Method for preparing lead directly from lead-containing material by solid phase reaction

Patent metadata

Field	Value
Publication number	US-11519054-B2
Application number	US-201916576765-A
Country	US
Kind code	B2
Filing date	Sep 20, 2019
Priority date	May 27, 2019
Publication date	Dec 6, 2022
Grant date	Dec 6, 2022

Abstract

A method for preparing lead directly from a lead-containing material by a solid phase reaction, includes: step 1, adding the lead-containing material to be processed to the grinder, and adding a metal substance and water to the grinder, wherein an activity of the metal substance is larger than that of lead; the solid phase reaction between the lead-containing material and the metal substance is caused directly by the grinder through a mechanical force to obtain a reaction product; step 2, washing and filtering the reaction product to obtain the lead and a metal salt solution corresponding to the metal substance; step 3, performing a melt casting on the lead to obtain a crude lead, crystallizing the metal salt solution to obtain a metal salt corresponding to the metal substance.

First claim

What is claimed is:

1. A method for preparing lead directly from a lead-containing material by a solid phase reaction, comprising the following steps:
step 1, adding the lead-containing material to be processed to a grinder, and adding a metal substance and optionally water to the grinder, wherein the metal substance is one selected from the group consisting of zinc, iron, and aluminum, wherein a solid phase reaction between the lead-containing material and the metal substance is caused directly by the grinder through a mechanical force to obtain a reaction product,
wherein
the lead-containing material and the metal substance are reaction materials of the solid phase reaction,
an amount of the metal substance is 0.9 to 1.5 times of a theoretical amount,
the lead-containing material is a lead paste containing 60 wt % to 75 wt % of lead or a lead residue containing 20 wt % to 60 wt % of lead,
the lead residue is one or more selected from the group consisting of a lead sulphate residue, a lead chloride residue, and a lead oxide residue,
a weight ratio of a grinding medium to the reaction materials in the grinder is 2 to 20:1, a ratio of the water to the reaction materials is 0 to 5:1, a unit of the ratio of the water to the reaction materials is m 3 /t, and a reaction time is 0.1 to 5 h;
step 2, washing and filtering the reaction product to obtain the lead and a metal salt solution corresponding to the metal substance, wherein the metal salt solution is a sulfate solution or a chloride solution corresponding to the metal substance;
step 3, performing a melt casting on the lead to obtain a crude lead, and crystallizing the metal salt solution to obtain a metal salt corresponding to the metal substance;
wherein the steps are performed without the steps of leaching, cementation, and electrodeposition.

2. The method for preparing the lead directly from the lead-containing material by the solid phase reaction according to claim 1 , wherein the grinder is one selected from the group consisting of a rod mill, a stirring mill, and a ball mill.

3. The method for preparing the lead directly from the lead-containing material by the solid phase reaction according to claim 1 , wherein
the zinc is one or more selected from the group consisting of zinc powder, zinc sheets, and zinc particles;
the iron is one or more selected from the group consisting of iron powder, scrap iron, iron wires, and iron sheets; and
the aluminum is one or more selected from the group consisting of aluminum powder, aluminum sheets, aluminum foils, and aluminum wires.

4. The method for preparing the lead directly from the lead-containing material by the solid phase reaction according to claim 1 , wherein in the step 1, the method further comprises adding sulfuric acid or hydrochloric acid to the water, and controlling a pH of the solution at 1.0 to 5.0 during the reaction.

5. The method for preparing the lead directly from the lead-containing material by the solid phase reaction according to claim 1 , wherein in the step 3, a temperature of performing the melt casting on the lead is 500° C. to 700° C., and an amount of coal is 0 to 5% of a weight of the lead to be melt casted.

Assignees

• Univ Beijing Science & Technology

Inventors

• Wang Chengyan

Classifications

• C22B13/04 Primary

  by wet processes · CPC title

• C22B3/08

  Sulfuric acid {, other sulfurated acids or salts thereof} · CPC title

• C22B3/10

  Hydrochloric acid {, other halogenated acids or salts thereof} · CPC title

• C22B7/00 Primary

  Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; {Methods of a general interest or applied to the winning of more than two metals (briquetting of scrap C22B1/248; preliminary treatment of scrap C22B1/005)} · CPC title

• C22B13/045 Primary

  Recovery from waste materials · CPC title