Process and plant for producing pure methanol

Patent metadata

Field	Value
Publication number	US-11512033-B2
Application number	US-202117212900-A
Country	US
Kind code	B2
Filing date	Mar 25, 2021
Priority date	Mar 26, 2020
Publication date	Nov 29, 2022
Grant date	Nov 29, 2022

Abstract

The invention relates to a process and a plant for producing pure methanol, wherein the crude methanol stream discharged from a methanol synthesis unit is decompressed in a decompression vessel, is subsequently at least partially freed of low-boiling by-products in a prerun column and is then supplied to a single- or multi-stage methanol purification apparatus from which a pure methanol product stream is finally discharged. According to the invention the tops product stream from the prerun column is subjected to a scrubbing step with a methanol-selective scrubbing medium, thus at least partially recovering methanol present and sending a methanol-depleted tops product stream to the offgas disposal apparatus.

First claim

What is claimed is:

1. A process for producing pure methanol from a synthesis gas containing hydrogen and carbon oxides as synthesis gas constituents, comprising:
(a) at least partially converting the synthesis gas containing hydrogen and carbon oxides under methanol synthesis conditions in a methanol synthesis unit containing at least one methanol synthesis reactor,
(b) discharging a liquid crude methanol stream containing methanol, water, dissolved synthesis gas constituents and low-boiling by-products from the methanol synthesis unit,
(c) introducing the liquid crude methanol stream into a decompression vessel, discharging a liquid, decompressed crude methanol stream depleted in synthesis gas constituents as the bottoms product and a gaseous tops product stream comprising synthesis gas constituents from the decompression vessel,
(d) introducing the liquid, decompressed crude methanol stream depleted in synthesis gas constituents to a prerun column, distillatively resolving said stream, discharging a liquid, stabilized, methanol stream depleted in low-boiling by-products as the bottoms product stream and a gaseous tops product stream comprising low-boiling by-products and methanol vapour from the prerun column,
(e) introducing the bottoms product stream from the prerun column to a single- or multi-stage methanol purification apparatus, discharging a pure methanol product stream from the methanol purification apparatus,
(f) sending the tops product stream from the prerun column to an offgas disposal apparatus,

wherein,
(g) before sending to the offgas disposal apparatus, the tops product stream from the prerun column is subjected to a scrubbing step with a methanol-selective scrubbing medium in a scrubbing apparatus and a methanol-depleted tops product stream is sent to the offgas disposal apparatus.

2. The process according to claim 1 , wherein water is used as the scrubbing medium.

3. The process according to claim 2 , wherein methanol-laden water is discharged from the scrubbing apparatus and recycled to the prerun column.

4. The process according to claim 2 , wherein methanol-laden water is discharged from the scrubbing apparatus and introduced to the methanol purification apparatus.

5. The process according to claim 1 , wherein the gaseous tops product stream comprising synthesis gas constituents from the decompression vessel is subjected to a scrubbing step with a methanol-selective scrubbing medium in a scrubbing apparatus.

6. The process according to claim 1 , wherein the methanol purification apparatus comprises at least one methanol reservoir vessel whose free gas space is purged with an inert gas, wherein the methanol-laden inert gas is discharged from the at least one methanol reservoir vessel and subjected to a scrubbing step with a methanol-selective scrubbing medium in a scrubbing apparatus.

7. The process according to claim 1 , wherein at least two of the scrubbing steps are performed with the same scrubbing medium in a common scrubbing apparatus.

Assignees

• Air Liquide

Inventors

• Gronemann Veronika
• Huder Karin
• Lim Chin Han

Classifications

• C07C29/151 Primary

  with hydrogen or hydrogen-containing gases · CPC title

• C07C29/80 Primary

  by distillation · CPC title

• C07C29/86

  by liquid-liquid treatment · CPC title

• C07C31/04 Primary

  Methanol · CPC title

• C07C27/00 Primary

  Processes involving the simultaneous production of more than one class of oxygen-containing compounds · CPC title