Method of improving metal-impregnated catalyst performance

Patent metadata

Field	Value
Publication number	US-9868117-B2
Application number	US-201515122861-A
Country	US
Kind code	B2
Filing date	Mar 9, 2015
Priority date	Apr 30, 2014
Publication date	Jan 16, 2018
Grant date	Jan 16, 2018

Abstract

A method of reducing the amount of carbon monoxide present during the metal reduction step of start-up, thus, maintaining metal dispersion and improving the metal reduction and catalyst yields. Carbon monoxide formation is minimized during the start-up procedure and during the initial catalyst dryout phase in a hydrogen-containing atmosphere, gas is purged from the reactor system, either continuously at constant pressure or by a series of pressure/depressure cycles, to remove carbon monoxide. The purging is conducted at temperatures of about 30-500° C. and pressures of about −90-5,000 kPa(g) (−0.9-50 bar(g)). In this temperature range, carbon monoxide absorbed to the surface of the metal will desorb into the hydrogen-containing atmosphere and can be removed from the system along with carbon monoxide present in the atmosphere through the purging.

First claim

The invention claimed is:

1. A method of desorbing carbon monoxide from metal-impregnated catalysts, the method comprising purging gas from the catalyst reactor system at about 30-500° C. and about −90 kPa(g)-5,000 kPa(g) while the catalyst is in the presence of hydrogen by performing at least two pressure/depressure cycles, wherein said metal comprises platinum in an amount less than about 0.05 wt %, and wherein said purging reduces the carbon monoxide concentration in the catalyst reactor system to about 1 ppm or less.

2. The method of claim 1 wherein said hydrogen comprises about 0.3 ppm or less of carbon monoxide.

3. The method of claim 1 wherein said pressure/depressure cycle comprises pressurizing the catalyst reactor system to at least about 500 kPa(g) with a gas containing about 0.3 ppm or less of carbon monoxide and subsequently depressurizing the catalyst reactor system to about 200 kPa(g) or less.

4. The method of claim 3 wherein said gas comprises nitrogen or hydrogen.

5. The method of claim 1 wherein said pressure/depressure cycle is repeated four times.

6. The method of claim 1 wherein the catalyst reactor system is depressured to about 200 kPa(g) or less prior to the first pressure/depressure cycle.

7. The method of claim 1 wherein reactor system gas is purged from the catalyst reactor system within the temperature range of 100-280° C.

8. The method of claim 7 wherein reactor system gas is purged from the catalyst reactor system within the temperature range of 140-200° C.

9. The method of claim 7 wherein the reactor and the catalyst temperature is not raised above 200° C. prior to conducting the gas purging.

10. The method of claim 7 wherein reactor system gas is purged from the catalyst reactor system within the temperature range of 240-260° C.

11. The method of claim 7 wherein the reactor and the catalyst temperature is not raised above 280° C. prior to conducting the gas purging.

12. The method of claim 1 further comprising reducing the oxygen concentration in the catalyst reactor system to about 0.1% or less prior to said purging to reduce the carbon monoxide concentration.

13. The method of claim 1 wherein the catalyst further comprises at least a second Group 10 metal, a non-Group 10 metal selected from Groups 6-12, or a combination thereof.

14. The method of claim 13 wherein the Group 6-12 metal is selected from the group consisting of palladium, iridium, rhenium, copper, silver, gold, ruthenium, iron, tungsten, molybdenum, cobalt, nickel, tin, and zinc.

15. A method of reducing carbon monoxide concentration in a catalyst reactor system comprising a metal-impregnated catalyst, said process comprising:
a) providing hydrogen to the catalyst reactor system, wherein said hydrogen comprises about 0.3 ppm or less of carbon monoxide;
b) operating the catalyst reactor system at about 100-200° C.;
c) depressurizing the catalyst reactor system to about 200 kPa(g) or less;
d) pressurizing the catalyst reactor system with a gas containing about 0.3 ppm or less of carbon monoxide to at least about 500 kPa(g);
e) depressurizing the catalyst reactor system to about 200 kPa(g) or less; and
f) repeating steps d) and e) at least once more to reduce the carbon monoxide concentration in the catalyst reactor system to about 1 ppm or less.

16. The method of claim 15 wherein steps b) and c) are conducted simultaneously.

17. The method of claim 15 wherein steps d) and e) are repeated three times for a total of four pressure/depressure cycles.

18. The method of claim 15 wherein said gas in step d) comprises nitrogen or hydrogen.

19. The method of claim 15 wherein reactor system gas is purged from the catalyst reactor system within the temperature range of 140-200° C.

20. The method of claim 19 wherein the reactor and the catalyst temperature is not raised above 200° C. prior to conducting the gas purging.

21. The method of claim 15 wherein catalyst further comprises at least a second Group 10 metal, a non-Group 10 metal selected from Groups 6-12, or a combination thereof.

22. The method of claim 21 wherein the Group 6-12 metal is selected from the group consisting of palladium, iridium, rhenium, copper, silver, gold, ruthenium, iron, tungsten, molybdenum, cobalt, nickel, tin, and zinc.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Detjen Todd E
• Tinger Robert G
• Mohr Gary D
• Looney David B

Classifications

• B01J29/072 Primary

  Iron group metals or copper · CPC title

• C07C6/12

  of exclusively hydrocarbons containing a six-membered aromatic ring · CPC title

• C07C5/27

  Rearrangement of carbon atoms in the hydrocarbon skeleton · CPC title

• B01J38/10 Primary

  using elemental hydrogen · CPC title

• B01J29/068

  Noble metals · CPC title