Method and a system for adjusting S/Na-balance of a pulp mill

Patent metadata

Field	Value
Publication number	US-11634864-B2
Application number	US-201816768189-A
Country	US
Kind code	B2
Filing date	Dec 20, 2018
Priority date	Dec 29, 2017
Publication date	Apr 25, 2023
Grant date	Apr 25, 2023

Abstract

The invention relates to a method and a system for adjusting S/Na-balance of a sulphate pulp mill, wherein a pulp mill CNCG stream containing sulphur compounds is first scrubbed with an aqueous scrubbing solution containing an alkaline agent, thereby producing an aqueous spent scrubbing solution containing sulphides, which is then oxidized in a bioreactor by means of sulphur-oxidizing microbes, thereby obtaining an aqueous suspension containing elemental sulphur from which the elemental sulphur can be separated as a precipitate and the residual solution may be used for replenishing the aqueous scrubbing solution.

First claim

The invention claimed is:

1. A method for adjusting S/Na-balance of a sulphate pulp mill, the method comprising:
providing a sulphate pulp mill producing a pulp mill CNCG stream containing sulphur compounds and a gas comprising weak malodorous gas;
transporting, via one or more conduits, the pulp mill CNCG stream containing sulphur compounds from the sulphate pulp mill into a scrubber,
scrubbing the pulp mill CNCG stream containing sulphur compounds in the scrubber with an aqueous scrubbing solution containing an alkaline agent, whereby at least some of the sulphur compounds react with the alkaline agent, thereby producing a CNCG stream derivate and an aqueous spent scrubbing solution containing sulphides,
introducing the aqueous spent scrubbing solution containing sulphides into a bioreactor located downstream of the scrubber,
oxidizing the aqueous spent scrubbing solution containing sulphides in the bioreactor biologically in an oxidizing reaction by means of sulphur-oxidizing microbes, thereby obtaining an aqueous suspension containing elemental sulphur,
separating the elemental sulphur from the aqueous suspension in a sulphur separation unit located downstream of the bioreactor, thereby obtaining a residual solution and a precipitate containing the elemental sulphur, and
aerating the bioreactor with the gas comprising the weak malodorous gas, the weak malodorous gas being directed via at least one conduit connected to the pulp mill, from the pulp mill to the bioreactor.

2. The method according to claim 1 , further comprising directing at least some of the residual solution, from which the precipitate has been separated, back into the scrubber for replenishing the aqueous scrubbing solution.

3. The method according to claim 1 , further comprising directing at least some of the aqueous spent scrubbing solution by a pump back into the scrubber for re-scrubbing.

4. The method according to claim 1 , wherein the pulp mill CNCG stream contains at least one or more of the following: H 2 S, CH 3 SH, CH 3 SCH 3 , CH 3 SSCH 3 .

5. The method according to claim 1 , wherein the pulp mill CNCG stream prior to entering the scrubber has a temperature above room temperature.

6. The method according to claim 5 , wherein the temperature is in the range of 40 to 50° C.

7. The method according to claim 1 , wherein NaOH is added to the aqueous scrubbing solution.

8. The method according to claim 1 , wherein the pH of the aqueous scrubbing solution is above 8.

9. The method according to claim 1 , wherein the pH of the aqueous scrubbing solution is above 11.5.

10. The method according to claim 1 , wherein the pH of the aqueous scrubbing solution is in the range of 12 to 14.

11. The method according to claim 1 , further comprising directing at least some of the CNCG stream derivate from the scrubber into a sulphate pulp mill recovery boiler, thereby enabling recirculation of chemicals from the CNCG stream derivate into a chemical recovery cycle of the sulphate pulp mill.

12. The method according to claim 1 , further comprising directing at least some of the gas stream from the bioreactor into a sulphate pulp mill recovery boiler, thereby enabling recirculation of chemicals from the gas stream into a chemical recovery cycle of the sulphate pulp mill.

13. A system configured to adjust S/Na-balance of a sulphate pulp mill, the system comprising:
one or more conduits connected to a sulphate pulp mill producing a pulp mill CNCG stream containing sulphur compounds and a gas comprising weak malodorous gas, the one or more conduits feeding the pulp mill CNCG stream containing sulphur compounds from the sulphate pulp mill into a scrubber, the scrubber being configured to separate sulphur compounds from the pulp mill CNCG stream with an aqueous scrubbing solution containing an alkaline agent, thereby producing a CNCG stream derivate and an aqueous spent scrubbing solution containing sulphides,
a bioreactor located downstream of the scrubber, the bioreactor being configured to oxidize the aqueous spent scrubbing solution with sulphur-oxidizing microbes, thereby producing an aqueous suspension containing elemental sulphur,
a sulphur separation unit located downstream of the bioreactor, the sulphur separation unit being configured to produce a residual solution and a precipitate containing the elemental sulphur from the aqueous suspension, and
at least one conduit connected to the sulphate pulp mill to direct the gas comprising the weak malodorous gas from the sulphate pulp mill to the bioreactor, the at least one conduit being configured to aerate the bioreactor with the gas comprising the weak malodorous gas from the pulp mill.

14. The system according to claim 13 , the system further comprising a further conduit configured to recirculate at least some of the residual solution, from which the precipitate has been separated, into the scrubber for replenishing the aqueous scrubbing solution.

15. The system according to claim 13 , the system further comprising a pump and a conduit configured to direct at least some of the aqueous spent scrubbing solution back into the scrubber for re-scrubbing.

16. The system according to claim 13 , the system comprising more than one bioreactor.

17. The system according to claim 13 , further comprising at least one conduit connected to a recovery boiler of the sulphate pulp mill to direct CNCG stream derivate from the scrubber into the recovery boiler, thereby enabling recirculation of chemicals from the CNCG stream derivate into a chemical recovery cycle of the sulphate pulp mill.

18. The system according to claim 13 , further comprising at least one conduit connected to a recovery boiler of the sulphate pulp mill to direct gas stream from the bioreactor into the recovery boiler, thereby enabling recirculation of chemicals from the gas stream into a chemical recovery cycle of the sulphate pulp mill.

Assignees

• Valmet Technologies Oy

Inventors

• Hämäläinen Risto
• Tuominiemi Seppo

Classifications

• D21C11/0057

  Oxidation of liquors, e.g. in order to reduce the losses of sulfur compounds, followed by evaporation or combustion if the liquor in question is a black liquor (deodorisation of gases D21C11/08; combustion D21C11/12, D21C11/14) · CPC title

• D21C11/08 Primary

  Deodorisation {; Elimination of malodorous compounds, e.g. sulfur compounds such as hydrogen sulfide or mercaptans, from gas streams (oxidation of liquors D21C11/0057; post-combustion of gases D21C11/127)} · CPC title

• D21C11/06 Primary

  Treatment of pulp gases; Recovery of the heat content of the gases; {Treatment of gases arising from various sources in pulp and paper mills; Regeneration of gaseous SO2, e.g. arising from liquors containing sulfur compounds} · CPC title

• D21C11/0014

  Combination of various pulping processes with one or several recovery systems (cross-recovery) · CPC title

• D21C11/0007

  Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for (volatile compounds obtained by decomposition of spent liquors in order to regenerate them D21C11/125; compounds obtained by fractionating the liquors in order to regenerate them D21C11/0042) · CPC title