Graphene powder, production method thereof, and electrochemical device comprising same

Patent metadata

Field	Value
Publication number	US-9413007-B2
Application number	US-201113992937-A
Country	US
Kind code	B2
Filing date	Dec 9, 2011
Priority date	Dec 10, 2010
Publication date	Aug 9, 2016
Grant date	Aug 9, 2016

Abstract

Provided are a graphene powder, a production method thereof, and an electrochemical device comprising the same. The graphene powder has an elemental ratio of oxygen atoms to carbon atoms of not less than 0.07 and not more than 0.13 and an elemental ratio of nitrogen atoms to carbon atoms of not more than 0.01. In the production method, the graphene powder is produced by using a dithionous acid salt as a reducing agent. Since the graphene has a low content of nitrogen atoms and a proper amount of oxygen atoms and a proper defect, the graphene is provided with good performance of both dispersibility and conductive property, and is usable as a good conductive additive, such as the one for a lithium ion battery electrode. The production method has the advantages of low cost, high efficiency and low toxicity.

First claim

The invention claimed is:

1. A graphene powder having an elemental ratio of oxygen atoms to carbon atoms of not less than 0.07 and not more than 0.13 and an elemental ratio of nitrogen atoms to carbon atoms of not more than 0.01,
wherein a ratio of I D peak intensity I G peak intensity measured by Raman spectroscopy which is measured at an excitation wavelength of 514.5 nm using argon ion laser excitation laser is not less than 1 and not more than 2.

2. The graphene powder according to claim 1 , wherein a ratio of I 2D peak intensity to I G peak intensity measured by Raman spectroscopy which is measured at an excitation wavelength of 514.5 nm using argon ion laser as excitation laser is not less than 0.1 and not more than 0.2.

3. The graphene powder according to claim 1 , wherein the graphene powder comprises flakes of the graphene powder.

4. The graphene powder according to claim 3 , wherein a thickness of the flakes is no more than 100 nm.

5. The graphene powder according to claim 3 , wherein a thickness of the flakes is no more than 50 nm.

6. A graphene powder having an elemental ratio of oxygen atoms to carbon atoms of not less than 0.07 and not more than 0.13 and an elemental ratio of nitrogen atoms to carbon atoms of not more than 0.01, wherein a ratio of the peak area at around 1750 cm −1 derived from a carbonyl group to the peak area at around 1560 cm −1 derived from a carbon-carbon double bond measured by IR spectroscopy which is carried out by ATR method is not less than 0.1 and not more than 0.5.

7. A method for producing a graphene powder comprising reducing graphene oxide using a reducing agent, wherein a dithionous acid salt is used as the reducing agent wherein the elemental ratio of oxygen atoms to carbon atoms in graphene oxide is not more than 0.5 and no peak peculiar to graphite is detected in an x-ray diffraction spectrum of the graphene oxide.

8. The method for producing a graphene powder according to claim 7 , wherein the dithionous acid salt is sodium dithionite or potassium dithionite.

9. An electrochemical device comprising the graphene powder according to claim 1 .

10. The electrochemical device according to claim 9 , wherein the electrochemical device comprises a lithium ion secondary battery.

11. A graphene powder comprising oxygen and carbon, wherein the graphene powder comprises flakes of the graphene powder and wherein the elemental ratio of oxygen atoms to carbon atoms in graphene oxide is not more than 0.5 and no peak peculiar to graphite is detected in an x-ray diffraction spectrum of the graphene oxide.

12. The graphene powder according to claim 11 , wherein a thickness of the flakes is no more than 50 nm.

13. The graphene powder of claim 11 , wherein a thickness of the flakes is no more than 100 nm.

14. An electrochemical device comprising the graphene powder according to claim 11 .

15. The electrochemical device according to claim 14 , wherein the electrochemical device comprises a lithium ion secondary battery.

16. An electrochemical device comprising the graphene powder according to claim 11 .

17. The electrochemical device according to claim 16 , wherein the electrochemical device comprises a lithium ion secondary battery.

18. An electrochemical device comprising the graphene powder according to claim 11 , wherein the electrochemical device comprises a lithium ion secondary battery.

19. A graphene powder having an elemental ratio of oxygen atoms to carbon atoms of not less than 0.07 and not more than 0.13 and an elemental ratio of nitrogen atoms to carbon atoms of not more than 0.01, wherein the graphene powder is prepared by a method for producing the graphene powder comprising reducing graphene oxide using a reducing agent, wherein a dithionous acid salt is used as the reducing agent wherein the elemental ratio of oxygen atoms to carbon atoms in graphene oxide is not more than 0.5 and no peak peculiar to graphite is detected in an x-ray diffraction spectrum of the graphene oxide.

Assignees

• Sun Peiyu
• Wu Zhenqi
• Liu Gangqiao
• Tamaki Eiichiro
• Kubota Yasuo
• Wu Gang
• Toray Industries

Inventors

• Sun Peiyu
• Wu Zhenqi
• Liu Gangqiao
• Tamaki Eiichiro
• Kubota Yasuo
• Wu Gang

Classifications

• B82Y30/00 Primary

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• H01M4/0409

  by a doctor blade method, slip-casting or roller coating · CPC title

• C01B31/0476

  Chemistry & Metallurgy · mapped topic

• H01M4/583 Primary

  Carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/1391

  of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title