Method and apparatus for separating air by cryogenic distillation

Patent metadata

Field	Value
Publication number	US-11435139-B2
Application number	US-201816768067-A
Country	US
Kind code	B2
Filing date	Nov 8, 2018
Priority date	Nov 29, 2017
Publication date	Sep 6, 2022
Grant date	Sep 6, 2022

Abstract

The invention relates to a method for separating air by cryogenic distillation in a column system, comprising a first column operating at a first pressure and a second column operating at a second pressure, in which an argon-enriched flow is sent from an intermediate point of the first column to the tank of the second column and an argon-rich flow is drawn off at the top of the second column, wherein a nitrogen-enriched flow of the first column is compressed in a compressor, the compressed flow is sent to a head condenser of the second column after an expansion step and the vaporized flow is expanded in the condenser in a turbine where it at least partially liquefies.

First claim

The invention claimed is:

1. A method for separating air by cryogenic distillation in a column system comprising a first column operating at a first pressure and a second column operating at a second pressure, the first pressure being substantially equal to the second pressure, wherein:
(a) sending compressed, purified and cooled air to an intermediate point of the first column, drawing off a liquid enriched in oxygen from a bottom of the first column and/or drawing off a gas enriched in oxygen from the first column and drawing off a flow enriched in nitrogen from a top of the first column;
(b) sending a flow enriched in argon from an intermediate point of the first column to a bottom of the second column and drawing off a flow rich in argon from a top of the second column;
(c) compressing the flow enriched in nitrogen in a compressor and using the compressed flow to heat a bottom reboiler of the first column, producing an at least partially condensed flow enriched in nitrogen;
(d) dividing the at least partially condensed flow enriched in nitrogen into first and second portions, sending the first portion to the top of the first column after an expansion step and sending the second portion to a top condenser of the second column after an expansion step in which the second portion is at least partially vaporized to form an auxiliary flow; and
(e) expanding the auxiliary flow in a turbine wherein the auxiliary flow is at least partially liquefied and then sent to the top of the first column.

2. The method as claimed in claim 1 , wherein the auxiliary flow is partially liquefied at the outlet of a wheel of the turbine, or even in the wheel of the turbine, for example in order to obtain, at the outlet of the wheel or in same, an expanded auxiliary flow containing between 0.5% and 10% liquid.

3. The method as claimed in claim 1 , wherein the auxiliary flow is directly expanded in the turbine, without prior heating.

4. The method as claimed in claim 1 , wherein the flow enriched in nitrogen is heated in a heat exchanger upstream of the compressor, the compressed flow enriched in nitrogen being cooled in the heat exchanger and subsequently sent at least in part to the bottom reboiler.

5. The method as claimed in claim 4 , wherein a portion of the compressed flow enriched in nitrogen is expanded in a second turbine and returned to the heat exchanger.

6. The method as claimed in claim 1 , wherein the inlet temperature of the turbine and/or of the second turbine and/or of the compressor is a cryogenic temperature.

7. The method as claimed in claim 1 , wherein a liquid flow rich in argon is sent from the top of the second column to the top of the first column.

8. The method as claimed in claim 1 , wherein, in operation, no purge flow is drawn off from the condenser of the second column.

9. The method as claimed in claim 1 , wherein, after the expansion steps, the first and second portions of the at least partially condensed flow enriched in nitrogen are at different pressures and/or temperatures, the second portion preferably being at a higher pressure than the first portion.

10. An apparatus for separating air by cryogenic distillation in a column system, the apparatus comprising:
a first column operating at a first pressure and having a bottom reboiler and a second column operating at a second pressure having a top condenser, the first pressure being substantially equal to the second pressure;
a compressor;
a turbine;
a first pipe configured to send air, which has been compressed, purified and cooled, to an intermediate point of the first column;
a second pipe configured to withdraw a liquid enriched in oxygen from a bottom of the first column and/or a gas enriched in oxygen from the first column;
a third pipe configured to withdraw a flow enriched in nitrogen from a top of the first column and then send said flow enriched in nitrogen to the compressor to form a compressed flow enriched in nitrogen;
a fourth pipe configured to send a flow enriched in argon from an intermediate point of the first column to a bottom of the second column;
a fifth pipe configured to withdraw a flow rich in argon from a top of the second column;
a sixth pipe configured to send the flow enriched in nitrogen and compressed in the compressor to the bottom reboiler of the first column in order to produce an at least partially condensed flow enriched in nitrogen;
a seventh pipe configured to send a first portion of the at least partially condensed flow enriched in nitrogen to the top of the first column after being expanded in an expansion step;
an eighth pipe configured to send a second portion of the at least partially condensed flow enriched in nitrogen to the top condenser of the second column after being expanded in an expansion step in which the second portion is at least partially vaporized to form an auxillary flow;
wherein the turbine is in fluid communication with the top condenser of the second column such that the turbine is configured to receive the auxillary flow from the second column and expand the auxillary flower to form an at least partially liquefied flow; and
a ninth pipe configured to send the at least partially liquefied flow, or stream derived from the at least partially liquefied flow, to the top of the first column.

11. The method as claimed in claim 10 , comprising a heat exchanger upstream of the compressor, wherein the heat exchanger is configured to heat the flow enriched in nitrogen and cool the compressed flow enriched in nitrogen.

12. The method as claimed in claim 10 , comprising a second turbine that is in fluid communication with the heat exchanger such that the second turbine is configured to receive a portion of the compressed flow enriched in nitrogen.

13. The method as claimed in claim 10 wherein the top of the second column is in fluid communication with the top of the first column, such that a liquid flow rich in argon is sent from the top of the second column to the top of the first column.

14. The method as claimed in claim 10 , comprising an absence of an air turbine.

15. The method as claimed in claim 10 , further comprising a phase separator located downstream of the turbine, wherein the phase separator is configured to separate the at least partially liquefied flow into a liquid and a gas that are then sent separately to the first column.

Assignees

• Air Liquide

Inventors

• Davidian Benoit

Classifications

• F25J3/0423

  Subcooling of liquid process streams · CPC title

• F25J3/04969

  Retrofitting or revamping of an existing air fractionation unit · CPC title

• F25J2200/78

  Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column · CPC title

• F25J3/04393

  using multiple or multistage gas work expansion · CPC title

• F25J3/04939

  Vertical, e.g. dividing wall columns (details of dephlegmators F25J5/007) · CPC title