Electric resistance welded steel pipe or tube and production method for electric resistance welded steel pipe or tube

Patent metadata

Field	Value
Publication number	US-11512361-B2
Application number	US-201816958736-A
Country	US
Kind code	B2
Filing date	Dec 26, 2018
Priority date	Dec 27, 2017
Publication date	Nov 29, 2022
Grant date	Nov 29, 2022

Abstract

Provided is an electric resistance welded steel pipe or tube having excellent fatigue durability after rapid and short-time heating quenching treatment. An electric resistance welded steel pipe or tube comprises: a base metal being a steel sheet having a specific chemical composition and an electric resistance weld portion having a bond width of 40×10−6 m or more and 120×10−6 m or less, wherein C0-C1 is 0.05 mass % or less, where C0-C1 is a difference between C1 in mass % which is a minimum C content of the electric resistance weld portion and C0 in mass % which is a C content of the steel sheet, and a depth of a total decarburized layer in each of an inner surface layer and an outer surface layer of the electric resistance welded steel pipe or tube is 50×10−6 m or less.

First claim

The invention claimed is:

1. A method of producing an electric resistance welded steel pipe or tube, the method comprising:
electric resistance welding a steel sheet to form an electric resistance welded steel pipe or tube that includes an electric resistance weld portion having a bond width of 40×10 −6 m or more and 120×10 −6 m or less and in which a depth of a total decarburized layer in each of an inner surface layer and an outer surface layer is 50×10 −6 m or less, the steel sheet having a chemical composition containing, in mass %,
C: 0.15% to 0.40%,
Si: 0.05% to 0.50%,
Mn: 0.30% to 2.00%,
Al: 0.01% to 0.10%,
Ti: 0.001% to 0.04%,
B: 0.0005% to 0.0050%, and
N: 0.0010% to 0.0100%,
with a balance consisting of Fe and inevitable impurities, a Ti content and a N content satisfying the following Formula (1)
(N/14)<(Ti/47.9)  (1)

where N is the N content in mass % and Ti is the Ti content in mass %; and
thereafter normalizing the electric resistance welded steel pipe or tube under conditions that C 0 -C* 1 is 0.05 mass % or less where C 0 -C* 1 is a difference between C* 1 and C 0 , C* 1 in mass % is a calculated value of a minimum C content of the electric resistance weld portion according to the following Formula (2)
C* 1 =C 0 −(C 0 −0.09)erf( h ′)  (2)

where
C O is the C content in mass % of the steel sheet,
h′=h/(Dt) 1/2 ,
h is the bond width divided by 2 and in units of meters,
D in units of m 2 /s=D O exp(−Q/RT),
D 0 =4.7×10 −5 m 2 /s,
Q=155 kJ/mol·K,
R=8.31 J/mol·K,
T is a maximum heating temperature in Kelvin in the normalizing, and
t is a time in units of seconds during which the electric resistance welded steel pipe or tube is held in a temperature range of (T-50 K) to T in the normalizing, and C O in mass % is a C content of the steel sheet, in an atmosphere that is composed of C 0 , CO 2 , H 2 , H 2 O, and a gas neutral to C and Fe and satisfies the following Formulas (3) and (4),
(P CO ) 2 /P CO2 ≥K· a C γ   (3)

P H2 ·P CO /P H2O ≥K′· a C γ   (4)

where
log(K)=−9460/T−1.26 log(T)+13.52,
K′=exp[−(131300−134.3T)/RT],
a C γ =x C γ ·exp[(G C γ +Ω FeC γ −G C gr )·RT]·exp[(−2Ω FeC γ ·x C γ ·x M γ )/RT],
G C γ −G C gr =73744 J/mol,
2Ω FeC γ =−51956 J/mol,
W MnC γ =+41900 J/mol,
W SiC γ =+125700 J/mol,
W CrC γ =−104750 J/mol,
P CO is a partial pressure in units of atm of CO in a furnace atmosphere,
P CO2 is a partial pressure in units of atm of CO 2 in the furnace atmosphere,
P H2 is a partial pressure in units of atm of H 2 in the furnace atmosphere,
P H2O is a partial pressure in units of atm of H 2 O in the furnace atmosphere,
R=8.31 J/mol·K,
T is the maximum heating temperature in Kelvin in the normalizing,
a C γ is an activity of C in austenite phase,
x C γ is a mole fraction of C in the austenite phase,
x Si γ is a mole fraction of Si in the austenite phase,
x Mn γ is a mole fraction of Mn in the austenite phase,
x Cr ± is a mole fraction of Cr in the austenite phase,
G C γ is a free energy of C in the austenite phase, and
G C gr is a free energy of C in graphite.

2. The method of producing an electric resistance welded steel pipe or tube according to claim 1 , wherein the chemical composition further contains, in mass %, one or more selected from the group consisting of
Cr: 1.0% or less,
Mo: 1.0% or less,
W: 1.0% or less,
Ni: 1.0% or less,
Cu: 1.0% or less,
Nb: 0.2% or less,
V: 0.2% or less, and
Ca: 0.0050% or less.

3. A method of producing an electric resistance welded steel pipe or tube, the method comprising:
electric resistance welding a steel sheet to form an electric resistance welded steel pipe or tube that includes an electric resistance weld portion having a bond width of 40×10 −6 m or more and 120×10 −6 m or less and in which a depth of a total decarburized layer in each of an inner surface layer and an outer surface layer is 50×10 −6 m or less, the steel sheet having a chemical composition containing, in mass %,
C: 0.15% to 0.40%,
Si: 0.05% to 0.50%,
Mn: 0.30% to 2.00%,
Al: 0.01% to 0.10%,
Ti: 0.001% to 0.04%,
B: 0.0005% to 0.0050%, and
N: 0.0010% to 0.0100%,
with a balance consisting of Fe and inevitable impurities, a Ti content and a N content satisfying the following Formula (1)
(N/14)<(Ti/47.9)  (1)

where N is the N content in mass % and Ti is the Ti content in mass %; and
thereafter normalizing the electric resistance welded steel pipe or tube under conditions that C 0 -C* 1 is 0.05 mass % or less where C 0 -C* 1 is a difference between C* 1 and C 0 , C* 1 in mass % is a calculated value of a minimum C content of the electric resistance weld portion according to the following Formula (2)
C* 1 =C 0 −(C 0 −0.09)erf( h ′)  (2)

where
C O is the C content in mass % of the steel sheet,
h′=h/(Dt) 1/2 ,
h is the bond width divided by 2 and in units of meters,
D in units of m 2 /s=D 0 exp(−Q/RT),
D 0 =4.7×10 −5 m 2 /s,
Q=155 kJ/mol·K,
R=8.31 J/mol·K,
T is a maximum heating temperature in Kelvin in the normalizing, and
t is a time in units of seconds during which the electric resistance welded steel pipe or tube is held in a temperature range of (T-50 K) to T in the normalizing, and C O in mass % is a C content of the steel sheet, in an atmosphere that is composed of, in mole fraction in a furnace atmosphere, H 2 : 0% to 10% and O 2 : 80 ppm or less with a balance consisting of H 2 O and N 2 and has a dew point of 0° C. or less.

4. The method of producing an electric resistance welded steel pipe or tube according to claim 3 , wherein the chemical composition further contains, in mass %, one or more selected from the group consisting of
Cr: 1.0% or less,
Mo: 1.0% or less,
W: 1.0% or less,
Ni: 1.0% or less,
Cu: 1.0% or less,
Nb: 0.2% or less,
V: 0.2% or less, and
Ca: 0.0050% or less.

Assignees

• Jfe Steel Corp
• Jfe Welded Pipe Mfg Co Ltd

Inventors

• Kawabata Yoshikazu
• Gunji Makio

Classifications

• C21D9/08 Primary

  for tubular bodies or pipes · CPC title

• C22C38/06

  containing aluminium · CPC title

• C22C38/00

  Ferrous alloys, e.g. steel alloys (cast-iron alloys C22C37/00) · CPC title

• B23K2101/06

  Tubes · CPC title

• C22C38/44

  with molybdenum or tungsten · CPC title