Method for manufacturing photocatalytic filter having porous nanofiber heterostructure

Patent metadata

Field	Value
Publication number	US-11446647-B2
Application number	US-201816771298-A
Country	US
Kind code	B2
Filing date	May 28, 2018
Priority date	Dec 12, 2017
Publication date	Sep 20, 2022
Grant date	Sep 20, 2022

Abstract

A method for preparing a porous nano-fiber heterostructure photocatalytic filter screen includes: preparing a noble metal nanostructure with tunable spectra and a heterostructure composite photocatalyst of a photocatalytic material; and preparing a large area and multilayer porous nano-fiber filter screen structure, while utilizing a scattering enhancement effect of metal nanoparticles in an porous optical fiber to realize repeated conduction of sunlight in the optical fiber and finally interact with the composite photocatalyst on a surface to improve photocatalytic efficiency. Preparation of the heterostructure composite photocatalyst with a wide spectral response of and tunable visible to infrared band spectra is realized, at the same time, with reference to high adsorbability, high light transmission of nanometer fiber and unique optical characteristics of metal nanoparticles, an air purification filter screen with a high sunlight utilization rate and a high catalytic degradation capability is creatively provided.

First claim

What is claimed is:

1. A method for preparing a porous nano-fiber heterostructure photocatalytic filter screen, wherein the method comprises the following steps:
step I: preparing a photocatalytic heterostructure consisting of a plasmonic metal nanostructure with tunable visible to infrared band spectra and a semiconductor nanostructure,
1-1) centrifuging a solution containing the plasmonic metal nanostructure with the tunable visible to infrared band spectra, removing a capping agent on a surface of the solution, and preparing an initial solution a with a concentration of 0.1-20 mol/L of the plasmonic metal nanostructure;
1-2) centrifuging a semiconductor nanostructure solution, removing a capping agent on a surface of the solution to redisperse in deionized water, and preparing an initial solution b with a concentration of 0.1-10 mol/L of the semiconductor nanostructure;
1-3) dissolving surface ligand molecules in deionized water to prepare an initial solution c with a concentration of 0.2-20 mol/L of the surface ligand molecules;
1-4) mixing the initial solution b and the initial solution c and fully stirring them, wherein the surface ligand molecules are absorbed on a surface of a photocatalytic material, centrifuging, removing excessive surface ligand molecules, and redispersing in the deionized water to obtain a mixed solution d;
1-5) mixing the initial solution a and the mixed solution d and fully stirring them, ensuring that plasmonic metal nanostructures with tunable spectra in the mixed solution d and the initial solution a are fully absorbed, and finally forming a heterostructure solution e consisting of the plasmonic metal nanostructures with tunable spectra and semiconductor nanostructures that are randomly combined;
step II: preparing an electrospinning solution
dissolving the heterostructure solution e, a high molecular organic polymer, and an amphiphilic polymer organic polymer in a mono-component or multicomponent organic solvent, stirring at a room temperature to obtain a colorless transparent solution f with 6%-20% the high molecular organic polymer by mass, adding a large-size metal nanoparticle solution with a molar concentration of 0.0001-1 mol/L, and continuously stirring to obtain the electrospinning solution g that is colorless transparent;
step III: preparing a porous, large-area filter screen
taking the electrospinning solution g into a glass syringe, removing bubbles therein, loading the electrospinning solution g on an injection card slot of an electrospinning device, and cutting an aluminum foil to cover a receiving roller; turning on a power supply of the electrospinning device and set basic parameters, wherein a rotating speed of the receiving roller is 10-1000 rpm/min, a syringe needle is 5-20 cm away from the roller, a positive high voltage is set to 5-30 kv, a negative high voltage is set to 1-3 kv, an injection speed is set to 0.1-3 ml/h, and a spinning time is 0.01-24 hours, turning off the power supply after spinning is finished, taking off the aluminum foil and drying in a vacuum drying oven to obtain a composite polymer fiber structure;
soaking the aluminum foil loaded with fiber in the deionized water for 0.1-48 hours, dissolving the amphiphilic polymer organic polymer in the deionized water, taking out the aluminum foil, heating and air-drying to obtain an air purification filter screen structure with a diameter of 10-100 μm, a length of 10-10000 μm and a porosity of 1-99%.

2. The method for preparing the porous nano-fiber heterostructure photocatalytic filter screen according to claim 1 , wherein the plasmonic metal nanostructure is made from gold, silver, platinum, or a multicomponent alloy material consisting of gold, silver and platinum; wherein the plasmonic metal nanostructure has a triangular plate, cube or rod shape, and the plasmonic metal nanostructure is a nanostructure with tunable visible to infrared band spectra having a size of 10 nanometers to 2000 nanometers.

3. The method for preparing the porous nano-fiber heterostructure photocatalytic filter screen according to claim 1 , wherein the surface ligand molecules have high surface affinity with the plasmonic metal nanostructure, and are selected from the group consisting of dimercapto-polyethylene glycols, polyethylene glycols and 3-aminopropyltriethoxysilanes.

4. The method for preparing the porous nano-fiber heterostructure photocatalytic filter screen according to claim 1 , wherein the semiconductor nanostructure is made from a nano-size oxide or sulfide semiconductor nano-structure selected from the group consisting of titanium dioxide TiO 2 , zinc oxide ZnO, cadmium sulfide CdS, and ferric oxide Fe 2 O 3 ; or the semiconductor nanostructure is made from a heterostructure, wherein the heterostructure consisting of gold, silver and palladium.

5. The method for preparing the porous nano-fiber heterostructure photocatalytic filter screen according to claim 4 , wherein the nano-size oxide or the sulfide semiconductor nano-structure has a spherical, rod-shaped, triangular or cubic shape with a size of 10 nanometers to 100 nanometers, and the heterostructure has a spherical, rod-shaped, triangular or cubic shape with a size of 5 nanometers to 1000 nanometers.

6. The method for preparing the porous nano-fiber heterostructure photocatalytic filter screen according to claim 1 , wherein the high molecular organic polymer is made from polystyrene PS, polyimide PI or polyacrylonitrile PAN.

7. The method for preparing the porous nano-fiber heterostructure photocatalytic filter screen according to claim 1 , wherein the high molecular organic polymer is made from a two-phase polymer material that dissolves in both a water phase and an oil phase; and the high molecular organic polymer is selected from the group consisting of polyvinyl pyrrolidone PVP, cetyltrimethylammonium bromide CTAB and sodium dodecyl sulfate SDS.

8. The method for preparing the porous nano-fiber heterostructure photocatalytic filter screen according to claim 1 , wherein the multicomponent solvent comprising a mono-component solvent selected from the group consisting of cyclopentanone, dimethylformamide, ethanol, ethylene glycol and toluene; or a mixture thereof.

9. The method for preparing the porous nano-fiber heterostructure photocatalytic filter screen according to claim 1 , wherein the plasmonic metal nanostructure in the large-size metal nanoparticle solution is made from gold, silver or platinum; the plasmonic metal nanostructure has light scattering enhancement characteristics and forms shape of spherical, rod, triangular, or cubic, or a mixture of shapes with a size of 50 nanometers to 10000 nanometers.

Assignees

• Univ Southeast

Inventors

• Zhang Xiaoyang
• Zhang Tong
• Wang Shanjiang
• Ji Yu
• Zhao Minghu
• Zhao Linfeng

Classifications

• B01J35/55

  Cylinders or rings · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J35/50

  characterised by their shape or configuration · CPC title

• B01J31/1683 Primary

  the linkage being to a soluble polymer, e.g. PEG or dendrimer, i.e. molecular weight enlarged complexes · CPC title

• B01J2531/17

  Silver · CPC title