Ultraviolet curable resin composition, sliding member, and method for producing sliding member

Patent metadata

Field	Value
Publication number	US-10053645-B2
Application number	US-201615278456-A
Country	US
Kind code	B2
Filing date	Sep 28, 2016
Priority date	Apr 26, 2012
Publication date	Aug 21, 2018
Grant date	Aug 21, 2018

Abstract

There is provided a resin composition for a machinable liner of a sliding member. An ultraviolet curable resin composition for a self-lubricating liner contains a (meth)acrylate compound having an isocyanuric acid ring represented by the following formula and PTFE as a solid lubricant. In the formula (1), X is a group which contains an acryloyl group and is composed only of C, H, and O. Y and Z are groups each composed only of C, H, and O. PTFE is contained in an amount of 10 to 50% by weight with respect to a total amount of the ultraviolet curable resin composition. The ultraviolet curable resin composition is suitable for a self-lubricating liner 24 of a spherical bearing 20 having an outer race 22 and an inner race 26 .

First claim

What is claimed is:

1. An ultraviolet curable resin composition for a self-lubricating liner, comprising:
fumed silica in an amount of 5% by weight or less with respect to the total amount of the ultraviolet curable resin composition;
a polytetrafluoroethylene resin as a solid lubricant in an amount of 10% to 50% by weight with respect to the total amount of the ultraviolet curable resin composition;
a photopolymerization initiator in an amount of 0.01% to 5% by weight with respect to the total amount of the ultraviolet curable resin composition;
a (meth)acrylate compound having an isocyanuric acid ring in an amount of 20% to 85.5% by weight with respect to the total amount of the ultraviolet curable resin composition,
wherein the (meth)acrylate compound having the isocyanuric acid ring is selected from the group consisting of di-(2-acryloxyethyl) isocyanurate, tris-(2-acryloxyethyl) isocyanurate, ε-caprolactone modified tris-(2-acryloxyethyl) isocyanurate, and a mixture of the di-(2-acryloxyethyl) isocyanurate and the tris-(2-acryloxyethyl) isocyanurate;
optionally, melamine cyanurate in an amount of 30% by weight or less with respect to the total amount of the ultraviolet curable resin composition;
optionally, at least one selected from the group consisting of bisphenol A-type epoxy acrylate, hydroxyethyl(meth)acrylate, isobornyl (meth)acrylate, pentaerythritol triacrylate, and dipentaerythritol hexa(meth)acrylate in an amount of 30% by weight or less with respect to the total amount of the ultraviolet curable resin composition; and
optionally, glass fiber in an amount of 15% by weight or less with respect to the total amount of the ultraviolet curable resin composition,
wherein the combined amount of the (meth)acrylate compound having the isocyanuric acid ring, the polytetrafluoroethylene resin as a solid lubricant, the photopolymerization inhibitor, the fumed silica, the melamine cyanurate, the at least one selected from the group consisting of bisphenol A-type epoxy acrylate, hydroxyethyl(meth)acrylate, isobornyl (meth)acrylate, pentaerythritol triacrylate, and dipentaerythritol hexa(meth)acrylate, and the glass fiber is 92.0% by weight or greater with respect to the total amount of the ultraviolet curable resin composition.

2. The ultraviolet curable resin composition according to claim 1 , wherein the (meth)acrylate compound having the isocyanuric acid ring is a mixture of di-(2-acryloxyethyl) isocyanurate and tris-(2-acryloxyethyl) isocyanurate, or ε-caprolactone modified tris-(2-acryloxyethyl) isocyanurate.

3. The ultraviolet curable resin composition according to claim 1 , further comprising melamine cyanurate in an amount of 30% by weight or less with respect to the total amount of the ultraviolet curable resin composition.

4. The ultraviolet curable resin composition according to claim 1 , wherein the polytetrafluoroethylene resin is in a powder form having an average particle diameter ranging from 75 μm to 180 μm.

5. The ultraviolet curable resin composition according to claim 1 , wherein the polytetrafluoroethylene resin is a polytetrafluoroethylene resin surface-treated by epoxy modified acrylate.

6. The ultraviolet curable resin composition according to claim 1 , wherein the polytetrafluoroethylene resin is present in an amount of 30% by weight to 50% by weight with respect to the total amount of the ultraviolet curable resin composition.

7. The ultraviolet curable resin composition according to claim 1 , further comprising a thermosetting agent.

8. The ultraviolet curable resin composition according to claim 1 , further comprising at least one selected from the group consisting of bisphenol A-type epoxy acrylate, hydroxyethyl(meth)acrylate, isobornyl (meth)acrylate, pentaerythritol triacrylate, and dipentaerythritol hexa(meth)acrylate.

9. The ultraviolet curable resin composition according to claim 1 , further comprising urethane acrylate.

10. The ultraviolet curable resin composition according to claim 1 , further comprising ethylene glycol di(meth)acrylate.

11. The ultraviolet curable resin composition according to claim 1 , further comprising glass fiber.

12. The ultraviolet curable resin composition according to claim 7 , wherein the thermosetting agent is an organic peroxide or azo compound.

13. The ultraviolet curable resin composition according to claim 12 , wherein the thermosetting agent is the azo compound.

14. The ultraviolet curable resin composition according to claim 1 , wherein the (meth)acrylate compound having the isocyanuric acid ring is ε-caprolactone modified tris-(2-acryloxyethyl) isocyanurate.

15. The ultraviolet curable resin composition according to claim 1 , further comprising at least one selected from the group consisting of hydroxyethyl(meth)acrylate and isobornyl (meth)acrylate.

16. A self-lubricating liner made of the ultraviolet curable resin composition for the self-lubricating liner defined in claim 1 .

17. A method for forming a self-lubricating liner on a surface of an object comprising:
applying the ultraviolet curable resin composition defined in claim 1 on the surface of the object; and
curing the ultraviolet curable resin composition by irradiation with ultraviolet rays to form the self-lubricating liner on the surface of the object.

Assignees

• Minebea Co Ltd

Inventors

• Karaki Tadahiko
• Matsumoto Kunihiro
• Sagiyama Koichiro

Classifications

• C10N2050/08

  Solids · CPC title

• C10N2040/02

  Bearings · CPC title

• F16C33/208

  Methods of manufacture, e.g. shaping, applying coatings · CPC title

• C10M2215/305

  used as base material · CPC title

• C10M125/28

  Glass · CPC title