Thermal integration in synthesis gas production by partial oxidation

Patent metadata

Field	Value
Publication number	US-11524894-B2
Application number	US-202017018021-A
Country	US
Kind code	B2
Filing date	Sep 11, 2020
Priority date	Sep 12, 2019
Publication date	Dec 13, 2022
Grant date	Dec 13, 2022

Abstract

A process and a plant are proposed for producing a synthesis gas including hydrogen and carbon oxides by partial oxidation of carbon-containing fuel in the presence of an oxygen-containing oxidant and a moderator, wherein the obtained raw synthesis gas is laden with soot particles. According to the invention the cooling of the raw synthesis gas is carried out using a crossflow heat exchanger, a shell and tube heat exchanger or a spiral heat exchanger, wherein the carbon-containing input stream or the oxidant stream or the moderator stream or a plurality of these streams serve as the first coolant and are thus preheated before introduction into the partial oxidation plant.

First claim

What is claimed is:

1. A process for producing a raw synthesis gas containing hydrogen and carbon oxides by noncatalytic partial oxidation of a solid, liquid or gaseous carbon-containing input stream with an oxygen-containing oxidant, comprising:
(a) providing the carbon-containing input stream in fluid or fluidized form, providing an oxidant stream,
(b) providing a partial oxidation reactor comprising a reaction chamber having an inlet and an outlet, a burner arranged at the inlet of the reaction chamber and a cooling chamber arranged downstream of the outlet of the reaction chamber and in fluid connection therewith,
(c) providing a cold, water-containing quench medium stream,
(d) introducing the carbon-containing input stream and the oxidant stream into the reaction chamber via the burner,
(e) at least partially reacting the carbon-containing input stream with the oxidant stream under partial oxidation conditions in the burner and/or in the reaction chamber arranged downstream of the burner to afford a hot raw synthesis gas stream,
(f) discharging the hot raw synthesis gas stream from the reaction chamber and introducing same into the cooling chamber,
(g) subjecting the hot raw synthesis gas stream in the cooling chamber to the cold, water-containing quench medium stream to obtain a cold raw synthesis gas stream and a stream of hot, liquid quench medium laden with solids particles,
(h) discharging the cold raw synthesis gas stream from the partial oxidation reactor for further processing or further treatment,
(i) discharging the hot, liquid quench medium stream laden with solids particles from the partial oxidation reactor and introducing at least a portion of the hot quench medium stream into a first heat exchanger for cooling the hot quench medium stream by indirect heat exchange against a first coolant to obtain the cold quench medium stream,

wherein the first heat exchanger is selected from the group consisting of:
(i1) crossflow heat exchangers, wherein the coolant is passed through tubes which have the hot quench medium stream flowing around them,
(i2) shell and tube heat exchangers, wherein the coolant flows through the tube side and the hot quench medium stream flows through the shell side, and
(i3) spiral heat exchangers,

wherein the carbon-containing input stream or the oxidant stream or a plurality of these streams serve as the first coolant and are thus preheated before introduction into the burner, and
(j) discharging the cold quench medium stream from the first heat exchanger and recycling at least a portion of the cold quench medium stream to the cooling chamber to form a quench medium stream circuit.

2. The process according to claim 1 , wherein at least a second heat exchanger for cooling the hot quench medium stream by indirect heat exchange is present, wherein the second heat exchanger is operated with a second coolant selected from the group of: carbon-containing input stream and oxidant stream.

3. The process according to claim 1 , wherein a proportion of the hot or cooled quench medium stream is discharged continuously or batchwise from the quench medium stream circuit as a purge stream and quantitatively replaced by fresh water or solids-free condensate streams.

4. The process according to claim 1 , wherein the quench medium stream is supplied to an apparatus for solids separation before recycling to the cooling chamber.

5. The process according to claim 4 , wherein the hot quench medium stream is supplied to the apparatus for solids separation before introduction into the first heat exchanger.

6. The process according to claim 4 , wherein the cold quench medium stream is supplied to the apparatus for solids separation after discharging from the first heat exchanger.

7. The process according to claim 1 , wherein, when using a shell and tube heat exchanger or a crossflow heat exchanger the tubes traversed by the coolant are arranged vertically and the hot quench medium is run in crossflow, co-current or countercurrent relative to the flow direction of the coolant, wherein the flow direction of the quench medium through the heat exchanger is substantially vertically upwards or downwards and wherein a storage volume for accommodating solids deposits and a service opening for removal of the solids deposits are provided at the bottom of the heat exchanger.

8. The process according to claim 1 , wherein a pyrolysis oil or pyrolysis slurry is used as the carbon-containing input stream and a spiral heat exchanger is used as the first heat exchanger.

9. The process according to claim 1 , wherein the pressure in the reaction chamber and in the cooling chamber is between 25 and 80 bar(a) and the temperature of the hot quench medium stream is between 150° C. and 250° C.

10. The process according to claim 1 , wherein the preheating temperature of the carbon-containing input stream before introduction into the burner is between 200° C. and 400° C. for gaseous input streams, between 150° C. and 300° C. for liquid input streams and between 20° C. and 150° C. for pyrolysis oils or pyrolysis slurries as the input stream.

11. The process according to claim 1 , wherein the preheating temperature of the oxygen-containing oxidant before introduction into the burner is between 120° C. and 250° C.

12. A plant for producing a raw synthesis gas containing hydrogen and carbon oxides by noncatalytic partial oxidation of a solid, liquid or gaseous carbon-containing input stream with an oxygen-containing oxidant, comprising:
(a) a means for providing the carbon-containing input stream in fluid or fluidized form, a means for providing an oxidant stream,
(b) a partial oxidation reactor comprising a reaction chamber having an inlet and an outlet, a burner arranged at the inlet of the reaction chamber and a cooling chamber arranged downstream of the outlet of the reaction chamber and in fluid connection therewith,
(c) a means for providing a cold, water-containing quench medium stream,
(d) a means for introducing the carbon-containing input stream and the oxidant stream into the burner,
(e) a means for discharging a hot raw synthesis gas stream from the reaction chamber and a means for introducing same into the cooling chamber,
(f) a means for subjecting the hot raw synthesis gas stream in the cooling chamber to the cold, water-containing quench medium stream,
(g) a means for discharging a cold raw synthesis gas stream from the partial oxidation reactor,
(h) a means for discharging a hot, liquid quench medium stream laden with solids particles from the partial oxidation reactor, a first heat exchanger, a means for introducing at least a portion of the hot quench medium stream into the first heat exchanger, wherein the first heat exchanger is selected from the group consisting of:
(h1) crossflow heat exchangers configured such that the coolant is passed through tubes which have the hot quench medium stream flowing around them,
(h2) shell and tube heat exchangers configured such that the coolant flows through the tube side and the hot quench medium stream flows through the shell side, and
(h3) spiral heat exchangers,

a means for supplying the carbon-containing input stream or the oxidant stream or the moderator stream or a plurality of these streams to the first heat exchanger as the first coolant,
(j) a means for discharging the cold quench medium stream from the first heat exchanger and a means for recycling at least a portion of the cold quench medium stream to the cooling chamber.

13. The plant according to claim 12 , further comprising a second heat exchanger in fluid connection with the quench medium stream.

Assignees

• Air Liquide
• Air Liquide

Inventors

• Mueller-Hagedorn Matthias

Classifications

• C01B2203/0883

  by indirect heat exchange · CPC title

• C01B2203/0877

  by direct injection of fluid · CPC title

• C10J2300/1884

  with one stream being synthesis gas · CPC title

• B01J2219/00092

  Tubes · CPC title

• C10J3/84

  with means for removing dust or tar from the gas · CPC title