Guayule latex extrusion

Patent metadata

Field	Value
Publication number	US-11440977-B2
Application number	US-201815895601-A
Country	US
Kind code	B2
Filing date	Feb 13, 2018
Priority date	Feb 13, 2017
Publication date	Sep 13, 2022
Grant date	Sep 13, 2022

Abstract

A latex processing system and method involves mixing a latex and at least one solvent blend in an extruder, in order to remove resin found in the latex and to coagulate the latex to form a coagulum. The at least one solvent blend has a first solvent configured to coagulate the latex, and a second solvent configured to swell the resulting coagulum. In particular, a series of the solvent blends may be used at different locations along a length of the extruder, and may further include distinct blends of the first solvent and the second solvent, introduced at the different locations, and having different ratios of the first solvent and the second solvent.

First claim

What is claimed is:

1. A latex processing method, comprising a step of
mixing a latex containing a natural rubber and at least one solvent blend in an extruder having a plurality of zones to remove resin found in the latex and to coagulate the latex to form a coagulum, wherein the at least one solvent blend includes a first solvent configured to coagulate the latex and a second solvent configured to swell the resulting coagulum,
wherein the at least one solvent blend does not dissolve the natural rubber but swells the natural rubber,
wherein the at least one solvent blend includes a series of solvent blends, the series of solvent blends including distinct blends of the first solvent and the second solvent, each of the distinct blends introduced at one of the plurality of zones in the extruder and having different ratios of the first solvent and the second solvent, a ratio of the first solvent to the second solvent increases through the series of solvent blends, the series of solvent blends including a first solvent blend of acetone and hexane with a hexane weight fraction in the acetone from greater than 0% to 53% and a second solvent blend of acetone and hexane with a hexane weight fraction in the acetone from 5% to 25%.

2. The latex processing method of claim 1 , wherein the latex is a guayule latex.

3. The latex processing method of claim 1 , wherein the series of solvent blends includes a third solvent blend having acetone and hexane with a hexane weight fraction in the acetone from 10% to 20%.

4. The latex processing method of claim 1 , wherein the plurality of zones includes a coagulation zone and a first wash zone and each of the distinct solvent blends is configured to swell the coagulum to a mass swell ratio between 1.5 and 1.6 at the coagulation zone and the first wash zone.

5. The latex processing method of claim 1 , wherein the extruder includes a filter, each of the first solvent blend and the second solvent blend is configured to swell the coagulum to a mass swell ratio between 1.5 and 1.6, and the filter is configured to retain the coagulum within a barrel of the extruder.

6. The latex processing method of claim 1 , wherein the first solvent blend includes a hexane weight fraction in acetone from 0% to 40% and the second solvent blend includes a hexane weight fraction in acetone from 5% to 25%.

7. The latex processing method of claim 6 , wherein the series of solvent blends includes a third solvent blend having acetone and hexane with a hexane weight fraction in the acetone from 10% to 20%.

8. The latex processing method of claim 1 , wherein the extruder is operated at an rpm value configured to provide a Mooney viscosity of 98.

9. The latex processing method of claim 1 , wherein the latex containing the natural rubber includes 45% moisture.

10. The latex processing method of claim 1 , further comprising apply a vacuum to the extruder to extract remaining solvent from the coagulum.

11. The latex processing method of claim 1 , further comprising extruding the coagulum through a die face cutter.

12. A latex processing method, comprising:
providing an extruder including a first end and a second end, and at least one screw, the extruder comprising a plurality of process zones positioned between the first end and second end, the plurality of process zones including a coagulation zone, a first wash zone, and a second wash zone, the coagulation zone configured to receive a latex and a first solvent blend and to coagulate the latex into a coagulum, the first wash zone in communication with the coagulation zone and configured to receive the coagulum and a second solvent blend, and the second wash zone in communication with the first wash zone and configured to receive the coagulum and a third solvent blend, a first mechanical filter in communication with the coagulation zone, each of the first solvent blend, the second solvent blend, and the third solvent blend includes a first solvent configured to coagulate the latex and a second solvent configured to swell the resulting coagulum, the first solvent blend, the second solvent blend, and the third solvent blend form a series of solvent blends and a ratio of the first solvent to the second solvent increases through the series of solvent blends, wherein the first solvent blend is acetone and hexane with a hexane weight fraction in the acetone from greater than 0% to 40%, the second solvent blend is acetone and hexane with a hexane weight fraction in the acetone from 5% to 25%, and the third solvent blend is acetone and hexane with a hexane weight fraction in the acetone from 10% to 20%;
mixing the latex and the first solvent blend in the coagulation zone of the extruder to form the coagulum;
removing a portion of the first solvent blend in the coagulation zone using the first mechanical filter;
washing the coagulum with the second solvent blend at the first wash zone;
removing a portion of the second solvent blend at the first wash zone using the second mechanical filter;
washing the coagulum with the third solvent blend at the second wash zone;
removing a portion of the third solvent blend as the second wash zone using the third mechanical filter;
applying a vacuum to the extruder at a location upstream from the third mechanical filter to extract extra residual amounts of the first solvent blend, the second solvent blend, and the third solvent blend; and
extruding the coagulum through the second end of the extruder to provide a natural rubber.

13. The latex processing method of claim 12 , wherein the latex is a guayule latex.

14. The latex processing method of claim 12 , wherein each of the first solvent blend and the second solvent blend is configured to swell the coagulum to a mass swell ratio between 1.5 and 1.6.

Assignees

• Cooper Tire & Rubber Co

Inventors

• Sauty Nicolas
• Sunday Brittney
• Colvin Howard

Classifications

• B29B7/94

  Liquid charges · CPC title

• B29B7/7495

  for mixing rubber · CPC title

• B29B7/805

  Cleaning of the mixing conduit, module or chamber part · CPC title

• B29B7/842

  Removing liquids in liquid form · CPC title

• B29C48/03

  characterised by the shape of the extruded material at extrusion · CPC title