Systems and methods for converting carbonaceous fuels

Patent metadata

Field	Value
Publication number	US-9616403-B2
Application number	US-201414774730-A
Country	US
Kind code	B2
Filing date	Mar 14, 2014
Priority date	Mar 14, 2013
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

A system for converting carbonaceous fuels is provided. The system includes a gaseous fuel conversion reactor, a solid fuel conversion reactor, and a fuel pretreatment fluidized bed reactor disposed between the gaseous fuel conversion reactor and the solid fuel conversion reactor. The fuel pretreatment fluidized bed reactor devolatilizes a solid fuel using heat to produce an off-gas and a devolatilized solid fuel. The gaseous fuel conversion reactor converts the off-gas from the fuel pretreatment fluidized bed reactor to a product gas stream comprising carbon dioxide and water. The solid fuel conversion reactor receives a mixture of oxygen carrier solids and devolatilized solid fuel from the pretreatment reactor discharge and reduces the devolatilized solid fuel with the oxygen carrier solids to convert the devolatilized solid fuel to an intermediate gas.

First claim

The invention claimed is:

1. A system for converting carbonaceous fuels comprising a gaseous fuel conversion reactor, a solid fuel conversion reactor, and a fuel pretreatment fluidized bed reactor disposed between the gaseous fuel conversion reactor and the solid fuel conversion reactor;
the gaseous fuel conversion reactor comprising:
a gaseous fuel reactor oxygen carrier solid inlet,
a gaseous fuel reactor off-gas inlet configured to receive off-gas from the fuel pretreatment fluidized bed reactor, and
a gaseous fuel reactor oxygen carrier solid outlet,
wherein the gaseous fuel conversion reactor is configured to convert the off-gas and oxygen carrier solids to a product gas stream comprising carbon dioxide and water, thereby reducing at least a portion of the oxygen carrier solids to reduced oxygen carrier solids;

the fuel pretreatment fluidized bed reactor comprising:
a pretreatment reactor solid fuel inlet disposed in a fuel introduction section of the fuel pretreatment reactor,
a pretreatment reactor oxygen carrier inlet configured to receive a mixture of oxygen carrier solids and reduced oxygen carrier solids from the gaseous fuel reactor oxygen carrier solid outlet,
a pretreatment reactor intermediate gas inlet configured to receive intermediate gas from the solid fuel conversion reactor, the intermediate gas being used for fluidization, and
a pretreatment reactor discharge in communication with the gaseous fuel conversion reactor off-gas inlet,
wherein the fuel pretreatment fluidized bed reactor is configured to volatilize solid fuel using heat from the mixture of oxygen carrier solids and reduced oxygen carrier solids to produce a devolatilized solid fuel and off-gas, and subsequently discharge the off-gas, the devolatilized solid fuel, and the mixture of oxygen carrier solids and reduced oxygen carrier solids via the pretreatment reactor discharge;

the solid fuel conversion reactor comprising:
a solid fuel conversion reactor inlet configured to receive the mixture of oxygen carrier solids and reduced oxygen carrier solids and devolatilized solid fuel from the pretreatment reactor discharge and
a solid fuel conversion reactor intermediate gas outlet in communication with the pretreatment reactor intermediate gas inlet, and
a solid fuel conversion reactor oxygen carrier solid outlet,
wherein the solid fuel conversion reactor is configured to react the devolatilized solid fuel with the mixture of oxygen carrier solids and reduced oxygen carrier solids to produce the intermediate gas comprising carbon dioxide and water, thereby further reducing oxygen carrier solids to reduced oxygen carrier solids.

2. The system of claim 1 , further comprising an oxidation reactor configured to react the reduced oxygen carrier solids from the solid fuel conversion reactor oxygen carrier solid outlet with an oxidation gas stream to convert the reduced oxygen carrier solid back to the oxygen carrier solid, the oxidation reactor comprising
a reduced oxygen carrier solid inlet configured to receive the reduced oxygen carrier solid, and
an oxidation reactor discharge configured to discharge the oxygen carrier solid and an oxygen depleted oxidation gas stream.

3. The system of claim 1 , further comprising a pretreatment gas-solids separation unit in communication with the pretreatment reactor discharge and configured to separate the off-gas from the devolatilized solid fuel and the oxygen carrier solid exiting the fuel pretreatment fluidized bed reactor.

4. The system of claim 1 , wherein the gaseous fuel conversion reactor is divided into two or more staged reactors in series.

5. The system of claim 1 , wherein the solid fuel conversion reactor is divided into two or more staged reactors in series.

6. The system of claim 1 , wherein the gas velocity of the off-gas through the gaseous fuel conversion reactor is less than the minimum fluidization velocity of the oxygen carrier solid.

7. The system of claim 1 , further comprising a conversion enhancement gas inlet configured to introduce a conversion enhancement gas into the solid fuel conversion reactor to enhance conversion of the devolatilized solid fuel.

8. The system of claim 7 , wherein the conversion enhancement gas is the product gas stream from the gaseous fuel conversion reactor.

9. The system of claim 7 , wherein the gas velocity of the conversion enhancement gas through the solid fuel conversion reactor is less than the minimum fluidization velocity of the oxygen carrier solid.

10. The system of claim 2 , further comprising an oxidizer gas-solids separation unit in communication with the oxidation reactor discharge and configured to separate the oxygen depleted oxidation gas stream from the oxygen carrier solid exiting the oxidation reactor.

11. The system of claim 2 , further comprising a non-mechanical seal separating the solid fuel conversion reactor and the oxidation reactor, the non-mechanical seal configured to prevent gases generated in the solid fuel conversion reactor and the oxidation gas stream in the oxidation reactor from transferring between the solid fuel conversion reactor and the oxidation reactor while allowing the reduced oxygen carrier solid to pass through.

12. The system of claim 10 , further comprising a non-mechanical seal separating the gaseous fuel conversion reactor and oxidizer gas-solids separation unit, the non-mechanical seal configured to prevent the product gas stream of the gaseous fuel conversion reactor and the oxygen depleted oxidation gas stream in the oxidizer gas-solids separation unit from transferring between the gaseous fuel conversion reactor and the oxidizer gas-solids separation unit or oxygen carrier solid storage vessel while allowing the oxygen carrier solid to pass through.

13. The system of claim 1 , wherein the fuel pretreatment reactor further comprises a substantially cone shaped bottom in communication with a gas-solids jet configured to provide a uniform distribution of the intermediate gas and the oxygen carrier solid into the fuel pretreatment fluidized bed reactor;
wherein the gas-solids jet comprises the pretreatment reactor intermediate gas inlet and the pretreatment reactor oxygen carrier inlet.

14. The system of claim 1 , wherein the fuel pretreatment reactor further comprises a supply chamber and a mixing chamber with a crossflow slit disposed between the supply chamber and the mixing chamber configured to allow passage of the oxygen carrier solid through the crossflow slit;
wherein an aeration inlet provides an aeration gas from the bottom or from the side of the supply chamber to propel the oxygen carrier solid through the crossflow slit into the mixing chamber.

15. The system of claim 1 , wherein the fuel pretreatment reactor further comprises a gas introduction zone and a solids mixing zone separated by a meshed gas distributor configured to distribute the intermediate gas uniformly across the fuel pretreatment fluidized bed reactor.

16. The system of claim 15 , further comprising an ash separator disposed between the solid fuel conversion intermediate gas outlet and the pretreatment reactor intermediate gas inlet and is configured to separate ash and/or unconverted carbon from the intermediate gas before the intermediate gas is provided to the fuel pretreatment fluidized bed reactor.

17. A system for converting carbonaceous fuels comprising a gaseous fuel conversion reactor, a solid fuel conversion reactor, a fuel pretreatment fluidized bed reactor disposed between the gaseous fuel conversion reactor and the solid fuel conversion reactor, an oxidat

Assignees

• Ohio State Innovation Foundation

Inventors

• Fan Liang-Shih
• Wang Dawei

Classifications

• B01J8/1836

  Heating and cooling the reactor (B01J8/42 takes precedence) · CPC title

• B01J8/087

  Heating or cooling the reactor · CPC title

• B01J2208/00893

  Feeding means for the reactants · CPC title

• B01J8/005

  Separating solid material from the gas/liquid stream (separation processes per se B01D) · CPC title

• B01J8/003

  in a downward flow · CPC title