Hydrogen-containing transition metal oxide, method for making the same, and primary battery

Patent metadata

Field	Value
Publication number	US-11434148-B2
Application number	US-201916420144-A
Country	US
Kind code	B2
Filing date	May 22, 2019
Priority date	Nov 23, 2016
Publication date	Sep 6, 2022
Grant date	Sep 6, 2022

Abstract

A hydrogen-containing transition metal oxide is provided. The hydrogen-containing transition metal oxide has a structural formula of ABOxHy, wherein A is one or more of alkaline earth metal elements and rare-earth metal elements, B is one or more of transition metal elements, x is a numeric value in a range of 1 to 3, and y is a numeric value in a range of 0 to 2.5. The present disclosure further provides a primary battery by using the hydrogen-containing transition metal oxide as electrodes and a method for making the hydrogen-containing transition metal oxide.

First claim

What is claimed is:

1. A hydrogen-containing transition metal oxide, having a structural formula of SrCoO x H y , wherein x is a numeric value in a range of 1 to 3, and y is a numeric value larger than 0 and smaller than or equal to 2.5, wherein H in the SrCoO x H y has an oxidation state of +1 and is connected to an oxygen ion in a cobalt-oxygen tetrahedron of the SrCoO x H y to form a OH bond.

2. The hydrogen-containing transition metal oxide of claim 1 , wherein x is 2.5.

3. The hydrogen-containing transition metal oxide of claim 1 , having a structural formula of SrCoO 2.8 H 0.82 , SrCoO 2.5 H, SrCoO 3 H 1.95 , or SrCoO 2.5 H 2.38 .

4. A method for making the hydrogen-containing transition metal oxide of claim 1 , the method comprising:
providing a transition metal oxide having a structural formula of SrCoO z , wherein z is greater than or equal to 2 and smaller than or equal to 3;
soaking the transition metal oxide with an ionic liquid, wherein water in the ionic liquid is capable of being decomposed into hydrogen ions and oxygen ions under an action of an electric field; and
applying an electric field to the transition metal oxide to cause the hydrogen ion in the ionic liquid to insert into the transition metal oxide.

5. The method of claim 4 , wherein the providing the transition metal oxide comprises:
providing a substrate;
depositing a film of the transition metal oxide having the structural formula of SrCoO z onto a surface of the substrate; and
forming a first electrode on a surface of the film of the transition metal oxide.

6. The method of claim 5 , wherein the substrate is one of a ceramic substrate, a silicon substrate, a glass substrate, a metal substrate, or a polymer.

7. The method of claim 5 , wherein the film of the transition metal oxide is obtained via an epitaxial growth on the surface of the substrate by using a pulsed laser deposition method.

8. The method of claim 5 , wherein the first electrode contacts the film of the transition metal oxide to form a bottom electrode.

9. The method of claim 5 , wherein the applying the electric field to the transition metal oxide comprises:
providing a second electrode and a power source;
disposing the second electrode to be spaced from the first electrode and connecting the second electrode and the first electrode electrically and respectively to the power source; and
soaking the second electrode with the ionic liquid and applying an electric field in a direction from the second electrode to the first electrode by the power source.

10. A primary battery, comprising:
a cathode electrode;
an anode electrode spaced from the cathode electrode; and
an electrolyte disposed between the cathode electrode and the anode electrode;
wherein at least one of the cathode electrode and the anode electrode is a hydrogen-containing transition metal oxide having a structural formula of SrCoO x H y , wherein x is a numeric value in a range of 1 to 3, and y is a numeric value larger than 0 and smaller than or equal to 2.5, wherein H in the SrCoO x H y has an oxidation state of +1 and is connected to an oxygen ion in a cobalt-oxygen tetrahedron of the SrCoO x H y to form a OH bond.

11. The primary battery of claim 10 , wherein x is 2.5.

12. The primary battery of claim 10 , the hydrogen-containing transition metal oxide is SrCoO 2.8 H 0.82 , SrCoO 2.5 H, SrCoO 3 H 1.95 , or SrCoO 2.5 H 2.38 .

13. The hydrogen-containing transition metal oxide of claim 1 , having a structural formula of SrCoO 2.5 H.

14. The primary battery of claim 10 , the hydrogen-containing transition metal oxide is SrCoO 2.5 H.

Assignees

• Univ Tsinghua

Inventors

• Yu Pu
• Lu nian-peng
• Wu Jian
• Zhou shu-yun

Classifications

• H01M2004/027

  Negative electrodes · CPC title

• H01M4/48 Primary

  of inorganic oxides or hydroxides · CPC title

• C01G51/04 Primary

  Oxides · CPC title

• C01P2002/34

  perovskite-type (ABO3) · CPC title

• H01M6/04 Primary

  Cells with aqueous electrolyte · CPC title