Process and apparatus for the recovery of methanol

Patent metadata

Field	Value
Publication number	US-10874983-B2
Application number	US-201616063500-A
Country	US
Kind code	B2
Filing date	Dec 6, 2016
Priority date	Dec 18, 2015
Publication date	Dec 29, 2020
Grant date	Dec 29, 2020

Abstract

There is proposed an efficient recovery of methanol from waste gases loaded with methanol in an integrated flow chart for the production and processing of methanol. The methanol fractions separated from the waste gases are recovered within the already existing, distillative processing of the crude methanol to pure methanol, so that no separate apparatuses are required for the recovery of the methanol from the loaded scrubber waste waters. The valuable substance methanol is recovered and the impact on the environment is reduced. By means of particular aspects of the invention the need for water as washing agent can be reduced further.

First claim

The invention claimed is:

1. A process for the recovery of methanol from process waste gases of the methanol synthesis, comprising the following process steps:
a) converting a synthesis gas stream under methanol synthesis conditions in at least one methanol synthesis reactor which is arranged in a synthesis gas circuit for non-converted synthesis gas;
b) discharging a liquid crude methanol stream from the synthesis gas circuit and discharging a purge gas stream from the synthesis gas circuit, wherein the purge gas stream is loaded with methanol vapor;
c) introducing the purge gas stream into a purge gas washing apparatus, contacting the purge gas stream in the purge gas washing apparatus with a water stream as washing agent which is guided through the purge gas washing apparatus in counterflow to the purge gas stream, wherein the water stream absorbs at least a part of the methanol from the purge gas stream;
d) discharging a water stream loaded with methanol and a purge gas stream depleted of methanol from the purge gas washing apparatus;
e) introducing the liquid crude methanol stream into an expansion tank in which the pressure of the liquid crude methanol stream is reduced, wherein an expansion gas stream loaded with methanol and a depressurized crude methanol stream are obtained;
f) introducing the expansion gas stream into an expansion gas washing apparatus, contacting the expansion gas stream in the expansion gas washing apparatus with a water stream as washing agent which is guided through the expansion gas washing apparatus in counterflow to the expansion gas stream, wherein the water stream absorbs at least a part of the methanol from the expansion gas stream;
g) discharging a water stream loaded with methanol and an expansion gas stream depleted of methanol from the expansion gas washing apparatus, wherein the water stream loaded with methanol is added to the depressurized crude methanol stream;
h) introducing the depressurized crude methanol stream into a storage tank in which it is stored until its further processing or further use and in the process is covered by an inertizing gas which thereby is loaded with methanol;
i) discharging an inertizing gas stream loaded with methanol from the storage tank and introducing the same into an inertizing gas washing apparatus, contacting the inertizing gas stream in the inertizing gas washing apparatus with a water stream as washing agent which is guided through the inertizing gas washing apparatus in counterflow to the inertizing gas stream, wherein the water stream absorbs at least a part of the methanol from the inertizing gas stream; and
j) discharging a water stream loaded with methanol and an inertizing gas stream depleted of methanol from the inertizing gas washing apparatus.

2. The process according to claim 1 , wherein the purge gas stream depleted of methanol, which is obtained in step (d), is supplied to a hydrogen recovery apparatus.

3. The process according to claim 1 , wherein the water stream loaded with methanol, which is obtained in step (d), is at least partly supplied to the expansion tank.

4. The process according to claim 1 , wherein the water stream loaded with methanol, which is obtained in step (d), is at least partly used as washing agent in the expansion gas washing apparatus.

5. The process according to claim 1 , wherein at least a part of the depressurized crude methanol stream obtained in process step (e) is supplied to a distillation apparatus without intermediate storage in the storage tank.

6. The process according to claim 1 , wherein at least a part of the expansion gas stream depleted of methanol, which is obtained in step (g), is introduced into the storage tank as inertizing gas.

7. The process according to claim 1 , wherein at least a part of the water stream loaded with methanol, which is obtained in step (j), is used as washing agent in the expansion gas washing apparatus.

8. The process according to claim 1 , wherein at least a part of the water stream loaded with methanol, which is obtained in step (j), is supplied to the expansion tank.

9. An apparatus for the recovery of methanol from process waste gases of the methanol synthesis, the apparatus comprising:
a) a methanol synthesis reactor which is arranged in a synthesis gas circuit for non-converted synthesis gas;
b) a conduit for discharging a liquid crude methanol stream from the synthesis gas circuit and a conduit for discharging a purge gas stream from the synthesis gas circuit, wherein the purge gas stream is loaded with methanol vapor;
c) a purge gas washing apparatus designed as countercurrent washer, a conduit for introducing the purge gas stream into a purge gas washing apparatus, a conduit for supplying a water stream as washing agent, a conduit for discharging a water stream loaded with methanol, and a conduit for discharging a purge gas stream depleted of methanol from the purge gas washing apparatus;
d) an expansion tank in which the pressure of the liquid crude methanol stream is reduced, a conduit for introducing the liquid crude methanol stream into the expansion tank, an expansion gas washing apparatus designed as countercurrent scrubber which is connected with the expansion tank, a conduit for introducing a water stream as washing agent into the expansion gas washing apparatus, a conduit for discharging a depressurized crude methanol stream, and a conduit for discharging an expansion gas stream depleted of methanol;
e) a storage tank, a conduit for introducing the depressurized crude methanol stream into the storage tank, a conduit for introducing an inertizing gas and a conduit for discharging an inertizing gas stream loaded with methanol from the storage tank, a conduit for discharging the crude methanol; and
f) an inertizing gas washing apparatus designed as countercurrent scrubber, a conduit for introducing an inertizing gas stream loaded with methanol into the inertizing gas washing apparatus, a conduit for introducing a water stream as washing agent into the inertizing gas washing apparatus, a conduit for discharging an inertizing gas stream depleted of methanol, and a conduit for discharging a water stream loaded with methanol from the inertizing gas washing apparatus.

10. The apparatus according to claim 9 , furthermore comprising a hydrogen recovery apparatus and a conduit for introducing a purge gas stream depleted of methanol into the hydrogen recovery apparatus.

11. The apparatus according to claim 9 , furthermore comprising a conduit for supplying the water stream loaded with methanol, which is obtained in process step (d), to the expansion tank.

12. The apparatus according to claim 9 , furthermore comprising a conduit for supplying the water stream loaded with methanol, which is obtained in process step (d), to the expansion gas washing apparatus as washing agent.

13. The apparatus according to claim 9 , furthermore comprising a distillation apparatus and a conduit for supplying the depressurized crude methanol stream obtained in process step (e) to the distillation apparatus.

14. The apparatus according to claim 9 , furthermore comprising a conduit for supplying at least a part of the expansion gas stream depleted of methanol, which is obtained in process step (g), into the storage tank as inertizing gas.

15. The apparatus according to claim 9 , furthermore comprising a conduit for supplying at least a part of the water stream loaded with methanol, which is obtained in process step (j), to the expansion gas washing apparatus as washing agent.

16. The apparatus according to claim 9 , furthermore comprising a conduit

Assignees

• Air Liquide

Inventors

• Huder Karin
• Gronemann Veronika
• Oelmann Tobias

Classifications

• C07C29/151 Primary

  with hydrogen or hydrogen-containing gases · CPC title

• C07C29/76 Primary

  by physical treatment · CPC title

• B01D53/74 Primary

  General processes for purification of waste gases; Apparatus or devices specially adapted therefor (B01D53/92 takes precedence) · CPC title

• Y02P20/129

  Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines · CPC title

• B01J19/0053

  Details of the reactor · CPC title