Potassium-promoted red mud as a catalyst for forming hydrocarbons from carbon dioxide

Patent metadata

Field	Value
Publication number	US-11426708-B2
Application number	US-202016879576-A
Country	US
Kind code	B2
Filing date	May 20, 2020
Priority date	Mar 2, 2020
Publication date	Aug 30, 2022
Grant date	Aug 30, 2022

Abstract

A method and catalyst for forming higher carbon number products from carbon dioxide is provided. An exemplary catalyst includes red mud including iron and aluminum, and impregnated potassium.

First claim

What is claimed is:

1. A method for using red mud as a catalyst for forming hydrocarbons from carbon dioxide (CO 2 ), comprising:
impregnating red mud with potassium to create a potassium promoted catalyst with about 2 weight % potassium;
loading the potassium promoted catalyst in a reactor;
passing a reaction feed through the reactor, wherein the reaction feed comprises CO 2 and hydrogen (H 2 ); and
forming higher carbon number products in the reactor from the CO 2 and H 2 using the potassium promoted catalyst.

2. The method of claim 1 , further comprising using the potassium promoted catalyst to facilitate a reverse water-gas shift reaction between CO 2 and hydrogen (H 2 ) to form carbon monoxide (CO) and water (H 2 O).

3. The method of claim 2 , further comprising using the potassium promoted catalyst to facilitate a Fischer-Tropsch reaction between the CO 2 and the H 2 to form the higher carbon number products.

4. The method of claim 1 , wherein the higher carbon number products comprise C 2 -C 4 olefins.

5. The method of claim 1 , further comprising impregnating the red mud with potassium from potassium carbonate using an incipient wetness impregnation.

6. The method of claim 1 , further comprising impregnating the red mud with potassium from potassium hydroxide using an incipient wetness impregnation.

7. The method of claim 1 , further comprising:
impregnating the red mud with a potassium precursor;
evaporating liquid water from the impregnated red mud at an elevated temperature of about 70° C.; and
further drying the impregnated red mud by:
placing the impregnated red mud in a heating device;
ramping a temperature of the heating device to a maximum temperature of between about 50° C. and about 200° C. at a rate of between about 0.5° C. per minute and about 20° C. per minute; and
holding the temperature at the maximum temperature for about 12 hours.

8. The method of claim 1 , wherein the potassium promoted catalyst provides an about 45% conversion of CO 2 with a selectivity for C 2 -C 4 olefins of about 36% at a temperature of between about 300° C. and about 400° C., and 30 bar, and about 9600 mL per gram per hour.

9. A method of making a reverse water gas shift/Fischer-Tropsch catalyst for forming higher carbon number products from CO 2 , comprising impregnating red mud with potassium to form a potassium promoted catalyst with about 2 weight % potassium.

10. The method of claim 9 , further comprising mixing the red mud with a potassium precursor in a water solution.

11. The method of claim 10 , wherein the potassium precursor comprises potassium carbonate, or potassium hydroxide, or both.

12. The method of claim 9 , further comprising:
evaporating liquid water from the impregnated red mud at an elevated temperature of about 70° C.; and
further drying the impregnated red mud by:
placing the impregnated red mud in a heating device;
ramping a temperature of the heating device to a maximum temperature of between about 50° C. and about 200° C. at a rate of between about 0.5° C. per minute and about 20° C. per minute; and
holding the temperature the maximum temperature for about 12 hours.

13. A catalyst for forming higher carbon number products from CO 2 , comprising red mud comprising iron and aluminum, and impregnated potassium wherein the catalyst comprises about 2 weight % potassium.

14. The catalyst of claim 13 , further comprising 0.5 weight % impregnated potassium, or 1.0 weight % impregnated potassium.

15. The catalyst of claim 13 , comprising titanium.

16. The catalyst of claim 13 , wherein the red mud comprises gibbsite, perovskite, hematite, or cancrinite, or any combinations thereof.

17. The catalyst of claim 13 , wherein the red mud comprises Saudi Arabian red mud.

Assignees

• Saudi Arabian Oil Co
• Univ King Abdullah Sci & Tech
• Saudi Arabian Oil Componv

Inventors

• Alsolami Bandar H
• Russkikh Artem
• Ramirez Adrian
• Shterk Genrikh
• Gascon Jorge
• Fadhel Bandar A

Classifications

• C07C11/08

  with four carbon atoms · CPC title

• C07C2523/04

  Alkali metals · CPC title

• C07C2523/78

  with alkali- or alkaline earth metals or beryllium · CPC title

• B01J23/78

  with alkali- or alkaline earth metals · CPC title

• Y02P20/00

  Technologies relating to chemical industry · CPC title