Process for manufacturing composite articles

Patent metadata

Field	Value
Publication number	US-11498249-B2
Application number	US-201917057455-A
Country	US
Kind code	B2
Filing date	May 21, 2019
Priority date	May 24, 2018
Publication date	Nov 15, 2022
Grant date	Nov 15, 2022

Abstract

The present invention relates to the use of thermoplastic polymer compositions for impregnating reinforcing materials in the form of fabric or industrial fabrics for the manufacture of composite materials. The field of the invention is that of composite materials as well as molding/consolidation processes and obtained parts. The invention more particularly relates to a method of manufacturing a composite article by injection molding comprising at least the steps of introducing at least one reinforcement fabric into a preheated mold, partial closure of the mold, a temperature rise step of the mold, optionally a step of maintaining the temperature of the mold before injection of a thermoplastic polymer composition, a step of injecting a thermoplastic polymer composition into the mold, a step of mold closure to the final part thickness allowing the flow of the resin through the reinforcing fabric, a cooling step and a recovery step of the obtained composite article.

First claim

The invention claimed is:

1. A process for manufacturing a composite article by injection molding a polymer composition comprising at least one semi-crystalline thermoplastic polymer and/or at least one amorphous thermoplastic polymer, comprising the following steps:
(a) Introducing at least one reinforcement material into a preheated mold having a temperature T 1 that is in the range of from 50° C. to a temperature T 1 max , wherein T 1 max is defined as follows:
T 1 max =T g max +40° C.,  (i)

if the polymer composition has no melting transition, or
if the polymer composition has at least one melting transition and the highest melting temperature T m max of the polymer composition is lower than T g max +40° C., wherein T g max denotes the highest glass transition temperature of the polymer composition,
or
T 1 max =T m max ,  (ii)

if the polymer composition has at least one melting transition and the highest melting temperature T m max of the polymer composition is equal or greater than T g max +40° C.; and

(b) after the introducing, partially closing the mold including the at least one reinforcement material, such that the mold exhibits an open gap with a volume of from 70% to 200% of the polymer volume to be injected; and
(c) after the partial closing, raising the temperature of the mold to a temperature T 2 that is in the range of from T 2 min to T 2 max , wherein T 2 min and T 2 max are defined as follows:
T 2 min =T g max +50° C., T 2 max =T g max +300° C.,  (i)

if the polymer composition has no melting transition,
or
T 2 min =T g max +50° C., T 2 max =T g max +150° C.,  (ii)

if the polymer composition has at least one melting transition and the highest melting temperature T m max of the polymer composition is lower than T g max +40° C.,
or
T g min =T m max +10° C., T 2 max =T m max +100° C.,  (iii)

if the polymer composition has at least one melting transition and the highest melting temperature T m max of the polymer composition is equal or greater than T g max +40° C.; and

(d) optionally maintaining the raised temperature of the mold for a period of time; and
(e) after the raising the temperature and the optional maintaining, injecting a polymer composition having a melt viscosity of from 5 to 200 Pa·s, determined according to ISO 11403-2 at the temperature of step (c) and a shear rate of 100 s−1, into the mold, filling the free cavity obtained by partial closure of the mold; and
(f) after the injecting, closing the mold to the final thickness of the part, maintaining the temperature of step (c), employing a compression rate of from 0.001 to 0.5 mm/s and permitting the mold pressure to rise to a range of from 0.2 to 17.5 MPa; and
(g) after the mold pressure rises, cooling the mold to a temperature T 3 that is in the range of from T 3 min to T 3 max , wherein T 3 min and T 3 max are defined as follows:
T 3 min =T g min −100° C., T 3 max =T g min +50° C.,  (i)

if the polymer composition has no crystallization transition, and wherein T g min denotes the lowest glass transition temperature of the polymer composition,
or
T 3 min =T c min −120° C., T 3 max =T c min +25° C.,  (ii)

if the polymer composition has at least one crystallization transition, and wherein T c min denotes the lowest crystallization temperature of the polymer composition; and

(h) after the cooling, opening the mold, ejecting and recovering the produced composite article.

2. The process of claim 1 , wherein the preheated mold has a temperature in the range of from 75° C. to T 1 max .

3. The process of claim 1 , wherein the reinforcement material is heated before introduction into the mold.

4. The process of claim 1 , wherein temperature raising step (c) is carried out in a period of from 1 minute to 30 minutes.

5. The process of claim 1 , wherein injection step (e) is carried out in a period of from 10 seconds to 2 minutes.

6. The process of claim 1 , wherein the composite article comprises from 20% to 65% by volume, of reinforcing material, based on the total volume of the composite article.

7. The process of claim 1 , wherein the variation of viscosity of the polymer composition amounts to less than ±20%.

8. The process of claim 1 , wherein the semi-crystalline polymer comprises a fully aliphatic polyamide or a partially aromatic polyamide or mixtures thereof.

9. The process of claim 1 , wherein the semi-crystalline polymer comprises a polyphenylene sulphide or a mixture of two or more polyphenylene sulfides.

10. The process of claim 1 , wherein the polymer composition comprises at least one polyamide and at least one polyphenylene sulphide.

11. The process of claim 1 , wherein the amorphous thermoplastic polymer is at least one from the group consisting of: polyacrylate, polystyrene, polycarbonate, polyurethane, polydimethylphenylene ether, polyarylether sulfone, polyetherimide, and polyamideimide.

12. The process of claim 1 , wherein the polymer composition comprises a mixture comprising at least one semi-crystalline and at least one amorphous polymer.

13. The process of claim 1 , wherein the polymer composition comprises a mixture comprising at least one polymer having a glass transition temperature of from 5° C. to 80° C., and at least one polymer having a glass transition temperature of from 81° C. to 250° C.

14. The process of claim 1 , wherein the polymer composition comprises a mixture comprising at least one polymer having a melt viscosity of from 1 to 50 Pas and at least one polymer having a melt viscosity of from 75 to 350 Pa·s.

15. The process of claim 1 , wherein the polymer composition exhibits a melt viscosity η of from 10 to 125 Pa·s.

16. The process of claim 1 , further comprising: placing the composite article as recovered in step (h) into a second mold and subsequently at least partially overmolding, via injection molding, the surface of the composite article with a second polymer composition wherein, during the overmolding, the temperature difference between the injected second polymer composition and the composite article is lower than 175° C.

17. The process of claim 1 , wherein in step (f) the mold pressure is permitted to rise to a range of from 0.5 to 10 MPa.

18. The process of claim 16 , wherein the temperature difference between the injected second polymer composition and the composite article is lower than 150° C.

19. The process of claim 16 , wherein the temperature difference between the injected second polymer composition and the composite article is lower than 125° C.

Assignees

• Rhodia Operations
• Georges Pernoud Sas
• Billion SAS

Inventors

• Orange Gilles
• Pascal Fabien
• Jacquet Patrice
• Giroud Alexandre

Classifications

• B29K2025/06

  PS, i.e. polystyrene · CPC title

• B29K2081/04

  Polysulfides, e.g. PPS, i.e. polyphenylene sulfide or derivatives thereof · CPC title

• B29K2079/00

  Use of polymers having nitrogen, with or without oxygen or carbon only, in the main chain {, not provided for in groups B29K2061/00 - B29K2077/00}, as moulding material · CPC title

• B29C70/467

  and impregnating the reinforcements during mould closing (B29C70/465 takes precedence) · CPC title

• B29K2069/00

  Use of PC, i.e. polycarbonates {or derivatives thereof}, as moulding material · CPC title