expansion · CPC title

• E21B33/1208

  characterised by the construction of the sealing or packing means (E21B33/1277 takes precedence) · CPC title