Method and apparatus for burning odor gas

Patent metadata

Field	Value
Publication number	US-11486090-B2
Application number	US-201816771509-A
Country	US
Kind code	B2
Filing date	Dec 13, 2018
Priority date	Dec 22, 2017
Publication date	Nov 1, 2022
Grant date	Nov 1, 2022

Abstract

A method for burning primary fuel (F 1 ), wherein the primary fuel (F 1 ) comprises at least a first compound containing nitrogen and a second compound comprising sulfur. The method comprises producing primary combustion gas (G 1 ) having a temperature of at least 450° C. and comprising oxygen; feeding the primary fuel (F 1 ) and the primary combustion gas (G 1 ) to a primary process zone (Z 1 ) of a furnace ( 200 ); feeding tertiary combustion gas (G 3 ) to a secondary process zone (Z 2 ) of the furnace ( 200 ); letting the primary fuel (F 1 ), the primary combustion gas (G 1 ), and/or their reaction products to move from the primary process zone (Z 1 ) via the secondary process zone (Z 2 ) to a tertiary process zone (Z 3 ) of the furnace ( 200 ); and feeding quaternary combustion gas (G 4 ) comprising oxygen to the tertiary process zone (Z 3 ) of the furnace ( 200 ). An embodiment comprises collecting the primary fuel (F 1 ) from a pulp process. A corresponding system.

First claim

The invention claimed is:

1. A method for burning primary fuel, the method comprising:
producing primary combustion gas having an oxygen content from 7 vol % to 19 vol % by burning a tertiary fuel,
feeding the primary fuel and the primary combustion gas to a primary process zone of a furnace,
feeding tertiary combustion gas to a secondary process zone of the furnace,
letting at least one of the primary fuel, the primary combustion gas, or their reaction products move from the primary process zone via the secondary process zone to a tertiary process zone of the furnace,
feeding quaternary combustion gas comprising oxygen to the tertiary process zone of the furnace,
producing such primary combustion gas that has a temperature of at least 450° C., and
delivering the primary combustion gas to the primary process zone by means of a compressor or a fan,
wherein the primary fuel comprises ammonia (NH 3 ) and methyl mercaptan (CH 3 SH).

2. The method of claim 1 , wherein an oxygen content of the quaternary combustion gas is higher than an oxygen content of the primary combustion gas.

3. The method of claim 1 , further comprising feeding secondary combustion gas to the primary process zone of the furnace.

4. The method of claim 3 , wherein an oxygen content of the secondary combustion gas is higher than an oxygen content of the primary combustion gas.

5. The method of any of claim 1 , wherein at least a part of the furnace is surrounded by at least a wall that is arranged in a container at least partially filled with liquid heat transfer medium such as oil or water.

6. The method of claim 1 , further comprising feeding secondary fuel to the secondary process zone of the furnace.

7. The method of claim 6 , wherein either:
the secondary fuel comprises at least a compound containing nitrogen; or
the secondary fuel comprises at least a compound containing nitrogen such that a nitrogen content of the secondary fuel is less than a nitrogen content of the primary fuel.

8. The method of claim 1 , wherein:
a concentration of the methyl mercaptan in the primary fuel is at least 20000 ppm; or
a concentration of the methyl mercaptan in the primary fuel is at least 20000 ppm and a concentration of the ammonia is at least 1000 ppm on dry basis.

9. The method of claim 1 , comprising controlling an amount of the primary combustion gas and an amount of the primary fuel in such a way that an air-fuel equivalence ratio at the primary process zone is at most 0.95.

10. The method of claim 1 , comprising controlling an amount of the primary combustion gas and an amount of the primary fuel in such a way that an air-fuel equivalence ratio at the primary process zone is less than 0.8.

11. The method of claim 1 , further comprising controlling an amount of the quaternary combustion gas in such a way that an air-fuel equivalence ratio at the tertiary process zone is more than 1.1.

12. The method of claim 1 , further comprising either:
collecting the primary fuel from a pulp process; or
collecting the primary fuel and secondary fuel from the pulp process with the secondary fuel being fed to the secondary process zone of the furnace.

13. The method of claim 1 , further comprising providing mechanical energy to the compressor or the fan by means of a turbine.

14. A pulp mill comprising:
an apparatus for burning primary fuel, the apparatus comprising:
a furnace limited by at least a wall, the furnace having a primary process zone, a tertiary process zone, and a secondary process zone arranged in between the primary process zone and the tertiary process zone,
a combustion gas heater comprising a secondary furnace configured to burn tertiary fuel to produce primary combustion gas,
a primary pipeline for conveying primary combustion gas from the combustion gas heater to the primary process zone,
a first pipeline for conveying primary fuel to the primary process zone,
a tertiary pipeline for conveying tertiary combustion gas to the secondary process zone, and
a quaternary pipeline for conveying quaternary combustion gas to the tertiary process zone,
wherein the combustion gas heater is configured to form primary combustion gas having a temperature of at least 450° C. and the combustion gas heater comprises a compressor or a fan configured to drive primary combustion gas to the furnace; and

at least one of:
(i) an evaporator area to which at least one evaporator has been arranged,
(ii) a digester area to which at least one digester has been arranged, and
(iii) a stripper, and
a collector configured to collect strong odorous gas, such as stripper off gas from the stripper and/or concentrated non-condensable odorous gas from the evaporator area and/or the digester area,
wherein the first pipeline extends from the apparatus to the collector.

15. The pulp mill of claim 14 , wherein:
the collector is a first collector configured to collect stripper off gas from the stripper and the first pipeline extends from the apparatus to the first collector; and
the system comprises a second collector configured to collect concentrated non-condensable odorous gas from the evaporator area and/or the digester area, wherein a second pipeline extends from the apparatus to the second collector and the second pipeline is configured to convey secondary fuel to the secondary process zone.

16. The pulp mill of claim 14 , further comprising a secondary pipeline for conveying secondary combustion gas to the primary process zone.

17. Pulp mill of claim 14 , further comprising a second pipeline for conveying secondary fuel to the secondary process zone.

18. A method for burning primary fuel, wherein the primary fuel comprises at least a first compound containing nitrogen and a second compound comprising sulfur, the method comprising:
producing primary combustion gas having an oxygen content from 7 vol % to 19 vol % by burning a tertiary fuel,
feeding the primary fuel and the primary combustion gas to a primary process zone of a furnace,
feeding tertiary combustion gas to a secondary process zone of the furnace,
letting at least one of the primary fuel, the primary combustion gas, or their reaction products move from the primary process zone via the secondary process zone to a tertiary process zone of the furnace,
feeding quaternary combustion gas comprising oxygen to the tertiary process zone of the furnace,
producing such primary combustion gas that has a temperature of at least 450° C.,
delivering the primary combustion gas to the primary process zone by means of a compressor or a fan, and
controlling an amount of the quaternary combustion gas in such a way that an air-fuel equivalence ratio at the tertiary process zone is more than 1.1.

19. The method of claim 18 , further comprising feeding secondary combustion gas to the primary process zone of the furnace.

20. The method of claim 19 , wherein an oxygen content of the secondary combustion gas is higher than an oxygen content of the primary combustion gas.

21. The method of claim 18 , further comprising feeding secondary fuel to the secondary process zone of the furnace.

22. The method of claim 18 , comprising controlling an amount of the primary combustion gas and an amount of the primary fuel in such a way that an air-fuel equivalence ratio at the primary process zone is at most 0.95.

23. The method of claim 18 , comprising controlling an amount of the primary combustion gas and an amount of the primary fuel in such a

Assignees

• Valmet Technologies Oy

Inventors

• Kytö Matti

Classifications

• F23J2215/20

  Sulfur; Compounds thereof · CPC title

• F23G7/063

  electric heating · CPC title

• D21C11/08 Primary

  Deodorisation {; Elimination of malodorous compounds, e.g. sulfur compounds such as hydrogen sulfide or mercaptans, from gas streams (oxidation of liquors D21C11/0057; post-combustion of gases D21C11/127)} · CPC title

• F23C7/06

  for heating the incoming air (arrangements of regenerators and recuperators F23L15/00) · CPC title

• D21C7/08

  Discharge devices · CPC title