Process for the production of ethylene oxide

Patent metadata

Field	Value
Publication number	US-9260366-B2
Application number	US-201514717189-A
Country	US
Kind code	B2
Filing date	May 20, 2015
Priority date	Jan 24, 2011
Publication date	Feb 16, 2016
Grant date	Feb 16, 2016

Abstract

The invention relates to a process for the production of ethylene oxide, comprising the steps of: producing ethylene by converting a stream comprising an oxygenate into a stream comprising ethylene and ethane; producing ethylene oxide by subjecting ethylene and ethane from the stream comprising ethylene and ethane to oxidation conditions resulting in a stream comprising ethylene oxide, unconverted ethylene and ethane; and recovering ethylene oxide from the stream comprising ethylene oxide, unconverted ethylene and ethane.

First claim

The invention claimed is:

1. A process for the production of monoethylene glycol, comprising the steps of:
a. producing ethylene by converting a stream comprising an oxygenate into a first product stream comprising ethylene and ethane through an oxygenate-to-olefins process;
b. producing ethylene oxide by subjecting ethylene and ethane from the first product stream comprising ethylene and ethane to oxidation conditions resulting in a second product stream comprising ethylene oxide, unconverted ethylene and ethane;
c. recovering ethylene oxide from the second product stream comprising ethylene oxide, unconverted ethylene and ethane; and
d. converting the ethylene oxide to monoethylene glycol through an hydrolysis reaction.

2. A process according to claim 1 , wherein the ethylene oxide is first converted with carbon dioxide to ethylene carbonate which is then hydrolysed to monoethylene glycol and carbon dioxide.

3. A process according to claim 1 , wherein a stream comprising unconverted ethylene and ethane is separated from the second product stream comprising ethylene oxide, unconverted ethylene and ethane and is recycled to the step of producing ethylene oxide.

4. A process according to claim 1 , wherein the first product stream comprising ethylene and ethane further comprises methane.

5. A process according to claim 1 , wherein the first product stream comprising ethylene and ethane further comprises acetylene and the first product stream comprising ethylene and ethane is subjected to hydrotreatment to convert any acetylene prior to subjecting ethylene and ethane from the first product stream comprising ethylene and ethane to oxidation conditions.

6. A process according to claim 4 , wherein the first product stream comprising ethylene and ethane further comprises hydrogen and at least part of the hydrogen is used to convert at least part of the acetylene.

7. A process for the production of monoethylene glycol, comprising the steps of:
a. producing ethylene by converting a stream comprising an oxygenate into a first product stream comprising ethylene and ethane through an oxygenate-to-olefins process;
b. producing ethylene by converting a stream comprising ethane into a second product stream comprising ethylene and unconverted ethane through a steam cracking process;
c. producing ethylene oxide by subjecting ethylene and ethane from the first product stream comprising ethylene and ethane and the second product stream comprising ethylene and unconverted ethane to oxidation conditions resulting in a stream comprising ethylene oxide, unconverted ethylene and ethane;
d. recovering ethylene oxide from the stream comprising ethylene oxide, unconverted ethylene and ethane; and
e. converting the ethylene oxide to monoethylene glycol through an hydrolysis reaction.

8. A process according to claim 7 , wherein the ethylene oxide is first converted with carbon dioxide to ethylene carbonate which is then hydrolysed to monoethylene glycol and carbon dioxide.

9. A process according to claim 7 , wherein ethane from the stream comprising ethylene oxide, unconverted ethylene and ethane is recycled to the step of producing ethylene which latter step comprises converting a stream comprising ethane into a stream comprising ethylene and unconverted ethane.

10. A process according to claim 7 , wherein ethane from the stream comprising ethylene oxide, unconverted ethylene and ethane is recycled to the step of producing ethylene oxide and to the step of producing ethylene which latter step comprises converting a stream comprising ethane into a stream comprising ethylene and unconverted ethane.

11. A process according to claim 7 , wherein a stream comprising unconverted ethylene and ethane is separated from the stream comprising ethylene oxide, unconverted ethylene and ethane, the stream comprising unconverted ethylene and ethane is separated into a stream comprising unconverted ethylene which is recycled to the step of producing ethylene oxide and a stream comprising ethane which is recycled to the step of producing ethylene which latter step comprises converting a stream comprising ethane into a stream comprising ethylene and unconverted ethane.

Assignees

• Shell Oil Co

Inventors

• VERHAAK Michael Johannes Franciscus Maria
• Van Westrenen Jeroen

Classifications

• C07D301/10 Primary

  with catalysts containing silver or gold · CPC title

• C07C1/20

  starting from organic compounds containing only oxygen atoms as heteroatoms · CPC title

• C07C29/132

  by reduction of an oxygen containing functional group · CPC title

• C07C29/106 Primary

  of oxiranes · CPC title

• C07D301/03

  by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds · CPC title