Process for drying polysaccharides

Patent metadata

Field	Value
Publication number	US-11466932-B2
Application number	US-201816649326-A
Country	US
Kind code	B2
Filing date	Sep 27, 2018
Priority date	Sep 28, 2017
Publication date	Oct 11, 2022
Grant date	Oct 11, 2022

Abstract

The present invention is directed to a process for drying a material comprising at least one polysaccharide, said process comprising a step wherein the material is submitted to microwave irradiations under conditions which do not degrade said polysaccharide.

First claim

The invention claimed is:

1. A process for drying a material comprising at least one polysaccharide, said process comprising a step wherein the material is submitted to microwave irradiations with a reduced pressure ranging from 1 mbar to 500 mbar under conditions which do not degrade said polysaccharide, wherein the polysaccharide is selected from the group consisting of guar gum, nonionic guar derivatives, amphoteric guar derivatives, cationic guar derivatives, anionic guar derivatives and any combination thereof.

2. The process according to claim 1 , wherein the material comprises, before being submitted to microwave irradiations, at least 20% by weight of the at least one polysaccharide, based on a total weight of the material.

3. The process according to claim 1 , wherein the material further comprises, before being submitted to microwave irradiations, at least one solvent.

4. The process according to claim 3 , wherein the at least one solvent is selected from solvents characterized by tan δ of higher than 0.1, measured at 2450 MHz at 25° C.

5. The process according to claim 3 , wherein the at least one solvent is selected from water, alcohols, organosulfur solvents, organohalogenated solvents, carboxylic acids, and apolar amine solvents.

6. The process according to claim 3 , wherein the material comprises, before being submitted to microwave irradiations, from 5 to 80% by weight of the at least one solvent, based on a total weight of the material.

7. The process according to claim 1 , wherein a microwave power density received by the material ranges from 0.001 to 10 kW/kg.

8. The process according to claim 1 , wherein the process is performed at a temperature ranging from −10° C. to 100° C.

9. The process according to claim 1 , wherein guar derivatives are selected from cationic guar derivatives and anionic guar derivatives.

10. The process according to claim 1 , wherein the polysaccharide has a number-average molecular weight greater than or equal to 50,000 g/mol.

11. The process according to claim 1 , wherein the polysaccharide has a weight-average molecular weight greater than or equal to 50,000 g/mol.

12. The process according to claim 2 , wherein the material comprises, before being submitted to microwave irradiations, at least 30% by weight of the at least one polysaccharide, based on the total weight of the material.

13. The process according to claim 4 , wherein the at least one solvent is selected from solvents characterized by a tan δ of higher than or equal to 0.3, measured at 2450 MHz at 25° C.

14. The process according to claim 6 , wherein the material comprises, before being submitted to microwave irradiations, from 10 to 70% by weight of the at least one solvent, based on the total weight of the material.

15. The process according to 7 , wherein the microwave power density received by the material ranges from 0.005 to 1 kW/kg.

16. The process according to claim 8 , wherein the process is performed at a temperature ranging from 0° C. to 80° C.

17. The process according to claim 10 , wherein the polysaccharide has a number-average molecular weight ranging from 50,000 g/mol to 3,000,000 g/mol.

Assignees

• Rhodia Operations

Inventors

• Baussaron Loïc
• Luczak Kraig
• Kirkpatrick Paul

Classifications

• C08B37/0096

  Guar, guar gum, guar flour, guaran, i.e. (beta-1,4) linked D-mannose units in the main chain branched with D-galactose units in (alpha-1,6), e.g. from Cyamopsis Tetragonolobus; Derivatives thereof · CPC title

• F26B9/06

  in stationary drums or chambers · CPC title

• A23L29/238

  from seeds, e.g. locust bean gum or guar gum (starch A23L29/212; pectin A23L29/231) · CPC title

• F26B25/006

  Separating volatiles, e.g. recovering solvents from dryer exhaust gases · CPC title

• F26B5/048 Primary

  in combination with heat developed by electro-magnetic means, e.g. microwave energy · CPC title