System and method for flexible conversion of feedstock to oil and gas

Patent metadata

Field	Value
Publication number	US-11479727-B2
Application number	US-201214355948-A
Country	US
Kind code	B2
Filing date	Nov 5, 2012
Priority date	Nov 4, 2011
Publication date	Oct 25, 2022
Grant date	Oct 25, 2022

Abstract

A feedstock flexible process for converting feedstock into oil and gas includes (i) indirectly heated hydrous devolatilization of volatile feedstock components, (ii) indirectly heated thermochemical conversion of fixed carbon feedstock components, (iii) heat integration and recovery, (iv) vapor and gas pressurization, and (v) vapor and gas clean-up and product recovery. A system and method for feedstock conversion includes a thermochemical reactor integrated with one or more hydrous devolatilization and solids circulation subsystems configured to accept a feedstock mixture, comprised of volatile feedstock components and fixed carbon feedstock components, and continuously produce a volatile reaction product stream therefrom, while simultaneously and continuously capturing, transferring, and converting the fixed carbon feedstock components to syngas.

First claim

What is claimed is:

1. A feedstock conversion process for simultaneously producing synthetic crude oil and syngas from first and second feedstocks ( 1590 a & 1590 b ), the process comprising:
subjecting, in a first chamber ( 1000 a ), the first feedstock ( 1590 a ) to a first indirectly-heated hydrous devolatilization process using steam as a fluidization medium and operating under a first set of processing conditions, to produce a first coarse mixed stream ( 1610 a ) containing char and first volatile reaction products ( 1375 a );
subjecting, in a second chamber ( 1000 b ), the second feedstock ( 1590 b ) to a second indirectly-heated hydrous devolatilization process using steam as a fluidization medium and operating under a second set of processing conditions to produce a second coarse mixed stream ( 1610 b ) containing char and second volatile reaction products ( 1375 b );
separating volatile reaction products ( 1375 a , 1375 b ) from char in the first coarse mixed stream ( 1610 a ) and the second coarse mixed stream ( 1610 b ) to create a first fine mixed stream ( 1380 a ) and a second fine mixed stream ( 1380 b ) and a first char stream ( 1360 a ) and a second char stream ( 1360 b );
inputting the first char stream ( 1360 a ) into a common reactor ( 1500 ) via a first conduit ( 1355 a ), and introducing the second char stream ( 1360 b ) into the common reactor ( 1500 ) via a second conduit ( 1355 b ), and converting the first char stream ( 1360 a ) and the second char stream ( 1360 b ) into syngas via an indirectly heated thermochemical process of steam reforming, partial oxidation, or both; and
condensing at least a portion of both the first and second volatile reaction products ( 1375 a , 1375 b ) from the first and second fine mixed streams ( 1380 a , 1380 b ), to produce synthetic crude oil;
wherein:
the first and second feedstocks ( 1590 a & 1590 b ) differ from one another in composition and moisture content.

2. The feedstock conversion process according to claim 1 , further comprising:
varying the composition or type of feedstock ( 1590 a , 1590 b ) during uninterrupted operation of the conversion process.

3. A feedstock conversion process for simultaneously producing synthetic crude oil and syngas from a carbonaceous feedstock ( 1590 a ) comprising fixed carbon feedstock components ( 1590 x , 1590 xa ) and volatile feedstock components ( 1590 y , 1590 ya ), the process comprising:
(a) introducing the carbonaceous feedstock ( 1590 a ) into a devolatilization chamber ( 1000 a ) having bed solids ( 1520 );
(b) in the devolatilization chamber, reacting the volatile feedstock components with steam ( 1630 a ) at a temperature of about 320° C. to about 569.99° C. to produce:
(i) an intermediate solids mixture ( 1655 a ) comprising bed solids ( 1520 ) and the fixed carbon feedstock components ( 1590 xa ); and
(ii) a coarse mixed stream ( 1610 a ) comprising volatile reaction products ( 1375 a ) and char;

(c) separating the volatile reaction products ( 1375 a ) from char in the first coarse mixed stream ( 1610 a ) to create a char stream ( 1360 a ) and a fine mixed stream ( 1380 a ) containing volatile reaction products ( 1375 a );
(d) transferring the intermediate solids mixture ( 1655 a ) and char stream ( 1360 a ) into a fluidized bed reactor ( 1500 ) already containing some bed solids ( 1520 );
(e) in the fluidized bed reactor ( 1500 ), reacting the char stream ( 1360 a ) and the fixed carbon feedstock components ( 1590 x ) within the intermediate solids mixture ( 1655 a ), with steam and oxygen, to produce a particulate-laden syngas stream ( 1600 ) containing syngas and fly-ash solids;
(f) transferring a portion of the bed solids ( 1520 ) in the fluidized bed reactor ( 1500 ) into the devolatilization chamber ( 1000 a ); and
(g) condensing at least a portion of the volatile reaction products ( 1375 a ) from the coarse mixed stream ( 1610 a ) to produce synthetic crude oil.

4. The feedstock conversion process according to claim 3 , comprising in step (d),
transferring the intermediate solids mixture ( 1655 a ) into the fluidized bed reactor ( 1500 ) via a gas solids flow regulator ( 1505 a ) into which a vapor or gas ( 1412 a ) is introduced.

5. The feedstock conversion process according to claim 4 , comprising:
in step (d), transferring the intermediate solids mixture ( 1655 a ) and char stream ( 1360 a ) into said fluidized bed reactor ( 1500 ) via separate inputs ( 1440 a , 1355 a ) into said reactor ( 1500 ).

6. The feedstock conversion process according to claim 4 , comprising:
in step (b), separating the intermediate solids mixture ( 1655 a ) from the coarse mixed stream ( 1610 a ); and
in step (d), introducing the intermediate solids mixture ( 1655 a ) and said char stream ( 1360 a ) separated out of the coarse mixed stream ( 1610 a ), into the bed solids ( 1520 ) of the fluidized bed of the reactor ( 1500 ).

7. The feedstock conversion process according to claim 3 , comprising in step (e):
from gas and solids present in a freeboard zone ( 1560 ) of the fluidized bed reactor ( 1500 ), separating particulate-laden syngas from char ( 1522 ) and bed solids ( 1520 ), to form said particulate-laden syngas stream ( 1600 ); and
recycling said char ( 1522 ) and bed solids ( 1520 ) back into the bed of the fluidized bed reactor ( 1500 );
wherein said freeboard zone ( 1560 ) is positioned within the fluidized bed reactor ( 1500 ) above a dense fluid bed ( 1510 ).

8. The feedstock conversion process according to claim 3 , comprising:
removing fly-ash solids from the particulate-laden syngas stream ( 1600 ) to form a particulate-depleted syngas-stream ( 1910 ); and
cooling the particulate-depleted syngas-stream ( 1910 ).

9. The feedstock conversion process according to claim 3 , comprising:
after step (c) and before step (d), cooling the fine mixed stream ( 1380 a ) to above a dew point of condensable vapors contained therein.

10. The feedstock conversion process according to claim 9 , comprising:
introducing carbon dioxide into the fluidized bed reactor ( 1500 ) to react char in the char stream ( 1360 a ) to produce syngas for said particulate-laden syngas stream ( 1600 ).

11. The feedstock conversion process according to claim 3 , comprising:
after step (e) removing fly-ash solids from the particulate-laden syngas stream ( 1600 ) to form a particulate-depleted syngas-stream ( 1910 ).

12. The feedstock conversion process according to claim 11 , comprising:
introducing carbon dioxide into the fluidized bed reactor ( 1500 ) to react char in the char stream ( 1360 a ) to produce syngas for said particulate-laden syngas stream ( 1600 ).

13. The feedstock conversion process according to claim 3 , comprising:
introducing carbonaceous feedstock ( 1590 a ) into the devolatilization chamber ( 1000 a ) at a throughput ranging from about 20 tons per day to about 250 tons per day.

14. The feedstock conversion process according to claim 3 , wherein in step (b):
the carbonaceous feedstock ( 1590 a ) is reacted with steam ( 1630 a ) at a pressure of about 0.65 bar to about 2 bar.

15. The feedstock conversion process according to claim 14 , comprising:
operating the fluid bed reactor at a higher pressure than the devolatilization chamber.

16. The feedstock conversion process according to claim 15 , wherein:
a ratio of the pressure of the fluid bed reactor to the pressure of the devolatilization ch

Assignees

• Thermochem Recovery Int Inc

Inventors

• Chandran Ravi
• Leo Daniel Michael
• Freitas Shawn Robert

Classifications

• C10J2300/0916

  Biomass · CPC title

• C10K3/06

  by mixing with gases · CPC title

• C10J3/62

  with separate withdrawal of the distillation products · CPC title

• C10J2300/0946

  Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale · CPC title

• C10G1/02

  by distillation · CPC title