Positive electrode for nonaqueous secondary battery, method for forming the same, nonaqueous secondary battery, and electrical device

Patent metadata

Field	Value
Publication number	US-11515517-B2
Application number	US-201916710468-A
Country	US
Kind code	B2
Filing date	Dec 11, 2019
Priority date	Nov 7, 2012
Publication date	Nov 29, 2022
Grant date	Nov 29, 2022

Abstract

A positive electrode for a nonaqueous secondary battery including an active material layer which has sufficient electron conductivity with a low ratio of a conductive additive is provided. A positive electrode for a nonaqueous secondary battery including an active material layer which is highly filled with an active material, id est, including the active material and a low ratio of a conductive additive. The active material layer includes a plurality of particles of an active material with a layered rock salt structure, graphene that is in surface contact with the plurality of particles of the active material, and a binder.

First claim

What is claimed is:

1. An electric vehicle comprising:
a lithium-ion secondary battery;
a drive motor unit;
an accelerator pedal configured to work the drive motor unit;
a rear wheel; and
a front wheel,
wherein the lithium-ion secondary battery comprises:
a positive electrode;
a negative electrode; and
an electrolyte,

wherein the positive electrode comprises:
a current collector; and
an active material layer,

wherein the active material layer comprises:
a plurality of multi-layer graphene;
an active material; and
a binder,

wherein the active material layer comprises a first region where one of the plurality of the multi-layer graphene is in surface contact with the active material and a second region where the one of the plurality of the multi-layer graphene is in surface contact with the other one of the plurality of the multi-layer graphene, and
wherein the active material comprises Ni, Co and Mn.

2. The electric vehicle according to claim 1 , wherein the active material comprises a crystal belonging to a layered rock salt structure.

3. The electric vehicle according to claim 1 , wherein the active material comprises a crystal belonging to space group R-3m.

4. The electric vehicle according to claim 1 , wherein a primary particle diameter of the active material is greater than or equal to 0.2 μm and less than 20 μm.

5. The electric vehicle according to claim 1 , wherein a length of one side of the one of the plurality of the multi-layer graphene is greater than or equal to 50 nm and less than or equal to 100 μm.

6. The electric vehicle according to claim 1 , wherein the electrolyte comprising ethylene carbonate.

7. A hybrid vehicle comprising:
the electric vehicle according to claim 1 ; and
an internal-combustion engine.

8. An electric vehicle comprising;
a lithium-ion secondary battery;
a drive motor unit;
an accelerator pedal configured to work the drive motor unit;
a rear wheel; and
a front wheel,
wherein the lithium-ion secondary battery comprises:
a positive electrode;
a negative electrode; and
an electrolyte,

wherein the positive electrode comprises:
a current collector; and
a nactive material layer,

wherein the active material layer comprises:
a plurality of multi-layer graphene;
an active material; and
a binder,

wherein the active material comprises a first plurality of active material particles which has small particle diameter and a second plurality of active material particles which has large particle diameter,
wherein the active material layer comprises a first region where one of the plurality of the multi-layer graphene is in surface contact with the active material and a second region where the one of the plurality of the multi-layer graphene is in surface contact with the other one of the plurality of the multi-layer graphene, and
wherein the active material comprises Ni, Co and Mn.

9. The electric vehicle according to claim 8 , wherein the active material comprises a crystal belonging to a layered rock salt structure.

10. The electric vehicle according to claim 8 , wherein the active material comprises a crystal belonging to space group R-3m.

11. The electric vehicle according to claim 8 , wherein a primary particle diameter of the second plurality of the active material particles is greater than or equal to 0.2 μm and less than 20 μm.

12. The electric vehicle according to claim 8 , wherein a length of one side of the one of the plurality of the multi-layer graphene is greater than or equal to 50 nm and less than or equal to 100 μm.

13. The electric vehicle according to claim 8 , wherein the electrolyte comprising ethylene carbonate.

14. A hybrid vehicle comprising:
the electric vehicle according to claim 8 ; and
an internal-combustion engine.

15. The electric vehicle according to claim 1 , further comprising:
an electronic control unit,
wherein the electric vehicle is configured to drive by transferring torque generated in the drive motor unit to the rear wheel when the accelerator pedal is pressed and then the drive motor unit works,
wherein an output of electric power of the lithium-ion secondary battery is adjusted by the electronic control unit,
wherein the adjusted output of the electric power of the lithium-ion secondary battery is supplied to the drive motor unit, and
wherein the electronic control unit is configured to output a control signal to the drive motor unit and the lithium-ion secondary battery on the basis of operational information of the electric vehicle.

16. The electric vehicle according to claim 8 , further comprising:
an electronic control unit,
wherein the electric vehicle is configured to drive by transferring torque generated in the drive motor unit to the rear wheel when the accelerator pedal is pressed and then the drive motor unit works,
wherein an output of electric power of the lithium-ion secondary battery is adjusted by the electronic control unit,
wherein the adjusted output of the electric power of the lithium-ion secondary battery is supplied to the drive motor unit, and
wherein the electronic control unit is configured to output a control signal to the drive motor unit and the lithium-ion secondary battery on the basis of operational information of the electric vehicle.

17. The electric vehicle according to claim 1 , wherein the active material comprising a composite oxide Li, Ni, Co, and Mn.

18. The electric vehicle according to claim 8 , wherein the active material comprising a composite oxide Li, Ni, Co, and Mn.

Assignees

• Semiconductor Energy Lab

Inventors

• Kawakami Takahiro
• Yamakaji Masaki
• Motoyoshi Mako
• Yatabe Rika

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/1393 Primary

  of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title