Methods of preparing a catalyst

Patent metadata

Field	Value
Publication number	US-11472897-B2
Application number	US-202117518042-A
Country	US
Kind code	B2
Filing date	Nov 3, 2021
Priority date	Dec 29, 2016
Publication date	Oct 18, 2022
Grant date	Oct 18, 2022

Abstract

A hydrogel comprising water, and a plurality of titanium-silica nanoparticle agglomerates, wherein each titanium-silica nanoparticle agglomerate is an agglomeration of titanium-silica nanoparticles, the agglomerates having an average titanium loading designated x with a coefficient of variation for the average titanium loading of less than about 1.0, wherein a silica content of the hydrogel is of from about 10 wt. % to about 35 wt. % based on a total weight of the hydrogel.

First claim

What is claimed is:

1. A hydrogel comprising:
water; and
a plurality of titanium-silica nanoparticle agglomerates, wherein each titanium-silica nanoparticle agglomerate is an agglomeration of titanium-silica nanoparticles, the agglomerates having an average titanium loading designated x with a coefficient of variation for the average titanium loading of less than about 1.0,
wherein a silica content of the hydrogel is in a range of from about 18 wt. % to about 35 wt. % based on a total weight of the hydrogel.

2. The hydrogel of claim 1 wherein the titanium-silica nanoparticles have a coefficient of variation of the average titanium penetration depth of from about 0.1 to about 0.9.

3. The hydrogel of claim 1 wherein the titanium-silica nanoparticles have an average particle size of from about 4 to about 7 nanometers.

4. The hydrogel of claim 3 wherein a coefficient of variation for the average particle size of the titanium-silica nanoparticles is less than about 1.

5. The hydrogel of claim 1 having an x value of from about 0.25 wt. % to about 8 wt. % based on the total weight of the hydrogel.

6. The hydrogel of claim 1 having an x value of from about 1 titanium atoms/sqnm to less than about 4 titanium atoms/sqnm.

7. The hydrogel of claim 1 having a mL pore water in the pores of the hydrogel, per g of silica of from about 1.9 cm 3 /g to about 4.6 cm 3 /g.

8. The hydrogel of claim 1 wherein the titanium-silica nanoparticle agglomerates are formed from an acidic titanium solution comprising a trivalent titanium, tetravalent titanium, titania, or a combination thereof.

9. The hydrogel of claim 8 wherein the acidic titanium solution comprises TiCl 4 , TiOSO 4 , TiBr 4 , TiOCl 2 , TiOBr 2 , TiO 2 , TiO(oxylate) 2 , or a combination thereof.

10. The hydrogel of claim 8 wherein the acidic titanium solution comprises Ti 2 (SO 4 ) 3 ,Ti(OAc) 3 ,Ti(oxylate) 3 , Ti(NO 3 ) 3 , or a combination thereof.

11. The hydrogel of claim 8 wherein the acidic titanium solution comprises hydrochloric acid, hydrobromic acid, sulfuric acid, nitric acid, phosphoric acid, perchloric acid, sulfamic acid, or a combination thereof.

12. The hydrogel of claim 1 wherein titanium is present in an amount from about 0.01 wt. % to about 10 wt. % titanium based on the total weight of the hydrogel.

13. The hydrogel of claim 1 further comprising a chromium-containing compound.

14. The hydrogel of claim 13 wherein the chromium-containing compound comprises a water-soluble chromium compound, a hydrocarbon-soluble chromium compound, a chromium (II) compound, a chromium (III) compound, or a combination thereof.

15. The hydrogel of claim 13 wherein the chromium-containing compound comprises chromium carboxylates, chromium naphthenates, chromium halides, chromium pyrrolides, chromium benzoates, chromium dionates, chromium nitrates, chromium sulfates, or a combination thereof.

16. The hydrogel of claim 13 wherein the chromium-containing compound comprises chromium (III) isooctanoate, chromium (III) 2,2,6,6-tetramethylheptanedionate, chromium (III) naphthenate, chromium (III) chloride, chromium (III) tris(2-ethylhexanoate), chromic fluoride, chromium (III) oxy-2-ethylhexanoate, chromium (III) dichloroethylhexanoate, chromium (III) acetylacetonate, chromium (III) acetate, chromium (III) butyrate, chromium (III) neopentanoate, chromium (III) laurate, chromium (III) sulfate, chromium (III) oxalate, chromium (III) benzoate, chromium (III) pyrrolide(s), chromium (III) perchlorate, chromium (III) chlorate, or a combination thereof.

17. The hydrogel of claim 13 wherein the chromium-containing compound comprises chromous fluoride, chromous chloride, chromous bromide, chromous iodide, chromium (II) bis(2-ethylhexanoate), chromium (II) acetate, chromium (II) butyrate, chromium (II) neopentanoate, chromium (II) laurate, chromium (II) stearate, chromium (II) oxalate, chromium (II) benzoate, chromium (II) pyrrolide(s), chromous sulfate, or a combination thereof.

18. The hydrogel of claim 13 wherein the chromium-containing compound comprises tertiary butyl chromate in a hydrocarbon liquid; chromium trioxide in water; chromium acetate in water; chromium nitrate in alcohol; zerovalent organochromium; or a combination thereof.

19. The hydrogel of claim 13 wherein chromium is present in an amount of about 0.01 wt. % to about 10 wt. % based on the total weight of the hydrogel.

20. The hydrogel of claim 1 wherein the agglomerates of titanium-silica nanoparticles have an average agglomerate particle size of from about 40 microns to about 200 microns.

Assignees

• Chevron Phillips Chemical Co Lp

Inventors

• Mcdaniel Max P
• Schwerdtfeger Eric D
• Praetorius Jeremy M

Classifications

• C08F2410/06

  Catalyst characterized by its size · CPC title

• C08F4/18

  Oxides · CPC title

• C08F4/24

  Oxides · CPC title

• C08F10/00 Primary

  Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• C08F110/02 Primary

  Ethene · CPC title