Polymers and the use thereof as lubricating agents in the production of alkali metal films

Patent metadata

Field	Value
Publication number	US-11453835-B2
Application number	US-202016946048-A
Country	US
Kind code	B2
Filing date	Jun 4, 2020
Priority date	Apr 1, 2014
Publication date	Sep 27, 2022
Grant date	Sep 27, 2022

Abstract

Polymers used as rolling lubricating agents, to compositions including said polymers, and to alkali metal films including the polymers or compositions on the surface(s) thereof. The use of said polymers and compositions is also described for strip-rolling alkali metals or alloys thereof in order to obtain thin films. Methods for producing said thin films, which are suitable for use in electrochemical cells, are also described. An improved lubricant according to formula I, which, for example, achieves enhanced conductivity, and/or enables the production of electrochemical cells having an improved life span in cycles.

First claim

The invention claimed is:

1. An alkali metal film having a first surface and a second surface, and comprising on at least one of the first and second surfaces, a thin layer of a lubricating agent, the lubricating agent consisting of a polymer of Formula I:

wherein,
m and n denote the number of repeated units A and B, respectively, in the polymer; m being a positive whole number and n being a positive whole number or zero when the repeated unit B is absent, and where m and n are selected so that the molecular weight of the polymer of Formula I is in the range from 1000 to 10 6 ;
R 1 is independently at each occurrence selected from linear or branched monovalent hydrocarbon radicals;
R 2 is independently at each occurrence selected from —CH 2 CH 2 O— and —CH 2 CH 2 CH 2 O—, where R 2 is bound to N by a carbon atom, or R 2 is absent and N is covalently bound to R 4 ;
R 3 is independently at each occurrence selected from the linear or branched monovalent hydrocarbon radicals;
R 4 is independently at each occurrence a polyether residue of formula —[CH(R 5 )CH 2 O] s CH 3 , wherein 5≤s≤100; and
R 5 is independently at each occurrence a hydrogen atom or a CH 3 group.

2. The alkali metal film of claim 1 , wherein m and n are selected so that the molecular weight of the lubricating agent of Formula I is in the range from 2000 to 250,000.

3. The alkali metal film of claim 2 , wherein m and n are selected so that the molecular weight of the lubricating agent of Formula I is in the range from 2000 to 50,000.

4. The alkali metal film of claim 2 , wherein m and n are selected so that the molecular weight of the lubricating agent of Formula I is in the range from 50,000 to 200,000.

5. The alkali metal film of claim 1 , wherein R 1 is independently at each occurrence a linear or branched hydrocarbon radical of formula C r H 2r+1 , wherein 4≤r≤24.

6. The alkali metal film of claim 1 , wherein R 1 is independently at each occurrence a linear or branched hydrocarbon radical of formula C r H 2r+1 , wherein 8≤r≤18.

7. The alkali metal film of claim 1 , wherein R 3 is independently at each occurrence a linear or branched hydrocarbon radical of formula C t H 2t+1 , wherein 4≤t≤24.

8. The alkali metal film of claim 1 , wherein R 3 is independently at each occurrence a linear or branched hydrocarbon radical of formula C t H 2t+1 , wherein 8≤t≤18.

9. The alkali metal film of claim 1 , wherein 8≤s≤50.

10. The alkali metal film of claim 1 , wherein the ratio of the repeated units A:B expressed as mole percent in the polymer is in the range from 100:0 to 10:90.

11. The alkali metal film of claim 1 , wherein R 2 is a divalent radical of formula —CH 2 CH 2 O—.

12. The alkali metal film of claim 1 , wherein R 2 is a divalent radical of formula —CH 2 CH 2 CH 2 O—.

13. The alkali metal film of claim 1 , wherein R 2 is absent.

14. The alkali metal film of claim 1 , wherein R 4 is selected from:
(a) a polyether residue of formula —[CH(R 5 )CH 2 O] s CH 3 , wherein R 5 is CH 3 at each occurrence;
(b) a polyether residue of formula —[CH(R 5 )CH 2 O] s CH 3 , wherein R 5 is a hydrogen at each occurrence; and
(c) a polyether residue of formula —[CH(R 5 )CH 2 O] s CH 3 , and in which R 5 is independently at each occurrence CH 3 or hydrogen, such that R 4 is a polyether residue including repeated units of propylene oxide (PO) and of ethylene oxide (EO).

15. The alkali metal film of claim 14 , wherein the polyether residue has a molar ratio of PO:EO between about 20:1 and about 1:30.

16. The alkali metal film of claim 15 , wherein the molar ratio of PO:EO is between about 10:1 and about 1:10.

17. The alkali metal film of claim 14 , wherein the polyether residue has a molecular weight between about 300 g/mole and about 5000 g/mole.

18. The alkali metal film of claim 14 , wherein the polyether residue has a molecular weight between about 500 g/mole and about 2500 g/mole.

19. The alkali metal film of claim 2 , having a thickness in the range from about 5 μm to about 50 μm.

20. The alkali metal film of claim 2 , wherein said alkali metal is selected from lithium, lithium alloys, sodium, and sodium alloys.

21. The alkali metal film of claim 20 , wherein the alkali metal is lithium having a purity of at least 99% by weight, or a lithium alloy including at least 3000 ppm of impurities by weight.

22. The alkali metal film of claim 2 , further comprising a passivation layer on at least one of the first and second surfaces thereof.

23. The alkali metal film of claim 2 , further comprising a passivation layer on the first and second surfaces thereof.

24. The alkali metal film of claim 22 , wherein the passivation layer has a thickness of 100 Å or less or of 50 Å or less.

25. The alkali metal film of claim 22 , wherein the alkali metal is lithium or a lithium alloy, and the passivation layer includes Li 2 O, Li 2 CO 3 , LiOH or a combination of at least two thereof.

26. The alkali metal film of claim 1 , further comprising a solvent that is inert with respect to alkali metals.

27. The alkali metal film of claim 2 , further comprising a solvent that is inert with respect to alkali metals.

Assignees

• Hydro Quebec

Inventors

• Zaghib Karim
• Armand Michel
• Bouchard Patrick
• Verreault Serge
• Hamel-Pâquet Julie
• Girard Gabriel

Classifications

• Y02E60/50

  Fuel cells · CPC title

• H01M4/628

  Inhibitors, e.g. gassing inhibitors, corrosion inhibitors · CPC title

• H01M4/405

  Alloys based on lithium · CPC title

• H01M4/366

  as layered products · CPC title

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title