Activation of low metal content catalyst

Patent metadata

Field	Value
Publication number	US-11433386-B2
Application number	US-202016742566-A
Country	US
Kind code	B2
Filing date	Jan 14, 2020
Priority date	Jan 25, 2019
Publication date	Sep 6, 2022
Grant date	Sep 6, 2022

Abstract

Methods are provided for activation of catalysts comprising low amounts of a hydrogenation metal, such as low amounts of a Group 8-10 noble metal. The amount of hydrogenation metal on the catalyst can correspond to 0.5 wt % or less (with respect to the weight of the catalyst), or 0.1 wt % or less, or 0.05 wt % or less. Prior to loading a catalyst into a reactor, the corresponding catalyst precursor can be first activated in a hydrogen-containing atmosphere containing 1.0 vppm of CO or less. The thus first-activated catalyst can be transferred to a reactor with optional exposure to oxygen during the transfer, where it can be further activated using a hydrogen-containing atmosphere containing 3.0 vppm of CO or higher, to yield a twice-activated catalyst with high performance. The catalyst can be advantageously a transalkylation catalyst or an isomerization catalyst useful for converting aromatic hydrocarbons.

First claim

What is claimed is:

1. A method for activating a catalyst, comprising:
(I) providing a catalyst precursor comprising a hydrogenation metal and a molecular sieve, wherein the catalyst precursor comprises 0.5 wt % or less of the hydrogenation metal, based on the total weight of the catalyst precursor;
(II) reducing the catalyst precursor in a first vessel in the presence of a first atmosphere comprising H 2 and 1.0 vppm or less of CO, based on the total volume of the first atmosphere, to form an activated catalyst;
(III) transferring the activated catalyst to a second vessel; and
(IV) treating the activated catalyst in the second vessel in the presence of a second atmosphere comprising H 2 and 3.0 vppm or more of CO, based on the total volume of the second atmosphere, to form a twice-activated catalyst.

2. The method of claim 1 , wherein the method further comprises:
(IIa) exposing at least a portion of the activated catalyst to a third atmosphere comprising 1.0 vol % or more O 2 , based on the total volume of the third atmosphere, for an exposure time of 0.1 hours or more, to form an exposed activated catalyst, wherein the exposed activated catalyst is treated in step (IV) to form the twice-activated catalyst.

3. The method of claim 2 , wherein step (IIa) is at least partially performed during step (III).

4. The method of claim 2 , wherein the third atmosphere comprises air.

5. The method of claim 1 , wherein the second atmosphere comprises 5.0 vppm or more of CO, based on the total volume of the second atmosphere.

6. The method of claim 1 , wherein the second atmosphere comprises 10 vol % or more of CO, based on the total volume of the second atmosphere.

7. The method of claim 1 , wherein the first atmosphere comprises at least 99 vol % of H 2 , based on the total volume of the first atmosphere.

8. The method of claim 1 , wherein the second atmosphere comprises at least 99 vol % of H 2 , based on the total volume of the second atmosphere.

9. The method of claim 1 , wherein the catalyst precursor comprises 0.1 wt % or less of the hydrogenation metal, based on the total weight of the catalyst precursor.

10. The method of claim 1 , wherein the catalyst precursor comprises 0.05 wt % or less of the hydrogenation metal, based on the total weight of the catalyst precursor.

11. The method of claim 1 , further comprising:
(V) sulfiding the twice-activated catalyst during or after step (IV).

12. The method of claim 1 , wherein the twice-activated catalyst comprises a transalkylation catalyst or wherein the twice-activated catalyst comprises a xylene isomerization catalyst.

13. The method of claim 1 , wherein the hydrogenation metal comprises at least one Group 8-10 noble metal.

14. The method of claim 1 , wherein the hydrogenation metal comprises Pt.

15. The method of claim 14 , wherein the catalyst precursor further comprises a second metal different from the first metal, the second metal comprising Sn, Ga, a metal that alloys with Pt, or a combination thereof.

16. The method of claim 1 , wherein the hydrogenation metal is at least partly supported on the molecular sieve.

17. The method of claim 1 , wherein the catalyst precursor further comprises a binder.

18. The method of claim 1 , wherein the molecular sieve is a zeolite.

19. The method of claim 1 , wherein the molecular sieve comprises one or more medium pore zeolites.

20. The method of claim 1 , wherein step (I) comprises:
(Ia) providing at least a portion of the molecular sieve, at least a portion of the catalyst precursor, or a combination thereof;
(Ib) combining the at least a portion of the molecular sieve, the at least a portion of the catalyst precursor, or the combination thereof with a liquid dispersion of a compound of the hydrogenation metal to form a molecular sieve-metal mixture, a precursor-metal mixture, or a combination thereof;
(Ic) drying the molecular sieve-metal mixture, the precursor-metal mixture, or the combination thereof; and
(Id) calcining the dried molecular sieve-metal mixture, the dried precursor-metal mixture, or the combination thereof in an oxygen-containing atmosphere.

21. The method of claim 1 , wherein the second vessel is a transalkylation reactor or a xylene isomerization reactor.

22. A method for activating a catalyst, comprising:
(I) providing a catalyst precursor comprising a hydrogenation metal and a molecular sieve, wherein the catalyst precursor comprises 0.05 wt % or less of the hydrogenation metal, based on the total weight of the catalyst precursor;
(II) reducing the catalyst precursor in a first vessel in the presence of a first atmosphere comprising H 2 and 1.0 vppm or less of CO, based on the total volume of the first atmosphere, to form an activated catalyst; and
(III) transferring the activated catalyst to a second vessel.

23. The method of claim 22 , further comprising:
(IV) treating the activated catalyst in the second vessel in the presence of a second atmosphere comprising H 2 and 3.0 vppm or more of CO, based on the total volume of the second atmosphere, to form a twice-activated catalyst.

24. The method of claim 23 , wherein the method further comprises:
(IIa) exposing at least a portion of the activated catalyst to a third atmosphere comprising 1.0 vol % or more O 2 , based on the total volume of the third atmosphere, for an exposure time of 0.1 hours or more, to form an exposed activated catalyst, wherein the exposed activated catalyst is treated in step (IV) to form the twice-activated catalyst.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Shekhar Mayank
• Podsiadlo Paul
• Molinier Michel
• Weigel Scott J
• Sparks Travis D
• Gilcrest Jocelyn A
• Gatt Joseph E

Classifications

• B01J29/7276

  MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25 · CPC title

• B01J29/068

  Noble metals · CPC title

• B01J37/20

  Sulfiding · CPC title

• C07C15/08

  Xylenes · CPC title

• C07C5/2737

  with crystalline alumino-silicates, e.g. molecular sieves · CPC title