Alkene generation using metal sulfide particles

Patent metadata

Field	Value
Publication number	US-11453626-B2
Application number	US-202017602889-A
Country	US
Kind code	B2
Filing date	Apr 8, 2020
Priority date	Apr 9, 2019
Publication date	Sep 27, 2022
Grant date	Sep 27, 2022

Abstract

Systems and methods include providing a gaseous alkane input stream and metal sulfide (MSx) particles that can react with an alkane in the gaseous alkane input stream to generate an alkene, a reduced metal sulfide (MSx-1) particle, and at least one of: hydrogen sulfide (H2S) and at least one sulfur containing compound selected from: S2, CS, and CS2. A product stream can be collected that includes the alkene and at least one of: hydrogen sulfide (H2S) and the at least one sulfur containing compound. A reduced metal sulfide (MSx-1) particle reacts with sulfur in a sulfur stream and can generate the metal sulfide (MSx) particle and hydrogen (H2).

First claim

We claim:

1. A method, comprising:
providing a gaseous alkane input stream to a first reactor;
providing a metal sulfide (MS x ) particle to the first reactor,
whereupon the metal sulfide (MS x ) particle reacts with an alkane in the gaseous alkane input stream to generate an alkene, a reduced metal sulfide (MS x-1 ) particle, and at least one of: hydrogen sulfide (H 2 S) and a sulfur containing compound;

collecting a product stream from the first reactor including the alkene, hydrogen sulfide (H 2 S) and the sulfur containing compound;
providing the reduced metal sulfide (MS x-1 ) particle to a second reactor;
providing a sulfur stream to the second reactor,
whereupon the reduced metal sulfide (MS x-1 ) particle reacts with sulfur in the sulfur stream to generate the metal sulfide (MS x ) particle and hydrogen (H 2 ); and

collecting a second reactor output stream including hydrogen (H 2 ).

2. The method according to claim 1 , wherein the alkane in the gaseous alkane input stream includes at least one C 2 -C 6 alkane; and
wherein the sulfur containing compound is one or more of: S 2 , CS, and CS 2 .

3. The method according to claim 1 , further comprising:
monitoring alkane content in the product stream; and
if the alkane content differs from a predetermined target, adjusting a flow rate of the gaseous alkane input stream.

4. The method according to claim 1 , wherein the sulfur stream includes hydrogen sulfide (H 2 S).

5. The method according to claim 4 , wherein the second reactor output stream further comprises hydrogen sulfide (H 2 S), the method further comprising:
separating the hydrogen sulfide (H 2 S) from the second reactor output stream; and
recycling the separated hydrogen sulfide (H 2 S) to the second reactor.

6. The method according to claim 1 , wherein the sulfur stream includes at least one allotrope of sulfur (S).

7. The method according to claim 1 , further comprising separating the hydrogen sulfide (H 2 S) from the product stream; and
recycling the separated hydrogen sulfide (H 2 S) to the second reactor.

8. The method according to claim 1 , further comprising:
maintaining a temperature of the first reactor to be between 200° C. and 1200° C.;
maintaining a pressure of the first reactor to be between 1 atm and 30 atm;
maintaining a temperature of the second reactor to be between 200° C. and 1000° C.; and
maintaining a pressure of the second reactor to be between 1 atm and 30 atm.

9. The method according to claim 1 , wherein the sulfur stream further includes an inert carrier gas.

10. The method according to claim 1 , wherein a metal (M) in the metal sulfide (MS x ) particle includes iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), tungsten (W), lanthanum (La), cerium (Ce), titanium (Ti), zinc (Zn), cadmium (Cd), ruthenium (Ru), rhodium (Rh) or lead (Pb).

11. The method according to claim 1 , wherein the metal sulfide (MS x ) particle includes a promotor, dopant, or support.

12. The method according to claim 11 , wherein the promotor, dopant, or support is MoS 2 , Ce 2 S 3 , MgS, Na 2 S, K 2 O, MgO, SiO 2 , Al 2 O 3 , or MgAl 2 O 4 .

13. The method according to claim 1 , wherein the metal sulfide (MS x ) particle has a size of 100 μm to 2 mm; and
wherein the metal sulfide (MS x ) particle has density of 1.5 g/cm 3 to 6 g/cm 3 .

14. The method according to claim 1 , wherein the metal sulfide (MS x ) particle includes a mesoporous support selected from: Santa Barbara Amorphous-15 silica (SBA-15), Santa Barbara Amorphous-16 silica (SBA-16), Mesoporous Al 2 O 3 , and Mesoporous CeO 2 .

15. A method, comprising:
providing a gaseous alkane input stream to a reactor, the reactor including a metal sulfide (MS x ) particle,
whereupon the metal sulfide (MS x ) particle reacts with an alkane in the gaseous alkane input stream to generate an alkene, a reduced metal sulfide (MS x-1 ) particle, and at least one of: hydrogen sulfide (H 2 S) and at least one sulfur containing compound, the at least one sulfur containing compound being selected from: S 2 , CS, and CS 2 ;

collecting a product stream from the reactor including the alkene and at least one of hydrogen sulfide (H 2 S) and the at least one sulfur containing compound;
after collecting the product stream, providing an inert gas stream to the reactor;
after providing the inert gas stream to the reactor, providing a sulfur stream to the reactor,
whereupon the reduced metal sulfide (MS x-1 ) particle reacts with sulfur in the sulfur stream to generate the metal sulfide (MS x ) particle and hydrogen (H 2 ); and

collecting a reactor output stream including hydrogen (H 2 ).

16. The method according to claim 15 , further comprising:
after collecting the reactor output stream, providing the inert gas stream to the reactor,
wherein the alkane in the gaseous alkane input stream includes at least one C 2 -C 6 alkane; and
wherein the sulfur stream includes hydrogen sulfide (H 2 S).

17. The method according to claim 15 , wherein the sulfur stream includes at least one allotrope of sulfur (S); and
wherein the reactor output stream includes hydrogen sulfide (H 2 S), the method further comprising:
separating the hydrogen sulfide (H 2 S) from the reactor output stream; and
recycling the separated hydrogen sulfide (H 2 S) to the reactor.

18. The method according to claim 15 , further comprising:
while providing the gaseous alkane input stream:
maintaining a temperature of the reactor to be between 200° C. and 1200° C.;
maintaining a pressure of the reactor to be between 1 atm and 30 atm;

while providing the sulfur stream:
maintaining a temperature of the reactor to be between 200° C. and 1000° C.; and
maintaining a pressure of the reactor to be between 1 atm and 30 atm.

19. The method according to claim 15 ,
wherein a metal (M) in the metal sulfide (MS x ) particle includes iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), tungsten (W), lanthanum (La), cerium (Ce), titanium (Ti), zinc (Zn), cadmium (Cd), ruthenium (Ru), rhodium (Rh), or lead (Pb); and
wherein the metal sulfide (MS x ) particle includes a promotor, dopant, or support selected from MoS 2 , Ce 2 S 3 , MgS, Na 2 S, K 2 O, MgO, SiO 2 , Al 2 O 3 , or MgAl 2 O 4 .

20. The method according to claim 15 , wherein the metal sulfide (MS x ) particle has a size of 100 μm to 2 mm;
wherein the metal sulfide (MS x ) particle has density of 1.5 g/cm 3 to 6 g/cm 3 ; and

wherein the metal sulfide (MS x ) particle includes a mesoporous support selected from: Santa Barbara Amorphous-15 silica (SBA-15), Santa Barbara Amorphous-16 silica (SBA-16), Mesoporous Al 2 O 3 , and Mesoporous CeO 2 .

Assignees

• Ohio State Innovation Foundation

Inventors

• Fan Liang-Shih
• Baser Deven
• Nadgouda Sourabh
• Joshi Anuj
• Mohapatra Pinak

Classifications

• C07C2527/043

  with iron group metals or platinum group metals · CPC title

• C07C2527/04

  Sulfides · CPC title

• C07C5/48

  with oxygen as an acceptor · CPC title

• C07C5/46 Primary

  with sulfur or a sulfur-containing compound as an acceptor · CPC title

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title