Method and system for recycling carbon dioxide from biomass gasification

Patent metadata

Field	Value
Publication number	US-9469820-B2
Application number	US-201514607020-A
Country	US
Kind code	B2
Filing date	Jan 27, 2015
Priority date	Aug 9, 2012
Publication date	Oct 18, 2016
Grant date	Oct 18, 2016

Abstract

A method for recycling carbon dioxide from biomass gasification. The method includes: 1) employing carbon dioxide as a gasifying agent, allowing the carbon dioxide to gasify biomass to yield syngas; 2) cooling the syngas; 3) introduced cooled syngas to a cyclone separator and a gas scrubber for dust removal and purification; 4) allowing purified syngas in 3) to react with the vapor to modify a ratio of hydrogen to carbon monoxide of the syngas; 5) desulfurizing modified syngas to remove H 2 S and COS therein; 6) decarburizing desulfurized syngas to separate carbon dioxide therein; 7) introducing desulfurized and decarburized syngas to a synthesizing tower to yield oil products and exhaust gas including carbon dioxide; 8) decarburizing the exhaust gas including carbon dioxide and separating the carbon dioxide; and 9) introducing the carbon dioxide separated in 6) and 8) to 1) as the gasifying agent for gasification.

First claim

The invention claimed is:

1. A method of biomass gasification by utilizing carbon dioxide as a gasifying agent, the method comprising:
1) allowing the carbon dioxide to gasify biomass in a gasifier in the presence of external energy, whereby yielding syngas comprising CO, CO 2 , CH 4 , H 2 , H 2 O, H 2 S, and COS;
2) cooling the syngas from 1) in a primary heat exchanger by using carbon dioxide as a cooling medium, whereby the carbon dioxide is heated by the syngas to a temperature of between 350 and 600° C.;
3) cooling the syngas from 2) in a secondary heat exchanger by using water as a cooling medium whereby producing water vapor;
4) feeding carbon dioxide from 2) to the gasifier;
5) introducing the syngas from 3) to a cyclone separator and a gas scrubber for dust removal and purification;
6) contacting the syngas from 5) with the water vapor so that part of carbon monoxide in the syngas reacts with the water vapor to produce hydrogen and carbon dioxide;
7) removing H 2 S and COS from the syngas from 6) to obtain a desulfurized syngas;
8) removing carbon dioxide from the desulfurized syngas to obtain a desulfurized and decarburized syngas;
9) introducing the desulfurized and decarburized syngas to a synthesizing tower, wherein the desulfurized and decarburized syngas is catalyzed to yield oil and exhaust gas comprising carbon dioxide;
10) separating carbon dioxide from the exhaust gas from 9) to obtain an effluent gas free of carbon dioxide, and discharging the effluent gas; and
11) introducing the carbon dioxide obtained in 8) and the carbon dioxide obtained in 10) to the primary heat exchanger as the cooling medium.

2. The method of claim 1 , wherein in 1), a gasification temperature is between 600 and 1300° C., and an outlet temperature of the syngas is between 700 and 1100° C.

3. The method of claim 2 , wherein in 1), the gasification temperature is between 850 and 1250° C., and the outlet temperature of the syngas is between 850 and 1100° C.

4. The method of claim 1 , wherein the external energy is plasma torch, microwave energy, solar energy, laser energy, electric induction energy, or a mixture thereof, and the external energy fed to the gasifier in a unit time accounts for 10-30% of the total energy of fuel fed to the gasifier in the unit time.

5. The method of claim 3 , wherein the external energy is plasma torch, microwave energy, solar energy, laser energy, electric induction energy, or a mixture thereof, and the external energy fed to the gasifier in a unit time accounts for 10-30% of the total energy of fuel fed to the gasifier in the unit time.

6. The method of claim 4 , wherein the external energy fed to the gasifier in a unit time accounts for 15-20% of the total energy of fuel fed to the gasifier in the unit time.

7. The method of claim 5 , wherein the external energy fed to the gasifier in a unit time accounts for 15-20% of the total energy of fuel fed to the gasifier in the unit time.

8. The method of claim 1 , wherein in 1), a ratio of the carbon dioxide to the syngas is between 0.36 and 0.51.

9. The method of claim 1 , wherein in 1), the biomass has a particle size of less than 50 mm, and the carbon dioxide has a flow rate of between 30 and 60 m/s.

10. The method of claim 1 , wherein in 6), a ratio of hydrogen to carbon monoxide in the syngas is 2:1 after part of carbon monoxide of in the syngas reacts with the water vapor.

Assignees

• Wuhan Kaidi Eng Tech Res Inst

Inventors

• Zhang Yanfeng
• Zhang Liang
• Xia Minggui
• Liu Wenyan

Classifications

• C10J3/482 Primary

  Gasifiers with stationary fluidised bed · CPC title

• C10J2300/1693

  with storage facilities for intermediate, feed and/or product · CPC title

• C10G2/32 Primary

  with the use of catalysts · CPC title

• C10J2300/1659

  to liquid hydrocarbons · CPC title

• C10J2300/1861

  Heat exchange between at least two process streams · CPC title