Methods for purifying and recycling lead from spent lead-acid batteries

Patent metadata

Field	Value
Publication number	US-10777858-B2
Application number	US-201715671857-A
Country	US
Kind code	B2
Filing date	Aug 8, 2017
Priority date	Jun 20, 2014
Publication date	Sep 15, 2020
Grant date	Sep 15, 2020

Abstract

The present disclosure relates to methods by which lead from spent lead-acid batteries may be extracted, purified, and used in the construction of new lead-acid batteries. A method includes: (A) forming a mixture including a carboxylate source and a lead-bearing material; (B) generating a first lead salt precipitate in the mixture as the carboxylate source reacts with the lead-bearing material; (C) increasing the pH of the mixture to dissolve the first lead salt precipitate; (D) isolating a liquid component of the mixture from one or more insoluble components of the mixture; (E) decreasing the pH of the liquid component of the mixture to generate a second lead salt precipitate; and (F) isolating the second lead salt precipitate from the liquid component of the mixture. Thereafter, the isolated lead salt precipitate may be converted to leady oxide for use in the manufacture of new lead-acid batteries.

First claim

The invention claimed is:

1. A method, comprising:
(A) forming a mixture comprising a carboxylate source and a lead-bearing material;
(B) generating a first lead salt precipitate in the mixture as the carboxylate source reacts with the lead-bearing material;
(C) increasing the pH of the mixture to dissolve the first lead salt precipitate;
(D) isolating a liquid component of the mixture from one or more insoluble components of the mixture;
(E) adding an antisolvent to the liquid component to generate a second lead salt precipitate;
(F) isolating the second lead salt precipitate from the liquid component of the mixture; and
(G) recovering the antisolvent from the liquid component via distillation.

2. The method of claim 1 , comprising: (H) recycling the antisolvent recovered in step (G) into step (E) to generate a second lead salt precipitate.

3. The method of claim 2 , wherein step (H) further comprises:
recycling at least a portion of the liquid component isolated from the antisolvent in step (G) into step (A) to facilitate leaching of lead solids.

4. The method of claim 1 , wherein step (H) further comprises:
recycling at least a portion of the liquid component isolated from the antisolvent in step (G) into step (C) to increase the pH of the mixture.

5. A method, comprising:
(A) forming a mixture comprising a carboxylate source and a lead-bearing material;
(B) generating a first lead salt precipitate in the mixture as the carboxylate source reacts with the lead-bearing material;
(C) increasing the pH of the mixture to dissolve the first lead salt precipitate;
(D) isolating a liquid component of the mixture from one or more insoluble components of the mixture;
adding a hydride source to the liquid component isolated in step (D) to reduce an impurity of the liquid component and evolve a hydrogen-based impurity gas that is released from the liquid component;
(E) adding an antisolvent to the liquid component to generate a second lead salt precipitate; and
(F) isolating the second lead salt precipitate from the liquid component of the mixture.

6. The method of claim 5 , wherein the impurity comprises a compound that includes tellurium, antimony, tin, selenium, arsenic, germanium, silicon, phosphorus, sulfur, or a combination thereof.

7. The method of claim 6 , wherein the hydrogen-based impurity gas comprises hydrogen telluride, antimony trihydride (stibine), tin tetrahydride (stannane), hydrogen selenide, arsenic trihydride (arsine), germanium tetrahydride (germane), silicon hydrides (silane), phosphine, hydrogen disulfide, or a combination thereof.

8. The method of claim 5 , wherein the hydride source comprises sodium tetraborohydride.

9. The method of claim 5 , wherein the hydride source comprises sodium hydride.

10. The method of claim 5 , wherein the at least one hydride source comprises hydrogen gas.

11. The method of claim 5 , wherein the hydride source comprises syngas.

Assignees

• Cps Tech Holdings Llc

Inventors

• Spence Matthew A

Classifications

• B01J6/001

  Calcining · CPC title

• C22B7/007

  by acid leaching · CPC title

• H01M6/52

  Reclaiming serviceable parts of waste cells or batteries {, e.g. recycling} · CPC title

• C22B7/009

  General processes for recovering metals or metallic compounds from spent catalysts (for recovering specific metals C22B11/00 - C22B61/00) · CPC title

• C22B13/04

  by wet processes · CPC title