Lithium air battery and method of preparing the same

Patent metadata

Field	Value
Publication number	US-11444348-B2
Application number	US-202016827747-A
Country	US
Kind code	B2
Filing date	Mar 24, 2020
Priority date	Aug 27, 2014
Publication date	Sep 13, 2022
Grant date	Sep 13, 2022

Abstract

A lithium air battery including a composite cathode including a porous material and a first solid electrolyte; a lithium metal anode; an oxygen blocking layer adjacent to the anode; and a cathode interlayer disposed between the cathode and the oxygen blocking layer, wherein the cathode interlayer includes a lithium ion conducting second solid electrolyte.

First claim

What is claimed is:

1. A lithium air battery comprising:
a composite cathode comprising a porous material and a first solid electrolyte;
a lithium metal anode;
an oxygen blocking layer adjacent to the anode; and
a cathode interlayer disposed between the cathode and the oxygen blocking layer,
wherein the cathode interlayer comprises a lithium ion conductive second solid electrolyte and wherein a thickness of the cathode interlayer is less than a thickness of each of the composite cathode and the oxygen blocking layer, and
wherein the first solid electrolyte comprises an inorganic electrolyte, an organic-inorganic composite electrolyte, or a combination thereof.

2. The lithium air battery of claim 1 , wherein the cathode interlayer does not comprise a gel.

3. The lithium air battery of claim 1 , wherein the cathode interlayer is non-porous.

4. The lithium air battery of claim 1 , wherein a thickness of the cathode interlayer is about 200 nm to about 5 μm.

5. The lithium air battery of claim 1 , wherein a thickness of the cathode interlayer is 50 μm or less.

6. The lithium air battery of claim 1 , wherein the second solid electrolyte comprises an inorganic electrolyte, an organic-inorganic composite electrolyte, or a combination thereof.

7. The lithium air battery of claim 1 , wherein the second solid electrolyte and the first solid electrolyte comprise a same solid electrolyte.

8. The lithium air battery of claim 1 , wherein the inorganic electrolyte comprises a glassy electrolyte, an amorphous electrolyte, a ceramic electrolyte, a glass-ceramic electrolyte, or a combination thereof.

9. The lithium air battery of claim 1 , wherein the inorganic electrolyte comprises Cu 3 N, LiN, LiPON (Lithium phosphorous oxynitride), Li 3 PO 4 .Li 2 S.SiS 2 , Li 2 S.GeS 2 .Ga 2 S 3 , Li 2 O.11Al 2 O 3 , Na 2 O.11Al 2 O 3 , (Na z Li 1−z ) 1+x Ti 2−x Al x (PO 4 ) 3 wherein 0.1≤x≤0.9 and 0≤z≤1, Li 1+x′ ,Hf 2−x′ Al x′ (PO 4 ) 3 wherein 0.1≤x′≤0.9, Na 3 Zr 2 Si 2 PO 12 , Li 3 Zr 2 Si 2 PO 12 , Na 5 ZrP 3 O 12 , Na 5 TiP 3 O 12 , Na 3 Fe 2 P 3 O 12 , Na 4 NbP 3 O 12 , a sodium silicate, Li 0.3 La 0.5 TiO 3 , Na 5 MSi 4 O 12 wherein M is a rare earth element, Li 5 ZrP 3 O 12 , Li 5 TiP 3 O 12 , Li 3 Fe 2 P 3 O 12 , Li 4 NbP 3 O 12 , Li 1+x″ (M′Al z′ Ga 1−z′ ) x″ (Ge 1−y Ti y ) 2−X″ (PO 4 ) 3 wherein 0≤x″≤0.8, 0≤y≤1.0, 0≤z′≤1, and M′ is Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or a combination thereof, Li 1+q+y′ Q q Ti 2−q Si y′ P 3−y′ O 12 wherein 0<q≤0.4, 0<y′≤0.6, and Q is Al or Ga, Li 6 BaLa 2 Ta 2 O 12 , Li 7 La 3 Zr 2 O 12 , Li 5 La 3 Nb 2 O 12 , Li 5 La 3 M 2 O 12 wherein M is Nb or Ta, Li 7+r A r La 3−r Zr 2 O 12 wherein 0<r<3, and A is Zn, or a combination thereof.

10. The lithium air battery of claim 1 , wherein the organic-inorganic electrolyte comprises an ion conducting polymer, a polymeric ionic liquid, inorganic electrolyte, or a combination thereof.

11. The lithium air battery of claim 1 , wherein a weight ratio of the porous material to the first solid electrolyte is in a range of about 1:2 to about 1:5.

12. The lithium air battery of claim 1 , wherein the oxygen blocking layer is impervious to oxygen.

13. The lithium air battery of claim 12 , wherein the oxygen blocking layer is a solid electrolyte layer comprising a crystalline lithium ion conducting compound.

14. The lithium air battery of claim 13 , wherein an amount of the crystalline lithium ion conducting compound is about 50 wt % or more, based on the total weight of the solid electrolyte layer.

15. The lithium air battery of claim 13 , wherein the crystalline lithium ion conducting compound comprises Li 3 N, Li 2+2n Zn 1−n GeO 4 wherein 0≤n≤1, La 0.55 Li 0.35 TiO 3 , LiTi 2 P 3 O 12 , Li 1+x+y (Al z Ga 1−z ) x″ (Ti y Ge 1−y ) 2−x″ Si y′ P 3−y′ O 12 wherein 0≤z≤1, 0≤y≤1, 0≤x″≤1′, 0≤y′≤1, 0≤x≤0.4 and 0<y≤0.6, a lithium-aluminum-germanium-phosphate, a lithium-aluminum-titanium-phosphate, a lithium-aluminum-titanium-silicon-phosphate, Li 1+x+y Al x Ti 2−x Si y P 3−y O 12 wherein 0≤x≤1 and 0≤y≤1, Li 1+x+y Al x Ti 2−x Si y P 3−y O 12 wherein 0≤x≤1 and 0≤y≤1, Li 1+x+y Al x (Ti p Ge 1−p ) 2−x Si y P 3−y O 1 wherein 0≤p≤1, 0≤x≤2, and 0≤y≤3, or a combination thereof.

16. The lithium air battery of claim 1 , further comprising an anode interlayer between the anode and the oxygen blocking layer, wherein the anode interlayer comprises a third solid electrolyte.

17. The lithium air battery of claim 1 , wherein the cathode interlayer consists of the lithium ion conductive second solid electrolyte and is in the form of a layer between the cathode and the oxygen blocking layer.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Kim Taeyoung
• Lee Dongjoon
• Lee Heungchan
• Im Dongmin
• Choi Wonsung

Classifications

• H01M50/431

  Inorganic material · CPC title

• H01M50/454

  comprising a non-fibrous layer and a fibrous layer superimposed on one another · CPC title

• H01M12/08 Primary

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• H01M2300/0065

  Solid electrolytes · CPC title

• H01M4/382

  Lithium (H01M4/405 takes precedence) · CPC title